Herbicidal triazolecarboxamides

ABSTRACT

PCT No. PCT/US92/08822 Sec. 371 Date Apr. 26, 1994 Sec. 102(e) Date Apr. 26, 1994 PCT Filed Oct. 22, 1992 PCT Pub. No. WO93/09100 PCT Pub. Date May 13, 1993.Herbicidal triazolecarboxamides are useful as agricultural chemicals. In particular the compounds are useful as herbicides, both general and selective, both post-emergent and pre-emergent. Examples of selective activity include excellent control of blackgrass and wild oats with outstanding wheat tolerance, and control of crabgrass, giant foxtail, barnyardgrass and blackgrass with outstanding tolerance to corn, soybeans, rice, cotton, wheat, sugarbeets and rape.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a continuation-in-part of U.S. patent applicationSer. No. 07/784,343, filed Oct. 29, 1991, now abandoned.

BACKGROUND OF THE INVENTION

This invention relates to certain substituted triazolecarboxamides whichare useful as herbicides and their agriculturally suitable compositionsas well as methods for their use as general or selective preemergent orpostemergent herbicides or as plant growth regulants.

New compounds effective for controlling the growth of undesiredvegetation are in constant demand. In the most common situation, suchcompounds are sought to selectively control the growth of weeds inuseful crops such as cotton, rice, corn, wheat and soybeans, to name afew. Unchecked weed growth in such crops can cause significant losses,reducing profit to the farmer and increasing costs to the consumer. Inother situations, herbicides are desired which will control all plantgrowth. Examples of areas in which complete control of all vegetation isdesired are areas around railroad tracks, storage tanks and industrialstorage areas. There are many products commercially available for thesepurposes, but the search continues for products which are moreeffective, less costly and environmentally safe.

EP-A-332,133 discloses triazole compounds of the formula: ##STR1##wherein

A is ##STR2##

JP 1-106,883 discloses herbicides of the formula ##STR3##

wherein, inter alia, X and Y are independently CH or N.

SUMMARY OF THE INVENTION

This invention comprises novel compounds of Formula I, agriculturallysuitable compositions containing them, and their method-of-use aspreemergent and/or postemergent herbicides or plant growth regulants.##STR4## wherein

A is a 5-membered heterocyclic ring containing 1 to 3 heteroatomsselected from the group 0-3 nitrogens, 0-1 oxygen and 0-1 sulfur, and issubstituted with 1 to 4 substituents selected from R³, R⁴, R⁵ and R⁶ ;

R¹ is H; C₁ -C₆ alkyl optionally substituted with C₁ -C₃ alkoxy or 1 to5 halogens; C₃ -C₆ cycloalkyl; C₂ -C₆ alkenyl optionally substitutedwith 1 to 3 halogens; C₃ -C₆ alkynyl; or C₁ -C₃ alkoxy;

R² is C₁ -C₆ alkyl optionally substituted with C₁ -C₃ alkoxy or 1 to 5halogens; C₃ -C₆ cycloalkyl; C₂ -C₆ alkenyl optionally substituted with1 to 3 halogens; or C₃ -C₆ alkynyl;

R¹ and R² may be taken together to form --(CH₂)₃ --, --(CH₂)₄ --,--(CH₂)₅ -- or --(CH₂)₆ --, each ring optionally substituted with 1 to 3substituents selected from halogen and C₁ -C₃ alkyl;

R³, R⁴ and R⁵ are independently H; halogen; C₁ -C₆ alkyl optionallysubstituted with one or more halogen, C₁ -C₆ alkoxy, CN, CO₂ R⁷,S(O)_(m) R⁸, C(O)NR⁹ R¹⁰ or SO₂ NR¹³ R¹⁴ ; C₃ -C₆ cycloalkyl; C₂ -C₆alkenyl; C₂ -C₆ haloalkenyl; C₂ -C₆ alkynyl; C₁ -C₆ alkoxy; CN; CO₂ R¹¹; S(O)_(p) R¹² ; C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ; C(O)R¹⁹, C(OR²⁰)(OR²¹)R²²; CR²³ ═NOR²⁴ ; NO₂ ; NR²⁵ R²⁶ ; or phenyl or benzyl, each ringoptionally substituted with 1 to 3 substituents selected from halogen,C₁ -C₃ alkyl, C₁ -C₃ haloalkyl and C₁ -C₃ alkoxy;

R⁶ is H; C₁ -C₆ alkyl optionally substituted with one or more halogen,C₁ -C₆ alkoxy, CN, CO₂ R⁷, S(O)_(m) R⁸, C(O)NR⁹ R¹⁰ or SO₂ NR¹³ R¹⁴ ; C₂-C₆ alkenyl; C₂ -C₆ haloalkenyl; C₂ -C₆ alkynyl; CN; CO₂ R¹¹ ; SO₂ R¹² ;C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ; phenyl or benzyl, each ring optionallysubstituted with 1 to 3 substituents selected from halogen, C₁ -C₃alkyl, C₁ -C₃ haloalkyl and C₁ -C₃ alkoxy; or pyridine, pyrimidine,thiazole, thiophene or pyrazole, each ring optionally substituted with 1to 3 substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃ haloalkyland C₁ -C₃ alkoxy; and when A is ##STR5## then R³ and R⁶ may be takentogether as --(CH₂)₃ -- or --(CH₂)₄ --;

R⁷ and R¹¹ are independently H, C₁ -C₃ alkyl or allyl;

R⁸ and R¹² are independently C₁ -C₃ alkyl;

R⁹, R¹⁰, R¹³, R¹⁴, R¹⁵, R¹⁶, R¹⁷ and R¹⁸ are independently H or C₁ -C₃alkyl;

R⁹ and R¹⁰ may be taken together to form a 5- or 6-membered ring; R¹³and R¹⁴ may be taken together to form a 5- or 6-membered ring: R¹⁵ andR¹⁶ may be taken together to form a 5- or 6-membered ring; and R¹⁷ andR¹⁸ may be taken together to form a 5- or 6-membered ring;

R¹⁹, R²² and R²³ are independently H or C₁ -C₃ alkyl;

R²⁰ and R²¹ are independently C₁ -C₃ alkyl or may be taken together toform a 5- or 6-membered ring;

R²⁴ is H or C₁ -C₃ alkyl;

R²⁵ and R²⁶ are independently H, C₁ -C₃ alkyl or may be taken togetherto form a 5- or 6-membered ring;

m, n and p are independently 0, 1 or 2;

provided that

a) R³, R⁴ and R⁵ are independently bonded to carbon, and R⁶ is bonded tonitrogen; and

b) when S(O)_(n) is bonded to nitrogen then n is 2.

In the above definitions, the term "alkyl" includes straight chain orbranched alkyl, e.g., methyl, ethyl, n-propyl, isopropyl or thedifferent butyl isomers. Alkoxy includes methoxy, ethoxy, n-propyloxy,isopropyloxy, etc. Alkenyl includes straight chain or branched alkenes,e.g., 1-propenyl, 2-propenyl, 3-propenyl and the different butenylisomers. Cycloalkyl includes cyclopropyl, cyclobutyl, cyclopentyl andcyclohexyl. The term "halogen", either alone or in compound words suchas "haloalkenyl", means fluorine, chlorine, bromine or iodine. Further,when used in compound words said alkyl or alkenyl may be partially orfully substituted with halogen atoms, which may be the same ordifferent.

Preferred for reasons including ease of synthesis and/or greaterherbicidal efficacy are:

1. A compound of Formula I whereto n is 1 or 2.

2. A compound of Preferred 1 wherein A is ##STR6## wherein

X is NR⁶, O or S.

3. A compound of Preferred 2 wherein n is 2 and R¹ and R² areindependently C₁ -C₃ alkyl or C₂ -C₃ alkenyl.

4. A compound of Preferred 3 wherein A is selected from A-3, A-4, A-5and A-17, and X is NR⁶.

5. A compound of Preferred 4 wherein R³, R⁴ and R⁵ are independently H;F; Cl; Br; C₁ -C₃ alkyl optionally substituted with one or more F, Cl,Br or C₁ -C₃ alkoxy; cyclopropyl; C₂ -C₃ alkenyl; C₂ -C₃ haloalkenyl; C₂-C₃ alkenyl; C₁ -C₃ alkoxy; CN; CO₂ (C₁ -C₂ alkyl), S(O)_(p) (C₁ -C₂alkyl); C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ; C(O)R¹⁹ ; C(OR²⁰)(OR²¹)R²² ; CR²³═NOR²⁴ ; NO₂ ; NR²⁵ R²⁶ ; or phenyl optionally substituted with 1 to 3substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃ haloalkyl andC₁ -C₃ alkoxy;

R⁶ is H, C₁ -C₄ alkyl optionally substituted with one or more F, Cl, Br.C₁ -C₃ alkoxy, CN, CO₂ (C₁ -C₂ alkyl), S(O)_(m) (C₁ -C₂ alkyl), C(O)NR⁹R¹⁰ or SO₂ NR¹³ R¹⁴ ; C₂ -C₄ alkenyl; C₂ -C₄ haloalkenyl; C₂ -C₄alkynyl; CO₂ R¹¹ ; SO₂ (C₁ -C₂ alkyl); C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ;phenyl or benzyl, each ring optionally substituted with 1 to 3substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃ haloalkyl andC₁ -C₃ alkoxy; or pyridine, pyrimidine or thiazole, each ring optionallysubstituted with 1 to 3 substituents selected from halogen, C₁ -C₃alkyl, C₁ -C₃ haloalkyl and C₁ -C₃ alkoxy;

R⁹, R¹⁰, R¹³ and R¹⁴ are independently C₁ -C₂ alkyl;

R¹¹ is C₁ -C₂ alkyl or allyl;

R¹⁵, R¹⁶, R¹⁷, R¹⁸, R²⁵ and R²⁶ are independently C₁ -C₃ alkyl; and R¹⁹,R²² and R²³ are independently H or C₁ -C₂ alkyl.

6. A compound of Preferred 5 wherein

R¹ and R² are independently ethyl or allyl; and

R⁵ is H, cyclopropyl, Cl, CH₃, C₂ H₅ or CF₃.

7. A compound of Preferred 6 wherein

R³ and R⁴ are independently H, Cl, C₁ -C₃ alkyl, CF₃, C₁ -C₂ alkoxy orC₂ -C₃ alkenyl; and

R⁶ is C₁ -C₃ alkyl optionally substituted with 1 to 3 F, Cl, Br, C₁ -C₂alkoxy, CN, CO₂ (C₁ -C₂ alkyl)or C(O)NR⁹ R¹⁰ ; allyl; propargyl;C(O)NR¹⁵ R¹⁶ ; phenyl; pyridine; pyrimidine; or thiazole.

8. A compound of Preferred 7 selected from:

3-(5-chloro-1-ethyl-3-methyl-1H-pyrazol-4-yl)sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide;

3- (3,5-diethyl-1-methyl-1H-pyrazol-4-yl)sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide; and

3-5-chloro-3-methyl-1-(2,2,2-trifluoroethyl)-1H-pyrazol-4-yl!sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide.

DETAILED DESCRIPTION OF THE INVENTION

Compounds of General Formula I can be readily prepared by one skilled inthe art by using the reactions and techniques described in Scheme 1 toScheme 29 below. In cases where the substituent of a starting materialis not compatible with the reaction conditions described for any of thereaction schemes, it can be assumed that the substituent is convened toa protected form prior to the described reaction scheme and thendeprotected after the reaction using commonly acceptedprotecting/deprotecting techniques (as an example, see T. W. Greene andP. G. M. Wuts, "Protective Groups in Organic Synthesis", 2nd Edition,John Wiley and Sons. Inc., New York, 1991). Otherwise alternativeapproaches known to one skilled in the art are available.

Scheme 1 illustrates the preparation of compounds of General Formula I(where n, A, R¹ and R² are defined as above) whereby the triazolederivative of General Formula II (where n and A are defined as above) isallowed to react with the carbamoyl halide of General Formula III (whereR¹ and R² are defined as above; W is a halogen atom). ##STR7##

This reaction is performed in an inert solvent such as acetonitrile,acetone. N,N-dimethylformamide, benzene, toluene, xylene, chloroform,dichloroethane, dioxane, tetrahydrofuran or methylethylketone and in thepresence of a hydrogen halide removing agent such as trimethylamine,pyridine, sodium carbonate, potassium carbonate, sodium ethoxide,potassium t-butoxide or sodium hydride with the reaction temperaturebeing between 0° and 140° C. and the reaction time being between 10minutes and 100 hours.

One to 5 equivalents of hydrogen halide removing agent and 1 to 4equivalents of carbamoyl halide of General Formula III are usually usedper one equivalent of the triazole derivative of Formula II.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure and water is added to the residue. The aqueouslayer is then extracted with organic solvent. The organic extract isthen dried and concentrated. The crude product can be further purifiedby means of flash column chromatography, recrystallization, or a similaroperation if needed.

Scheme 2 illustrates the preparation of compounds of General Formula Ia(which are compounds of General Formula I where R¹ is H; A, n and R² aredefined as above) whereby the triazole derivative of General Formula II(wherein A and n are defined as above) is allowed to react with anisocyanate of General Formula IV (wherein R² is defined as above).##STR8##

This reaction is performed in an inert solvent such as acetonitrile,N,N-dimethylformamide, benzene, toluene, xylene, chloroform,dichloroethane, dioxane, tetrahydrofuran or methylethylketone with orwithout a catalyst such as methylamine, pyridine, potassium t-butoxideor 1,8-diazabicyclo 5.4.0!-undec-7-ene (DBU). The reaction temperatureranges from 0° to 140° C. and the reaction time is between 10 minutesand 100 hours.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure. Water is then added to the residue and theaqueous layer is extracted with organic solvent. The organic extract isdried and concentrated to give the crude product. This crude product canbe further purified by flash column chromatography if needed.

Compounds of General Formula Ib (which are compounds of General FormulaI where n is 1 or 2; A, R¹ and R² are defined as above; m is the same asn if applicable) can also be prepared by oxidizing the compounds ofGeneral Formula Ic (which are compounds of General Formula I where n is0; A, R¹ and R² are defined as above) as illustrated in Scheme 3.##STR9## wherein

n^(a) is 1 or 2

The oxidizing reagents that can be used in the process of Scheme 3include 3-chloroperoxybenzoic acid, peracetic acid, trifluoroperaceticacid and hydrogen peroxide. This oxidation is normally performed in asolvent and the solvents that can be used will vary depending on thetype of oxidizing reagent used. For example, if the oxidizing reagent is3-chloroperoxybenzoic acid, benzene, methylene chloride, chloroform orother halogenated hydrocarbons can be used as solvent. If peracetic acidor trifluoroperacetic acid is used as the oxidizing reagent, halogenatedhydrocarbons or the corresponding acid can be used as solvent. If theoxidant is hydrogen peroxide, water, acetone, acetic acid or the likecan be used.

The reaction temperature range is normally 0° to 80° C. while thereaction time ranges from 10 minutes to 100 hours. In general, 0.9 to1.2 equivalents of the oxidizing reagent are used for the preparation ofcompounds of General Formula Ib where n is 1. Two to five equivalents ofoxidant are used for preparing compounds of General Formula Ib where nis 2. When substituent(s) on A contains sulfur atom(s), additionalamounts of oxidant will be needed for the oxidation of the additionalsulfur atom(s) on the substituent(s) to the desired oxidation state.

Upon completion of the reaction, methylsulfide or other reducing agentsare added to destroy the unreacted oxidant. Water is then added followedby organic solvent extraction. If 3-chloroperoxybenzoic acid is used asthe oxidant, the organic extract is washed with dilute basic aqueoussolution such as sodium bicarbonate aqueous solution. The organicextract is then dried and concentrated to give the crude product. Flashcolumn chromatography, recrystallization or a similar operation may beperformed to further purify the crude product if needed.

Scheme 4 illustrates the preparation of compounds of General Formula Id(which are compounds of General Formula I where A is A-2; X is O; n isdefined as above; R¹ is defined as above, other than H; R² is defined asabove; R³ is H, C₃ -C₆ cycloalkyl, C₂ -C₆ alkenyl, C₂ -C₆ alkynyl, C₁-C₆ alkoxy or C₁ -C₆ alkyl optionally substituted with one or more F,Cl, Br or C₁ -C₃ alkoxy; R⁴ is C₁ -C₆ alkyl; R⁵ is H or C₁ -C₆ alkyl)whereby a triazolecarboxamide derivative of General Formula V is allowedto react with an acetylenic sulphonium salt of General Formula VI in thepresence of a base. ##STR10## wherein

R^(1a) is R¹ except H;

R^(3a) is H, C₃ -C₆ cycloalkyl, C₂ -C₆ alkenyl, C₂ -C₆ alkynyl, C₁ -C₆alkoxy or C₁ -C₆ alkyl optionally substituted with one or more F, Cl, Bror C₁ -C₃ alkoxy;

R^(4a) is C₁ -C₆ alkyl;

R^(5a) is H or C₁ -C₆ alkyl;

R^(4b) is H or C₁ -C₅ alkyl.

This reaction is carried out in a solvent such as acetonitrile,methylene chloride, N,N-dimethylformamide, dioxane, tetrahydrofuran,ethyl alcohol or t-butyl alcohol with reaction temperature ranging from0° to 120° C. and reaction time being between 10 minutes and 100 hours.

One to two equivalents of base such as 1,8-diazabicyclo5.4.0!-undec-7-ene (DBU), triethylamine, diisopropyl-ethylamine, sodiumethoxide or potassium t-butoxide and 1 to 1.2 equivalents of theacetylenic sulphonium salt of General Formula VI are used per equivalentof the triazolecarboxamide derivative of General Formula V.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure. The desired product is isolated from the residueby flash column chromatography.

Compounds of General Formula IIa (which are compounds of General FormulaII where n is 2; A is defined as above) can be prepared by reacting thesulfonyl fluoride of General Formula VII with the lithium salt generatedin situ from compounds of General Formula VIII (where R²⁸ is C₁ -C₄alkyl and the two R²⁸ groups may be taken together to form --(CH₂)₃ --,--(CH₂)₄ --, --(CH₂)₅ -- or --(CH₂)₆)-- as illustrated in Scheme 5.##STR11## wherein

R²⁷ is n-butyl, 2-butyl or t-butyl;

A is defined as above.

In this reaction, the compound of General Formula VIII in an inertsolvent such as diethylether, dimethoxyethane or tetrahydrofuran iscooled under N₂ to -60° C. to -100° C. and the solution of an alkylLithium such as n-butyllithium or t-butylithium in an inert solvent suchas hexane is slowly added dropwise to it. The resulting mixture is keptat -50° to -100° C. for a period of time ranging from 10 minutes to 2hours. The sulfonyl fluoride of General Formula VII in an inert solventsuch as diethylether or dimethoxyethane or tetrahydrofuran is then addedwhile the reaction temperature is kept at -50° to -100° C. After theaddition, the reaction mixture is allowed to warm up to room temperatureand stirred at that temperature for 10 minutes to 5 hours. Aqueoushydrochloric acid is then added. The resulting mixture is allowed tostir for 10 minutes to 2 hours. Aqueous NaHCO₃ solution is then added tothis mixture until a pH between 4 and 7 is reached. Organic solvent suchas methylene chloride is then added. The mixture is then shaken in aseparatory funnel. The organic layer is separated, dried over sodiumsulfate or magnesium sulfate and concentrated to give the crude product.This crude product can be further purified through flash columnchromatography, recrystallization or other similar operations.Alternatively, the reaction procedures taught by A. R. Katritzky et al.,Tetrahedron 46(2), 641 (1990), or slight modifications thereof, can alsobe used for the reaction of Scheme 5. Compounds IIa can also be preparedfrom compounds I through alkaline hydrolysis by one skilled in the art.

Compounds of General Formula IIb (which are compounds of General FormulaII where n is 0, A is defined as above) can be prepared by reacting thedisulfide of General Formula IX (where A is defined as above) with thelithium salt generated in situ from compounds of General Formula VIII(where R²⁸ is C₁ -C₄ alkyl) as illustrated in Scheme 6. ##STR12##wherein

R²⁷ is n-butyl, 2-butyl or t-butyl.

In this reaction, the compound of General Formula VIII in an inertsolvent such as diethylether, dimethoxyethane or tetrahydrofuran iscooled under N₂ to -60° C. to -100° C. and the solution of an alkyllithium such n-butyl lithium or t-butyl lithium in an inert solvent suchas hexane is slowly added dropwise to it. The resulting mixture is keptat -50° to -100° C. for a period of time ranging from 10 minutes to 2hours. The disulfide of Genera/Formula IX in an inert solvent such asdiethylether, dimethoxyethane or tetrahydrofuran is then added while thereaction temperature is kept at -50° to -100° C. After the addition, thereaction mixture is allowed to warm up to a temperature ranging from 20°C. to 60° C. and stirred at that temperature for 10 minutes to 5 hours.Aqueous hydrochloric acid is then added. The resulting mixture isallowed to stir for 10 minutes to 2 hours. Aqueous NaHCO₃ solution isthen added to this mixture until a pH between 5 and 7 is reached.Organic solvent such as methylene chloride is then added. The mixture isthen shaken in a separatory funnel. The organic layer is separated,dried over sodium sulfate or magnesium sulfate and concentrated to givethe crude product. The crude product can be further purified by flashcolumn chromatography, recrystallization or other similar operation.Alternatively, the reaction procedures taught by A. R. Katritzky et al.,Tetrahedron 46(2), 641 (1990), or slight modifications thereof, can alsobe used for the reaction of Scheme 6.

Scheme 7 illustrates the preparation of compounds of General Formula IIc(which are compounds of Genera/Formula II where n is 0, A is A-4; R³ andR⁴ are independently C₁ -C₆ alkyl or C₃ -C₆ cycloalkyl, X is O or NR⁶)whereby a triazolylthiodiketone of Genera/Formula X is reacted with ahydrazinc or a hydroxylamine of General Formula XI. ##STR13## wherein

R^(4d) is C₁ -C₆ alkyl or C₃ -C₆ cycloalkyl;

R^(3b) is C₁ -C₆ alkyl or C₃ -C₆ cycloalkyl;

X is O or NR⁶.

This reaction is carried out in a solvent such as methanol, ethanol,isopropanol, N-N-dimethylformamide or acetonitrile with the reactiontemperature between 25° C. and 140° C. for a period of time ranging from0.5 to 500 hours. One to 3 equivalents of XI are usually used perequivalent of X.

Upon completion of the reaction, the reaction mixture is concentrated.Water is added to the residue. The aqueous layer is then extracted withorganic solvent such as hexane, ether or methylene chloride. The organicextract is then dried over sodium sulfate or magnesium sulfate andconcentrated under reduced pressure to give the desired product. Thiscrude product may be further purified by flash column chromatography,recrystallization or other similar operation.

Scheme 8 illustrates the preparation of compounds of General Formula IId(which are compounds of General Formula II where n is 0, A is A-4; R³ isCl or Br; R⁴ is R^(4d) ; X is NR⁶) whereby a triazolylthioheterocycle ofGeneral Formula XII (wherein R^(4d) and R⁶ are defined as above) isallowed to react with a halogenating agent such as phosphorousoxychloride or phosphorous oxybromide. ##STR14## wherein

R^(4d) is defined as above;

R⁶ is defined as above;

V is Cl or Br.

This reaction is carried out in the absence of a solvent or in an inertsolvent such as dioxane, chloroform, dichloroethane or toluene in asealed tube or under atmospheric pressure. The reaction temperature isbetween 50° C. and 170° C. and the reaction time ranges from 2 to 50hours. One to 100 equivalents of halogenating agent such as phosphorusoxychloride or phosphorus oxybromide are used per equivalent of thecompound of General Formula XII.

Upon completion of the reaction, the solvent and/or the excesshalogenating agent are evaporated under reduced pressure. Water is thenadded to the residue. The aqueous layer is then extracted with organicsolvent such as ether or methylene chloride. The organic extract isdried over magnesium sulfate or sodium sulfate and then concentratedunder reduced pressure to give the desired product. This crude productcan be further purified by flash column chromatography,recrystallization or other similar operation.

Scheme 8a illustrates the preparation of compounds of General FormulaIIg (which are compounds of General Formula II where n is 0, A is A-4;R³ is C₁ -C₆ alkoxy; R⁴ is R^(4d) ; X is NR⁶) whereby atriazolylthioheterocycle of General Formula XII (wherein R^(4d) and R⁶are defined as above) is allowed to react with an alkylating agent suchas dialkylsulfate, alkyliodide, alkylbromide, or alkylsulfonate in thepresence of a base such as potassium carbonate, sodium carbonate,potassium bicarbonate, triethylamine, or 1,8-diazabicyclo5.4.0!-undec-7-ene (DBU). ##STR15## wherein

R^(4d) is defined as above;

R⁶ is defined as above;

R³⁰ is C₁ -C₆ alkyl.

To one equivalent of the compound of General Formula XII in an inertsolvent such as acetone, dioxane, N,N-dimethylformamide is added one totwenty equivalents of a base. The resulting mixture is stirred attemperature between 0° C. and 150° C. for 1 to 150 hours. One to fiveequivalents of an alkylating agent is then added. The resulting mixtureis stirred for another 1 to 100 hours at temperature between 0° C. and150° C. The solvent is then evaporated. To the residue is added water.The aqueous solution is then extracted with an organic solvent such asmethylene chloride or ethyl acetate. The organic extract is then driedover sodium sulfate or magnesium sulfate and concentrated under reducedpressure to give the desired product. This crude product may be furtherpurified by flash column chromatography, recrystallization or othersimilar operation.

Scheme 9 illustrates the preparation of compounds of General Formula IIe(which are compounds of General Formula II where A is A-1 to A-14);whereby a halogen substituted heterocycle of General Formula XIII(wherein V is Cl or Br; A^(a) is A-1 to A-14) is allowed to react withthe anion of 1,2,4-triazole-3-thiol (Formula XIV). ##STR16## wherein

M is Na, Li or K.

This reaction is carried out in a solvent such as N,N-dimethylformamide,ethanol, isopropanoI or t-butyl alcohol at temperatures between 50° C.and 140° C. for a period of time between 30 minutes and 48 hours. One to2 equivalents of XIV are usually used per equivalent of XIII.

Upon completion of the reaction, the reaction solvent is evaporatedunder reduced pressure and water is added to the residue. Aqueoushydrochloric acid is then added until the solution pH reaches about 7.

If the desired product precipitated out from the water, it is collectedby filtration, air dried and then dried in an oven. Alternatively,organic solvent such as methylene chloride or ethyl acetate is added toextract the product out of the aqueous layer. The organic extract isthen dried over sodium sulfate or magnesium sulfate and thenconcentrated to give the desired product. The crude product can befurther purified by recrystallization, flash column chromatography orother similar operation.

Compounds of Genera/Formula III and General Formula IV are eithercommercially available or can be prepared by one skilled in the an.

Compounds of General Formula Va (which are compounds of Genera/ FormulaV where n is 1 or 2; R¹, R² and R^(3a) are defined as above) can beprepared by allowing compounds of General Formula Vb (which arecompounds of General Formula V where n is 0; R¹, R² and R^(3a) aredefined as above) to react with the appropriate amount of an oxidizingreagent such as 3-chloroperoxybenzoic acid, peracetic acid,trifluoroperacetic acid or hydrogen peroxide as illustrated in Scheme10. ##STR17##

The reaction conditions for Scheme 10 are very similar to thosedescribed for Scheme 3 with the exception that Vb is used instead of Ic.

Scheme 11 illustrates the preparation of compounds of General Formula Vbhereby the α-triazolylthioketone of General Formula XV (wherein R^(3a)is defined as above) is allowed to react with the carbamoyl halide ofGeneral Formula III. ##STR18##

This reaction is performed in an inert solvent such as acetonitrile,N,N-dimethylformamide, toluene, chloroform or tetrahydrofuran and in thepresence of a hydrogen halide removing agent such as triethylamine,pyridine or sodium carbonate at a temperature between 0° and 140° C. fora period of time ranging from 10 minutes to 100 hours. One to 5equivalents of hydrogen halide removing agent and 1 to 4 equivalents ofcarbamoyl halide of General Formula III are usually used per equivalentof the triazole derivative of Formula XV.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure and water is added to the residue. The productcan be collected by filtration if it precipitates.

Alternatively, the aqueous solution is extracted with organic solvent.The organic extract is then dried and concentrated to give the desiredproduct. The crude product can be further purified by means ofrecrystallization, flash column chromatography or a similar operation ifneeded.

Compounds of General Formula VI can be prepared using methods taught byG. D. Appleyard and C. J. M. Stirling in J. Chem. Soc. (C), 1904 (1969);and by J. W. Batty, P. D. Howes and C. J. M. Stirling in J.C.S., PerkinI, 65 (1973) or using slight modifications of the above-mentionedmethod.

Compounds of General Formula VIII can be prepared from 1,2,4-triazole,dialkylamine (or its hydrochloride salt) and formaldehyde using methodstaught by Alan R. Katritzky, Gordon W. Rewcastle and Wei-Giang Fan in J.Org. Chem., 53 5685 (1988); by F. B. Stocker J. L. Kurtz, B. L. Gilmanand D. A. Forsyth in J. Org. Chem. 35 883 (1970); by K. Hideg and H. O.Hankovsky in Acta. Chim. Acad. Sci. Hung (Budapest) 53 271 (1967); byAlan R. Katritzky, Andrzej Jozwiak, Ping Lue, Konstantina Yannakopoulou,Gus J. Palenik and Ze Ying Zhang in Tetrahedron 46 (2), 633 (1990); andby S. Oeckl, H. G. Schmitt, W. Pattius, and H. Genth in German. PatentDE 3,238,006, Apr. 19, 1984, or using slight modification of theabove-mentioned methods.

Compounds of General Formula VII can be prepared from sulfonyl chloridesof General Formula XVI (where A is defined as above) as illustrated inScheme 12. ##STR19##

Reaction conditions taught by J. Ichihara, T. Matsuo, T. Hanafusa and T.Ando in J. Chem. Soc. Chem. Comm., No. 10, 793 (1986); by H. G. Liu, P.Wang and P. N. Sun in J. Fluorine Chem., 43(3), 429 (1989); by C. L.Borders, Jr., D. L. Macdonell, and J. L. Chambers, Jr., in J. Org. Chem.37 3549 (1972); by T. A. Blanchi and L. A. Cate, in J. Org. Chem., 422031 (1977); and by T. Kitazume and N. Ishikawa, in Chem. Lett., 283(1978) or slight modifications thereof can be used for reactions ofScheme 12.

Compounds of General Formula IX can be prepared by reacting thiols ofGeneral Formula XVII (wherein A is defined as above) with bromine,chlorine or sulfuryl chloride as illustrated in Scheme 13. ##STR20##

This reaction is carried out in a solvent such as methylene chloride,chloroform or methanol in the presence of 1 to 3 equivalents of hydrogenhalide removing agent such as triethylamine or sodium methoxide (perequivalent of the thiol of General Formula XVII) at temperature between0° and 60° C. for a period of time ranging from 10 minutes to 20 hours.Per equivalent of the thiol of Formula XVII, 0.5 to 1.2 equivalents ofthe halogenating agent such as bromine, chlorine or sulfuryl chlorideare usually used. The product can be isolated by filtration if itprecipitates out of the reaction solution. Otherwise the reactionmixture is concentrated under reduced pressure. To the residue is addedwater and the aqueous layer is then extracted with organic solvent suchas ether, hexane or methylene chloride. The organic extract is driedover sodium sulfate or magnesium sulfate and then concentrated underreduced pressure to give the desired product. The crude product can befurther purified by recrystallization, flash column chromatography orother similar operation.

Scheme 14 illustrates the preparation of compounds of General Formula Xwhereby compounds of General Formula XVIII (wherein R^(3b) and R^(4d)are defined as above: V is Cl or Br) are allowed to react with1,2,4-triazole-3-thiol. ##STR21##

This reaction is performed in a solvent such as N,N-dimethylformamide,acetonitrile, tetrahydrofuran or methanol in the presence of a base suchas methylamine, sodium methoxide, potassium hydroxide or sodium hydrideat temperature between 25° C. and 140° C. for a period of time rangingfrom 30 minutes to 70 hours.

One to 2 equivalents of 1,2,4-triazole-3-thiol and 1 to 3 equivalents ofthe base is usually used per equivalent of XVIII.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure. Water is added to the residue. The product canbe isolated by filtration if it precipitates. Otherwise the aqueoussolution is extracted with organic solvent. The organic solvent is driedover magnesium sulfate (or sodium sulfate) and concentrated underreduced pressure to give the desired product. The crude product can befurther purified by recrystallization, flash column chromatography orother similar operation.

Compounds of General Formula XI are either commercially available or canbe prepared by one skilled in the art.

Scheme 15 illustrates the preparation of compounds of General FormulaXII whereby a triazolylthioketoester of General Formula XIX (whereinR^(4d) is defined as above; R²⁹ is C₁ -C₂ alkyl) is allowed to reactwith hydrazines of General Formula XX (wherein R⁶ is defined as above).##STR22##

The reaction conditions for Scheme 15 are very similar to thosedescribed for Scheme 7 with the exception that XIX is used instead of X.

Compounds of General Formula XIII are either commercially available orcan be prepared by one skilled in the art using literature methods orslight modification thereof.

Some examples of the above-mentioned literature methods are:

Dario Chiarino et al., J. Med. Chem.,34(2),600(1991)

Kenzi Makino et al., J. Fluorine Chem., 39 (3), 435 (1988)

Robert Kenneth Howe et al., EP 27020

Dietmar Seyferth et al., J. Am. Chem. Soc., 95 (25), 84645 (1973)

Len F. Lee et al., J. Heterocycl. Chem.,22(6), 1621 (1985)

V. S. Korsunskii et al., Khim.-Farm. Zh.,23(2),249(1989)

Jerzy Suwinski et al., Pol. J., Chem.,56(10-12),1261 (1982)

Patricia Demaree et al., Can. J. Chem., 55 (2).243 (1977)

Yu. N. Bulychev et al., Khim. Geterotsikl. Soedin., (7) 920 (1988)

L. I. Bagal et al., Khim. Geterotsikl. Soedin., (12) 1701 (1970)

Ian J. Ferguson et al., J. Chem. Soc., Perkin Trans. 1, (6) 672 (1977)

Zdislaw Machon et al., Acta Pol. Pharm.,45(1) 18(1988)

Norio Sasaki et al., Yakugaicu Zasshi, 90(1)32(1970)

Tadaski Sasaki et al., J. Chem. Soc. C, (11) 2147 (1971)

Frartz Effenberger et al., Chem. Ber., 120 (1) 45 (1987)

Richard C. Larock et al., J. Org. Chem.,48,(13) 215i (1983)

Michael E. Sitzmann., J. Heterocycl. Chem., 16 (3) 477 (1979)

Scheme 16 illustrates the preparation of compounds of General Formula XVwhereby a haloketone of General Formula XXI (wherein V is Cl or Br;R^(3a) is defined as above) is allowed to react with1,2,4-triazole-3-thiol. ##STR23##

The reaction conditions for Scheme 16 are very similar to thosedescribed for Scheme 14 with the exception that XXI is used instead ofXVIII.

Compounds of General Formula XVI and General Formula XVII are eithercommercially available or can be prepared by one skilled in the artusing literature methods or slight modifications thereof.

The literature methods include:

George Levitt et al., U.S. H504 (published 8/2/88)

R. G. Jones et al., J. Am. Chem. Soc.,72,4000(1949)

Paolo Gnmanger and Paola Vita-Finzi, "Heterocyclic Compounds", Vol. 49p. 337 and p. 391

Geoffrey A. Carter et al., Pestic. Sci.,6(1),43 (1975)

Tyo Sone et al., Bull. Chem. Soc. Jap., 58 (3), 1063 (1985),

L. S. Abovyan et al., Kim.-Farm. Zh., 17 (6), 685 (1983)

Giovanni Consiglio et al., J. Chem. Soc., Perkin Trans. 2, (5), 625(1982)

Phillip A. Rossy et al., J. Org. Chem., 45 (4) 617 (1980)

Robert Bellemin et at., J. Heterocycl. Chem., 21 (4), 1017 (1984)

Fritz Eiden et at., Arch. Pharm. (Weinheim), 322 (11 ), 807 (1989)

Kenneth Clarke et at., J. Chem. Soc., Perkin Trans. 1, (4), 1029 (1980)

Manfred Regitz et al., Chem. Ber., 102 (2), 417 (1969)

Manfred Regitz et at., Justus Liebigs Ann. Chem., 710, 118 (1967)

Marcel Pesson et al., C. R. Acad Sci., Paris, Ser. C, 267 (25), 1726(1968)

Marcel Pesson et al., Bull. Soc. Chim. Fr., (4), 1590(1970)

Ludwig Nuesslein et al., DE 2853196

Charles A. R. Baxter et al., DE 2612761

Marc Montavon et al., EP-A-75 104

M. Liliana Graziano et al., J. Chem. Res., Synop., (2) 42 (1989)

Alfred Treibo et al., Jusms Liebigs Ann. Chem., (2), 207 (1973)

R. L. N. Harris, Aust. J. Chem., 25 (5), 985 (1972)

Ya. L. Goldfarb et at., Izv. Akad. Nauk SSSR, Ser. Khim., (10) 2260(1969)

L. A. Boilco et al., Khim. Geterotsikl. Soedin., (6), 723 (1970)

Nobuyuki Okajima et at., Synthesis, (5), 398 (1989)

I. M. Bazavova et al., Zh. Org. Khim., 17 (1), 200 (1981)

P. Manolova et al., Farmatsiya (Sofia), 29 (6), 1 (1979)

V. Buran et al., Boll. Chim. Farm., 119 (12), 725 (1980)

Surendra Kulkami et al., Aust. J. Chem., 40 (8) 1415 (1987)

T. K. Vinogradova et al., Zh. Org. Khim., 18 (9), 1864 (1982)

Benjamin Blank et al., J. Med. Chem., 20 (4), 572 (1977)

Manfred Regitz et al., Liebigs Ann. Chem., (2), 305 (1980)

R. Alan Jones; "Heterocyclic Compounds", Vol. 48 p. 235

Compounds of General Formula XVIII are either commercially available orcan be prepared by one skilled in the art by well-known methods.

Scheme 17 illustrates the preparation of compounds of General FormulaXIX whereby a haloketoester of General Formula XXII (wherein V is Cl orBr; R^(4d) and R²⁹ are defined as above) is allowed to react with1,2,4-triazole-3-thiol. ##STR24##

The reaction conditions for Scheme 17 are very similar to thosedescribed for Scheme 14 with the exception that XXII is used instead ofXVIII.

Compounds of General Formula XXI and General Formula XXII are eithercommercially available or can be prepared by one skilled in the an usingwell-known methods such as N. DeKimpe et at., Synthesis, 2, 188 (1987).

Scheme 18 illustrates an alternative method for preparing compounds ofGeneral Formula IIf (which are compounds of General Formula II where Ais A-4; n is 0; X is NR^(6a) and R^(6a) is C₁ -C₆ alkyl or C₃ -C₆cycloalkyl; R³ is R^(3b) ; R⁴ is R^(4d)) whereby an amine of GeneralFormula XXIII is allowed to react with hydroxylamine-O-sulfonic acid andthe reaction product formed in situ is then allowed to react with atnazolylthiodiketone of General Formula X. ##STR25## wherein

R^(3b) and R^(4d) are defined as above;

R^(6a) is C₁ -C₆ alkyl or C₃ -C₆ cycloalkyl.

This reaction is carried out by adding hydroxylamine-O-sulfonic acid ina solvent such as water to an amine of General Formula XXIII in asolvent such as water or in the absence of a solvent. The mixture isstirred at temperature between 0° C. and 8)° C. for a period of timebetween 1 minute and 24 hours. Most of the unreacted amine of GeneralFormula XXIII is then distilled away under reduced pressure. To theresidue is then added the triazolylthiodiketone of General Formula X ina solvent such as methanol, acetonitrile or N,N-dimethylformamide. Theresulting mixture is then stirred at a temperature between 0° C. for aperiod of time between 1 and 200 hours.

One to ten thousand equivalents of the amine of General Formula XXIIIand one to five equivalents of hydroxylamine-O-sulfonic acid perequivalent of the triazolylthiodicetone of General Formula X are usuallyused.

Upon completion of the reaction, the solvent is evaporated under reducedpressure. The residue is partitioned between water and an organicsolvent such as dichloromethane. The organic extract is then separated,dried over magnesium sulfate (or sodium sulfate) and concentrated underreduced pressure. This crude product can be further purified by flashcolumn chromatography, recrystallization or other similar operations.

The amines of General Formula XXIII are either commercially available orcan be prepared by one skilled in the an using well-known methods.

Scheme 19 illustrates the preparation of compounds of General Formula Ie(which are compounds of General Formula I where A is A-15, A-16, A-17,A-18, A-19 or A-20; n is 2; R is R^(1a), R² is defined as above) wherebya 1-amino-carbonyltriazole-3-sulfonyl chloride of General Formula XXIVis allowed to react with a heterocycle of General Formula XXV in thepresence of a base. ##STR26## wherein

A^(b) is A-15, A-16, A-17, A-18, A-19 or A-20.

This reaction is carried out in a solvent such as acetonitrile,methylene chloride, N,N-dimethylformamide, dioxane, tetrahydrofuran ortoluene with reaction temperature ranging from 0° to 120° C. andreaction time between 10 minutes and 100 hours.

In general, 0.5 to 5 equivalents of base such as triethylamine,diisopropylethylmine, sodium hydride or potassium t-butoxide and 0.5 to2 equivalents of 1-aminocarbonyltriazole-3-sulfonyl chloride of GeneralFormula XXIV are used per equivalent of the heterocycle of GeneralFormula XXV. Compounds of General Formula XXV are either commerciallyavailable or can be prepared by one skilled in the art.

Upon completion of the reaction, the reaction mixture is concentratedunder reduced pressure. The desired product is isolated from the residueby flash column chromatography, recrystallization or a similaroperation.

The 1-aminocarbonyltriazole-3-sulfonyl chlorides of General Formula XXIVcan be prepared from the thioether of General Formula XXVI as depictedin Scheme 20. ##STR27##

In this reaction, hypochlorite solution, i.e., NaOCl, is contacted withthioether of General Formula XXVI in a two-phase solvent system bufferedwith a suitable inorganic acid such as aqueous hydrochloric acid toprovide XXIV. The reaction temperature can be from about -10° to about10° C., preferably from about -5° to about 5° C., and the reaction timefrom about 0.5 to 3 hours, preferably from 0.5 to 1 hour. Suitablesolvents are water and an men organic solvent such as methylene chlorideor 1,2-dichlorobenzene, with methylene chloride being preferred.Following completion of the reaction, the organic phase is isolated,washed with aqueous sodium bisulfite solution, dried (e.g., MgSO₄) andconcentrated in vacuo at about 25° to 35° C. to provide a residuecontaining XXIV. The impure residue containing XXIV can be furtherpurified by slurrying with hexane and/or flash chromatography on silicagel, and/or recrystallization if a solid. For further details, seeanalogous reactions in South African Patent Application No. 84/8845 and84/8844.

Intermediate thioether of General Formula XXVI can be prepared asdepicted in Scheme 21. ##STR28##

The reaction of Scheme 21 can be carried out according to the teachingsof U.S. Pat. No. 4,280,83 1, DE 3,929,673 A1 and U.S. Pat. No.3,962,001. Thus, XXVI can be obtained by contacting3-benzylthio-1,2,4-triazole (XXVII) with carbamoyl chloride of GeneralFormula IIIa (which are compounds of General Formula III where R¹ isR^(1a) ; W is Cl; R² is defined as above) in excess pyridine at fromabout 20° to about 30° C.; or by contacting XXVII with IIIa and atertiary amine base such as triethylamine in an inert organic solventsuch as tetrahydrofuran at about 25° C. to reflux.

Intermediate carbamyl chloride IIIa can be prepared by contactingappropriate secondary amines with phosgene in an inert organic solventsuch as refluxing ethyl acetate, according to the teachings of U.S. Pat.No. 3,952,001. The preparation of 3-benzylthio-1,2,4-triazole XXVII istaught in U.S. Pat. No. 4,280,831.

Alternatively, thioethers of General Formula XXVI can be preparedaccording to the teachings of U.S. Pat. No. 3,952,001. Thus, contactingtriazole of General Formula XXVII with phosgene and a tertiary aminebase such as pyridine or methylamine in an inert organic solvent suchtetrahydrofuran at from about 0° to about 30° C. can provide thecorresponding carbamyl chloride. Subsequent reaction of the carbamylchloride with an appropriate secondary amine in the presence of asuitable base such as pyridine or triethylamine in an inert organicsolvent such as tetrahydrofuran at from about 0° to about 30° C. canprovide XXVI. Appropriate secondary amines axe known or can be preparedby methods generally known to those skilled in the art; see. e.g., U.S.Pat. No. 3,952,001.

Scheme 22 illustrates the preparation of compounds of General Formula If(which are compounds of General Formula I where A is A-2; X is NR⁶ ; nis 2; R¹ is R^(1a) ; R² is defined as above; R³ is H or C₁ -C₆ alkyloptionally substituted with one or more F, Cl, Br or C₁ -C₃ alkoxy; R⁴is R^(4a) ; R⁵ is H or C₁ -C₆ alkyl optionally substituted with one ormore halogen) whereby a mesoionic oxazolones of Gemeral Formula XXVIII(which may be prepared in situ) is allowed to react with an1,2-propaclienylsulfone of General Formula XXIX. ##STR29## wherein

R^(3b) is H or C₁ -C₆ alkyl optionally substituted with one or more F,Cl, Br or C₁ -C₃ alkoxy;

R^(5b) is H or C₁ -C₆ alkyl optionally substituted with one or morehalogen.

This reaction is carried out in a solvent such as xylene, toluene,1,2-dichlorobenzene, 1,3-dichlorobenzene or an anhydride of Formula(R^(3b) CO)₂ O with the reaction temperature ranging from 0° to 200° C.and the reaction time being between 10 minutes and 100 hours. One totwenty equivalents of the mesoionic oxazolone of General Formula XXVIIIis used per equivalent of the 1,2-propadienylsulfone of General FormulaXXIX.

Upon completion of the reaction, the reaction mixture is concentrated.The desired product is isolated from the residue by flash columnchromatography, recrystallization or other similar operation.

Scheme 23 illustrates the preparation of compounds of General Formula Ig(which are compounds of General Formula I where A is A-2, X is NR⁶ ; nis 2; R¹ is R^(1a) ; R² is defined as above; R³ is R^(3b) ; R⁴ is H, C₁-C₆ alkyl optionally substituted with one or more halogen, C₁ -C₆alkoxy, CN, CO₂ R⁷, S(O)_(m) R⁸, CONR⁹ R¹⁰, or SO₂ NR¹³ R¹⁴ ; C₃ -C₆cycloalkyl; C₁ -C₆ alkoxy; or phenyl or benzyl, each ring optionallysubstituted with 1 to 3 substituents selected from halogen, C₁ -C₃alkyl, C₁ -C₃ haloalkyl and C₁ -C₃ alkoxy) whereby a mesoionicoxazolones of General Formula XXVIII (which may be prepared in situ) isallowed to react with an alkynylsulfone of General Formula XXX.##STR30## wherein

R^(4c) is H, C₁ -C₆ alkyl optionally substituted with one or morehalogen, C₁ -C₆ alkoxy, CN, CO₂ R⁷, S(O)_(m) R⁸, C(O)NR⁹ R¹⁰ or SO₂ NR¹³R¹⁴, C₃ -C₆ cycloalkyl; C₁ -C₆ alkoxy; or phenyl or benzyl, each ringoptionally substituted with 1 to 3 substituents selected from halogen,C₁ -C₃ alkyl, C₁ -C₃ haloalkyl and C₁ -C₃ alkoxy.

This reaction is carried out in a solvent such as xylene, toluene,1,2-dichlorobenzene, 1.3-dichlorobenzene or an anhydride of Formula(R^(3b) CO)₂ O with the reaction temperature ranging from 0° to 200° C.and the reaction time being between 10 minutes and 100 hours. One totwenty equivalents of mesoionic oxazolone of General Formula XXVIII isused per equivalent of the alkynyl sulfone of General Formula XXX. Uponcompletion of the reaction, the reaction mixture is concentrated. Thedesired product is isolated from the residue by flash columnchromatography, recrystallization or other similar operation.

Scheme 24 illustrates the preparation of compounds of General Formula Ih(which are compounds of General Formula I where A is A-4, X is NR⁶, n is2; R¹ is R^(1a), R² is defined as above; R³ is R^(3b), R⁴ is R^(4a) ;R^(3b) and R⁶ may be taken together as --(CH₂)₃ -- or --(CH₂)₄ --whereby a sydnone of General Formula XXXI is allowed to react with a1,2-propadienylsulfone of General Formula XXIX. ##STR31## wherein

R^(3b) and R⁶ may be taken together as --(CH₂)₃ -- or --(CH₂)₄ --.

This reaction is carried out in a solvent such as xylene,1,2-dichlorobenzene. 1,3-dichlorobenzene, toluene, nitrobenzene,1,2-dimethoxyethane or N,N-dimethylformamide with the reactiontemperature ranging from 0° to 200° C. and the reaction time beingbetween 10 minutes and 100 hours. One to twenty equivalents of thesydnone of General Formula XXXI is used per equivalent of1,2-propaclienylsulfone of General Formula XXIX. Upon completion of thereaction, the reaction mixture is concentrated. The desired product isisolated from the residue by flash column chromatography,recrystallization or other similar operation.

Scheme 25 illustrates the preparation of compounds of General Formula Ii(which are compounds of General Formula I where A is A-4, X is NR⁶, n is2; R¹ is R^(1a), R² is defined as above, R³ is R^(3b), R⁴ is R^(4c),R^(3b) and R⁶ may be taken together as --(CH₂)₃ -- or --(CH₂)₄ --)whereby a sydnone of General Formula XXXI is allowed to react with analkynylsulfone of General Formula XXX. ##STR32## wherein

R^(3b) and R⁶ may be taken together as --(CH₂)₃ -- or --(CH₂)₄ --.

This reaction is carried out in a solvent such as xylene,1,2-dichlorobenzene, 1,3-dichlorobenzene, toluene, nitrobenzene,1,2-dimethoxyethane or N,N-dimethylformamide with the reactiontemperature ranging from 0° to 200° C. and the reaction time beingbetween 10 minutes and 100 hours. One to twenty equivalents of thesydnone of General Formula XXXI are used per equivalent ofalkynylsulfone of General Formula XXX.

The 1,2-propadienylsulfones of General Formula XXIX can be prepared byoxidizing the compounds of General Formula XXXII followed by treatmentof a base such as sodium bicarbonate aqueous solution sodium carbonateaqueous solution, triethylamine, 1,8-diazobicyclo 5.4.0!-undec-7-ene(DBU)or potassium t-butoxide as illustrated in Scheme 26. ##STR33##

The oxidizing reagents that can be used in the process of Scheme 26include 3-chloroperoxybenzoic acid, peracetic acid, trifluoroperaceticacid, and hydrogen peroxide. The oxidation is normally performed in asolvent and solvents that can be used will vary depending on the type ofoxidizing reagent used. For example, if the oxidizing reagent is3-chloroperoxybenzoic acid, benzene, methylene chloride, chloroform orother halogenated hydrocarbons can be used as solvent. If peracetic acidor trifluoroperacetic acid is used as the oxidizing reagent, halogenatedhydrocarbon or the corresponding acid can be used as solvent. If theoxidant is hydrogen peroxide, water, acetone, acetic acid or the likecan be used.

The reaction temperature range is normally 0° to 80° C. while thereaction time ranges from 10 minutes to 100 hours. In general, two tofive equivalents of oxidant are used per equivalent of the compound ofGeneral Formula XXXII. Upon completion of the reaction, methylsulfide orother reducing agents are added to destroy the unreacted oxidant.Additional organic solvent such as methylene chloride or chloroform wasthen added. The reaction mixture was then washed or treated with theabove mentioned base. The organic layer is dried and concentrated. Thecrude product is then purified by flash column chromatography oversilica gel.

Scheme 27 illustrates the preparation of compounds of General FormulaXXXII whereby the thiotriazole of General Formula XXXIII is allowed toreact with the carbamyl chloride of General Formula IIIa. ##STR34##

The reaction conditions for Scheme 27 are very similar to thosedescribed for Scheme 21 with the exception that XXXIII is used insteadof XXVII.

Scheme 28 illustrates the preparation of compounds of General FormulaXXXIII whereby a 2-propynyl halide of General Formula XXXIV (wherein Vis Cl or Br; R^(4b) is defined as above) is allowed to react with1,2,4-triazole-3-thiol. ##STR35##

The reaction conditions for Scheme 28 are very similar to thosedescribed for Scheme 14 with the exception that XXXIV is used instead ofXVIII.

The alkynylsulfones of General Formula XXX can be prepared by reactingthe 1-aminocarbonyltriazole-3-sulfonyl chlorides of General Formula XXIVwith a trimethylsilylalkyne of General Formula XXXV or an alkyne ofGeneral Formula XXXVI as depicted in Scheme 29. ##STR36##

The reaction conditions (including the catalysts which may be needed)for Scheme 29 are very similar to those reaction conditions for thesynthesis of alkynylsulfones taught by J. Dunogues et al., in J. Chem.Res. (S) 16 (1982) and K. Schank in The Chemistry of Sulfones andSulfoxide (edited by S. Patai et al.; published by John-WHey & Sons; pp.190-202) with the exception that XXIV is used instead of other sulfonylchlorides.

Compounds of General Formula XXXIV, XXXV and XXXVI are eithercommercially available or can be prepared by one skilled in the art.

The sydnones of General Formula XXXI can be prepared by one skilled inthe art using literature methods or slight modifications thereof.

Some examples of the above mentioned literature methods are:

F. H. C. Stewart, Chemical Reviews 64 129 (1964)

H. J. Tien et al., Bull. Chem. Soc. of Japan 45 2944 (1972)

C. V. Greco et al., J. Heterocycl. Chem.,3(3) 391 (1966)

The mesoiordc oxazolone of General Formula XXVIII can be prepared (insitu in most cases) by one skilled in the art using literature methodsof slight modifications thereof.

Some examples of the above mentioned literature methods are:

R. Huisgen et at., Chem. Ber. 103,2611 (I970)

M. T. Pizzomo et al., J. Org. Chem., 42(5) 909 (1977)

K. T. Potts et al., J. Org. Chem., 44(6) 977(1979)

The following are non-limiting examples illustrating the preparation ofcompounds of this invention Chemical shits in the proton nuclearmagnetic resonance (NMR) spectra are reported as parts per milliondownfield from the internal standard tetramethylsilanes. Melting pointsare uncorrected.

EXAMPLE 1 Preparation of 3-(4H-1,2,4-triazol-3-yl)thio!-2,4-pentanedione

Under N₂, 1.25 g of sodium was added to 100 ml of methanol. This mixturewas stirred at ambient temperature for 15 minutes and 5.7 g of1,2,4-triazole-3-thiol was then added. The reaction solution was thenstirred at ambient temperature for 45 minutes. To this reaction solutionwas then added 6.7 g of 3-chloro-2,4-pentanedione. The resulting mixturewas refluxed for ˜4 hours and was then concentrated under reducedpressure. The residue was stirred in water. The solid precipitated wascollected by filtration, washed with water, air dried, and then dried ina vacuum oven to give 3.53 g of the title product as a solid, m.p.114°-115° C. The aqueous filtrate was concentrated under reducedpressure to a smaller volume. The precipitate was collected byfiltration, air dried and then dried in a vacuum oven to give anadditional 3.35 g of the title product, m.p. 114°-115° C. NMR (CDCl₃):2.42 (s, 6H); 8.19 (s, 1H).

EXAMPLE 2 Preparation of 3-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)thio!-1H-1,2,4-triazole

Under N₂, 0.56 g of sodium was added to 100 ml of methanol. This mixturewas stirred at ambient temperature for 15 minutes and 2.8 g ofethylhydrazine oxalate was added. The reaction mixture was stirred atambient temperature for another 15 minutes. To the reaction solution wasthen added 2.5 g of 3- (4H-1,2,4-triazol-3-yl)thio!-2,4-pentanedione.

The resulting mixture was refluxed overnight and was then concentratedunder reduced pressure. The residue was dissolved in 200 ml of water andthe aqueous solution was extracted with methylene chloride (4×100 ml).The methylene chloride extracts were combined, dried over magnesiumsulfate and concentrated under reduced pressure to give 2 g of thetitled product as a solid, m.p. 127°-129° C. NMR (CDCl₃): 1.38 (t, 3H);2.24 (s, 3H); 2.32 (s, 3H); 4.04 (q, 2H); 7.98 (s, 1H).

EXAMPLE 3 Preparation of N,N-diethyl-3-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)thio!1H-1,2,4-triazole-1-carboxamide

To 34 ml of acetonitrile was added 1.1 g of 3-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)thio!-1H-1,2,4-triazole, 1.9 ml ofdiethylcarbamyl chloride and 2.2 ml of triethylamine. The resultingmixture was refluxed under nitrogen for 24 hours and was thenconcentrated under reduced pressure. To the residue was added 100 ml ofwater. The aqueous layer was then extracted with a solution of 150 ml ofdiethylether and 150 ml of hexane twice. The organic extracts were thencombined, dried over magnesium sulfate and concentrated under reducedpressure to give 1.2 g of the title product as a solid, m.p. 67°-69° C.NMR (CDCl₃): 1.18 (bt, 6H); 1.39 (t, 3H); 2.25 (s, 3H); 2.3 (s, 3H);3.64 (q, 4H); 4.05 (q, 2H); 8.69 (s, 1H).

EXAMPLE 4 Preparation of N,N-diethyl-3-(1-ethyl-3,5-dimethyl-1H-pyrazol-4-yl)sulfonyl!-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.82 g of N,N-diethyl-3 (1-ethyl-3,5-dimethyl-lH-pyrazol-4-yl)thio!-1H-1,2,4-triazole-1-carboxamide in 16 ml ofmethylene chloride at room temperature was added 2.8 g of3-chloroperoxybenzoic acid (50%-60% pure; from Aldrich Chemical Co.,Inc., Milwaukee, Wis.). The resulting mixture was stirred at roomtemperature for ˜58 hours. To this reaction mixture was then added 1.5ml of methylsulfide. The resulting mixture was stirred for another 5minutes and 100 ml of methylene chloride was added. The methylenechloride solution was then washed with dilute sodium bicarbonate aqueoussolution (3×150 ml), dried over magnesium sulfate and concentrated underreduced pressure .to give 0.5 g of the title product as a solid, m.p.90°-96° C. NMR (CDCl₃): 1.3 (t, 6H); 1.4 (t, 3H); 2.45 (s, 3H); 2.58 (s,3H); 3.6 (b, 4H); 4.03 (q, 2H); 8.8 (s, 1H).

EXAMPLE 5 Preparation of 3-(3,5-dimethyl-1-propyl-1H-pyrazol-4-yl)thio!-1H-1,2,4-triazole

Under N₂, 0.69 g of sodium was added to 100 ml of methanol. The mixturewas stirred at ambient temperature for 10 minutes and 3.4 g ofn-propylhydrazine oxalate was then added. The resulting mixture wasstirred at room temperature for another 15 minutes and 3 g of 3-(4H-1,2,4-triazol-3-yl)thio!-2,4-pentanedione was then added. Thereaction mixture was refluxed for 48 hours and was then concentratedunder reduced pressure. To the residue was added 200 ml of water and theaqueous layer was extracted with methylene chloride (4×100 ml). Themethylene chloride extracts were combined, dried over magnesium sulfateand concentrated under reduced pressure. The residue was triturated in10 ml of 1-chlorobutane. The precipitate was collected by filtration anddried in a vacuum oven to give 1.3 g of the title compound as a solid,m.p. 106°-108° C. NMR (CDCl₃): 0.9 (t, 3H); 1.8 (m, 2H); 2.24 (s, 3H);2.31 (s, 3H); 3.93 (t, 3H); 7.98 (s, 1H).

EXAMPLE 6 Preparation of 3-(3,5-dimethyl-1-propyl-1H-pyrazol-4-yl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 1.1 g of 3-(3,5-dimethyl1-propyl-1H-pyrazol-4-yl)thio!1H-1,2,4-triazole in 34 ml ofacetonitrile was added 1.9 ml of diethylcarbamyl chloride and then 2.2ml of triethylamine. The resulting mixture was refluxed under nitrogenfor 18 hours and was then concentrated under reduced pressure. To theresidue was added 100 ml of water. The aqueous layer was extracted witha solution of 150 ml of diethylether and 150 ml of hexane twice. Theorganic extracts were then combined, dried over magnesium sulfate andconcentrated under reduced pressure to give 1.15 g of the title productas a solid, m.p. 81°-83° C. NMR (CDCl₃): 0.93 (t, 3H); 1.2 (m, 6H); 1.82(m, 2H); 2.25 (s, 3H); 2.30 (s, 3H); 3.48 (q, 4H); 3.97 (t, 2H); 8.89(s, 1H).

EXAMPLE 7 Preparation of 3-(3,5-dimethyl-1-propyl-1H-pyrazol-4-yl)sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 1.1 g of 3-(3,5-dimethyl-1-propyl-1H-pyrazol-4-yl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamidein 24 ml of methylene chloride was added 3.8 g of 3-chloroperoxybenzoicacid (50-60% pure; from Aldrich Chemical Co., Inc.). The resultingmixture was stirred at room temperature overnight. To this reactionmixture was then added 1.5 ml of methylsulfide. The resulting mixturewas stirred for another 5 minutes and 100 ml of methylene chloride wasadded. The methylene chloride solution was then washed with dilutesodium bicarbonate aqueous solution (3×150 ml), dried over magnesiumsulfate and concentrated under reduced pressure to give 0.78 g of thetitle compound as an oil. NMR (CDCl₃): 0.92 (t, 3H); 1.29 (t, 6H); 1.8(m, 2H); 2.45 (s, 3H); 2.57 (s, 3H); 3.6 (m, 4H); 3.95 (t, 2H); 8.8 (s,1H).

EXAMPLE 8 Preparation of 3-(3,5-dimethyl-4-isoxazolyl)thio!-1H-1,2,4-triazole

Under nitrogen, 0.6 g of sodium was added to 50 ml of methanol. Thismixture was stirred at ambient temperature for 15 minutes and 2.4 g ofhydroxylamine hydrochloride was added. The resulting mixture was thenstirred for another hour. To it was added 3 g of 3-(4H-1,2,4-triazol-3-yl)thio!-2,4-pentanedione. The reaction mixture wasrefluxed for 2 weeks and then concentrated under reduced pressure. Theresidue was triturated in 300 ml of hexane which was then decanted away.The residue was then triturated in 150 ml of water. The precipitate wascollected by filtration to give 2.3 g of the title compound as a solid,m.p. 129°-131° C. NMR (CDCl₃): 2.28 (s, 3H); 2.5 (s, 3H); 8.15 (s, 1H).

EXAMPLE 9 Preparation of 3-(3,5-dimethyl-4-isoxazolyl)thio!-N,N-diethyl!-1H-1,2,4-triazole-1-carboxamide

To a solution of 1.2 g of 3-(3,5-dimethyl-4-isoxazolyl)thio!-1H-1,2,4-triazole in 34 ml ofacetonitrile was added 2.5 ml of diethylcarbamyl chloride and then 3 mlof triethylamine. The resulting mixture was refluxed under nitrogen for21 hours and was then concentrated. To the residue was added 100 ml ofwater. The aqueous layer was then extracted with a solution of 150 ml ofdiethylether and 150 ml of hexane twice. The organic extracts werecombined, dried over magnesium sulfate and concentrated under reducedpressure to give 1.15 g of the title compound as an oil. NMR (CDCl₃):1.2 (m, 6H); 2.27 (s, 3H); 2.48 (s, 3H); 3.48 (q, 4H); 8.72 (s, 1H).

EXAMPLE 10 Preparation of 3-(3,5-dimethyl-4-isoxazolyl)sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.7 g of 3-(3,5-dimethyl-4-isoxazolyl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamidein 16 ml of methylene chloride was added 2.8 g of 3-chloroperoxybenzoicacid (50-60% pure; from Aldrich Chemical Co., Inc.). The resultingmixture was stirred at room temperature for 14 hours. To this reactionmixture was then added 1.5 ml of methylsulfide. The resulting mixturewas stirred for another 5 minutes and 100 ml of methylene chloride wasadded. The methylene chloride solution was then washed with dilutesodium bicarbonate aqueous solution (3 ×150 ml), dried over magnesiumsulfate and concentrated under reduced pressure to give 0.58 g of thetitle compound as a solid, m.p. 108°-10° C. NMR (CDCl₃): 1.3 (t, 6H);2.49 (s, 3H); 2.76 (s, 3H); 3.6 (m, 4H); 8.86 (s, 1H).

EXAMPLE 11 Preparation of 1- 5 -chloro-2-(1H-1,2,4-triazol-3-yl)thio!3-thienyl!ethanone

To a solution of 4.5 g of 1,2,4-triazole-3-thiol in 100 mlN,N-dimethylformamide under N₂ was added 2 g of sodium hydride (60%dispersion in mineral oil). The resulting mixture was stirred at ambienttemperature for 15 minutes and 7.8 g of 3-acetyl-2,5-dichlorothiophenewas then added to it. The resulting mixture was heated at 90° C. for 2hours and was then concentrated under reduced pressure. To the residuewas added 100 ml of water. Aqueous hydrochloric acid (1 normal) was thenadded with stirring until the pH was 7. The precipitate was collected byfiltration, washed with water, air dried and dried in a vacuum oven togive 10.45 g of the title product as a solid, m.p. 187°-189° C. NMR(CDCl₃): 2.51 (s, 3H); 7.64 (s, 1H); 8.8 (s, 1H).

EXAMPLE 12 Preparation of 3-(3-acetyl-5-chloro-2-thienyl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 5.5 g of 1- 5-chloro-2-(1H-1,2,4-triazol-3-yl)thio!3-thienyl!ethanone in 75 ml of acetonitrilewas added 4.4 ml of diethylcarbamyl chloride and then 5.3 ml oftriethylamine. The resulting mixture was refluxed under nitrogenovernight and was then concentrated. The residue was stirred in 100 mlof water for 15 minutes. The precipitate was collected by filtration,washed with water and dried in a vacuum oven to give 6.8 g of the titleproduct as a solid, m.p. 103°-105° C. NMR (CDCl₃): 1.28 (t, 6H); 2.54(s, 3H); 3.6 (m, 4H); 7.24 (s, 1H); 8.87 (s, 1H).

EXAMPLE 13 Preparation of 3-(3-acetyl-5-chloro-2-thienyl)sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.98 g of 3-(3-acetyl-5-chloro-2-thienyl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamidein 21 ml of methylene chloride was added 3 g of 3-chloroperoxybenzoicacid (50-60% pure; from Aldrich Chemical Co., Inc.). The resultingmixture was stirred at ambient temperature for 20 hours and 1.5 ml ofmethylsulfide was then added. The reaction mixture was stirred formother 5 minutes and 100 ml of methylene chloride was then added. Themethylene chloride solution was washed with dilute sodium bicarbonateaqueous solution (3×150 ml), dried over magnesium sulfate andconcentrated under reduced pressure to give 0.79 g of the title productas a solid, m.p. 128°-130° C. NMR (CDCl₃): 1.29 (t, 6H); 2.52 (s,3 H);3.6 (b, 4H); 7.27 (s, 1H); 8.83 (s, 1H). IR (Nujol): 1700, 1328,1130cm⁻¹.

EXAMPLE 14 Preparation of methyl 3-oxo-2-(1H-1,2,4-triazol-3yl)thio!butanoate

Under nitrogen, 7 g of sodium was added to 300 ml of methanol. Thismixture was stirred at ambient temperature for 30 minutes and 30 g of1,2,4-triazol-3-thiol was then added. The reaction mixture was thenstirred at ambient temperature for 15 minutes. To this reaction mixturewith stirring was then added 50 ml of methyl 2-chloroacetoacetatedropwise. The resulting mixture was stirred at ambient temperature for 1hour and was then concentrated under reduced pressure. To the residuewas added 200 ml of water. The precipitate was collected by filtration,washed with 100 ml of water, air dried and then dried in oven to give50.5 g of the title compound as a solid. m.p. 63°-65° C. NMR (CDCl₃):2.39 (s, 3H); 3.75 (s, 3H); 8.14 (s, 1H); 13.7 (bs, 1H).

EXAMPLE 15 Preparation of 1,2-hydro-5-methyl-4-(1H-1,2,4-triazol-3-yl)thio!-2-(2.2.2-trifluoroethyl)-3H-pyrazol-3-one

To a solution of 4 g of methyl 3-oxo-2-(1H-1,2,4-triazol-3-yl)thio!butanoate in 100 ml of methanol was added2.8 ml of 2,2,2-trifluoroethylhydrazine. The resulting solution wasrefluxed under nitrogen for 20 hours and was then concentrated underreduced pressure. The residue was triturated in 200 ml of diethyletherfor ten minutes. The precipitate was collected by filtration, air driedand dried in oven to give a solid. This solid was then stirred in 400 mlof diethylether for 4 hours. The precipitate was then collected byfiltration, washed with diethylether and dried in oven to give 3 g ofthe title compound as a solid, m.p. 196°-200° C. NMR (DMSO-d₆): 2.02 (s,3H); 4.58 (q, 2H); 8.18 (s, 1H) with impurity peas.

EXAMPLE 16 Preparation of 3-5-chloro-3-methyl-1(2.2.2-trifluoroethyl)-1H-pyrazol-4yl)thio!-1H-1,2,4-triazole

To a heavy walled glass tube with a magnetic stirring bar and a screwteflon cap was added 40 ml of phosphorus oxychloride and then 2 g of1,2-dihydro-5-methyl-4-(1H-1,2,4-triazol-3-yl)thio!-2-(2,2,2-trifluoroethyl)-3H-pyrazol-3-one.The tube was purged with nitrogen and was then sealed with a teflon cap.The sealed glass tube was put into a silicon oil bath (˜2/3 of the tubewas under the oil surface) with the magnetic bar stirring. The oil bathwas heated at ˜160° C. for 5 hours and was then cooled down to roomtemperature. The resulting reaction mixture was then concentrated underreduced pressure. To the residue was added 40 ml of water. The resultingmixture was stirred for 10 minutes and was then extracted with methylenechloride (3×100 ml). The methylene chloride extracts were combined,dried over magnesium sulfate, and concentrated under reduced pressure togive 0.56 g of the title compound as a solid, m.p. 112°-114° C. NMR(CDCl₃): 2.31 (s, 3H); 4.7 (q, 2H); 8.13 (s, 1H).

EXAMPLE 17 Preparation of 3-5-chloro-3-methyl-1-(2.2.2-trifluoroethyl)-1H-pyrazol-4-yl!thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.56 g of 3-5-chloro-3-methyl-1-(2,2,2-trifluoroethyl)-1H-pyrazol-4-yl)thio!-1H-1,2,4-triazolein 21 ml of acetonitrile was added 1 ml of diethylcarbamyl chloride andthen 1.1 ml of methylmine. The resulting mixture was refluxed undernitrogen for 20 hours and was then concentrated under reduced pressure.To the residue was added 100 ml of water. The resulting mixture wasstirred at ambient temperature for 10 minutes. The precipitate wascollected by filtration, washed with water, air dried, and then dried inoven to give 0.64 g of the title product as a solid, m.p. 112°-114° C.NMR (CDCl₃): 1.15 (m, 6H); 2.3 (s, 3H); 3.48 (q, 4H); 4.72 (q, 2H); 8.73(s, 1H).

EXAMPLE 18 Preparation of 3-5-chloro-3-methyl-1-(2.2.2-trifluoroethyl)-1H-pyrazol-4-yl!-sulfonyl!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.6 g of 3-5-chloro-3-methyl-1-(2,2,2-trifluoroethyl)-1H-pyrazol-4-yl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamidein 16 ml of methylene chloride was added 2 g of 3-chloroperoxybenzoicacid (50-60% pure; from Aldrich Chemical Co., Inc.). The resultingmixture was stirred at ambient temperature for 20 hours. To thisreaction mixture was then added 1.5 ml of methylsulfide. The resultingmixture was stirred for another 5 minutes and 100 ml of methylenechloride was added. The methylene chloride solution was then washed withdilute sodium bicarbonate aqueous solution (3×150 ml), dried overmagnesium sulfate and concentrated under reduced pressure to give 0.44 gof the title compound as a solid, m.p. 103°-105° C. NMR (CDCl₃): 1.29(t, 6H); 2.53 (s, 3H); 3.6 (bs, 4H); 4.7 (q, 2H); 8.86 (s, 1H).

EXAMPLE 19 Preparation of 3-phenylmethyl!thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 3-benzylthio-1H-1,2,4-triazole (98.4 g, 0.52 mol) (U.S.Pat. No. 4,280,831) in pyridine (350 mL) was added dropwisediethylcarbamyl chloride (73.5 g, 0.54 mol) at ambient temperature. Thesolution was stirred overnight (ca. 16 h), then poured into excess water(1500 mL). The suspension was stirred until a precipitate formed, thenfiltered, and the residue was suction-dried overnight to provide thetitle compound (98.0 g) as a solid melting at 50°-55° C. IR (mineraloil): 1690 cm⁻¹ ; ¹ H-NMR (CDCl₃): δ1.25 (t, 6H), 3.6 (bs, 4H), 4.4 (s,2H), 7.2-7.4 (m, 5H), 8.75 (s, 1H).

EXAMPLE 20 Preparation of 1-(diethylamino)carbonyl-1H-1,2,4-triazole-3-sulfonyl chloride

To a solution of 40.0 g of 3-(phenylmethyl)thio!-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide inmethylene chloride (606 mL) was added water (318 mL), and the suspensionwas cooled with external cooling to about 0° to 5° C. Concentratedhydrochloric acid (41 mL) was added followed by dropwise addition ofClorox® (658 mL, active ingredient 5.25% sodium hypochlorite) whilemaintaining the reaction temperature at 0° to 5° C. with externalcooling and occasional addition of wet ice to the reaction suspension.After stirring at 0° to 5° C. for 1 h, the organic layer was separated,washed with saturated aqueous sodium bisulfite (150-175 mL ). then dried(MgSO₄) and concentrated in vacuo (25°-35° C.) to an oil. On standingovernight the oil partially crystallized. The suspension was slurriedwith hexane (75 mL), filtered and the residue suction-dried to providethe title compound as a solid (26.0 g). The solid was further purifiedby flash chromatography (silica gel with 1:1 hexane:ethyl acetate) toprovide the title compound (23.0 g), melting at 44°-47° C. IR (mineraloil): 1160, 1270-1290, 1720 cm⁻¹ ; ¹ H-NMR (CDCl₃): δ1.35 (t, 6H), 3.6(bs, 4H), 9.0 (s, 1H).

EXAMPLE 21 Preparation of 3-(3,5-diethyl-1H-pyrazol-1-yl)sulfonyl)-N,N-diethyl-1H-1,2,4-triazole-1-carboxamide

To a solution of 0.62 g of 3,5-diethyl-1H-pyrazole in 22 ml of anhydroustetrahydrofuran under nitrogen with stirring was added 0.62 g of 60%sodium hydride (dispersion in mineral oil; from Aldrich Chemical Co.,Inc.). The resulting mixture was stirred at ambient temperature for 1hour. To this mixture was then added 1.36 g of 1-(diethylamino)carbonyl!-1H-1,2,4-triazole-3-sulfonyl chloride. Theresulting mixture was stirred at ambient temperature for another 2 hoursand was then concentrated under reduced pressure. The residue was flashcolumn chromatographed (silica gel with 1:9 ethyl acetate/hexane and 1:2ethyl acetate/hexane as eluents) to provide 1.0 g of the title compoundas a solid, m.p. 70°-71° C. NMR (CDCl₃): 1.15-1.4 (m. 12H); 2.6 (q, 2H);3.03 (q, 2H); 3.6 (m, 4H); 6.1 (s, 1H); 8.82 (s, 1H).

EXAMPLE 22 Preparation of 3-(2-propynylthio)-1H-1,2,4-triazole

To a solution of 21.8 g of potassium hydroxide in 400 ml of methanolunder nitrogen was added 33.37 g of 1,2,4-triazole-3-thiol. Theresulting mixture was stirred at ambient temperature for ˜1 hour. Tothis mixture was added 33.4 ml of propargyl bromide dropwise whilekeeping the reaction temperature below 30° C. After the addition, theresulting mixture was stirred at ambient temperature for ˜4 hours andwas then concentrated under reduced pressure. The residue was trituratedin 300 ml of water. The precipitate was collected by filtration, washedwith water and then hexanes, air dried and then dried in oven to give24.6 g of the title product as a solid, m.p. 102°-104° C. NMR (DMSO-d6):3.14 (t, 1H); 3.92 (d, 2H); 8.48 (s, 1H); 14.2 (bs, 1H).

EXAMPLE 23 Preparation ofN,N-diethyl-3-(2-propynylthio)-1H-1,2,4-triazol-1-carboxamide

To 31.5 ml of pyridine was added 5.56 g of3-(2-propynylthio)-1H-1,2,4-triazole and then 6.3 ml of diethylcarbamylchloride. The resulting mixture was stirred under nitrogen at ambienttemperature for 3 days and was then poured into 350 ml of cold waterwith agitation. The precipitate was collected by filtration, washed withwater air dried and then dried in oven to give 8.1 g of the titlecompound as a solid. m.p. 67°-69° C. NMR (CDCl₃): 1.3 (t, 6H); 2,21 (t.1H); 3.62 (m, 4H); 3.88 (d, 2H); 8.78 (s, 1H).

EXAMPLE 24 Preparation ofN,N-diethyl-3-(1,2-propadienylsulfonyl)-1H-1,2,4-triazole-1-carboxamide

To a solution of 2 g ofN,N-diethyl-3-(2-propynylthio)-1H-1,2,4-triazole-1-carboxamide in 40 mlof methylene chloride was added 10 g of 3-chloroperoxybenzoic acid(50-60%; from Aldrich Chemical Co., Inc.). The resulting mixture wasstirred at ambient temperature for 22 hours. To this reaction mixturewas then added 3 ml of methylsulfide. The resulting mixture was stirredfor mother 15 minutes and 50 ml of methylene chloride was added. Themethylene chloride solution was then washed with 5% sodium bicarbonateaqueous solution (3×150 ml), dried over magnesium sulfate andconcentrated under reduced pressure. The residue was then flash columnchromatographed (silica gel with 1:2 ethyl acetate/hexanes as eluent) toprovide 1.87 g of the title compound as a solid, m.p. 98°-100° C. NMR(CDCl₃): 1.32 (t, 6H); 3.6 (m, 4H); 5.62 (d, 2H); 6.46 (t, 1H); 8.89 (s,1H). IR (neat): 1966 cm⁻¹, 1712 cm⁻¹, 1334 cm⁻¹, 1140 cm⁻¹.

EXAMPLE 25 Preparation of N,N-diethyl-3-(1,2,4-trimethyl-1H-pyrrol-3-yl)-sulfonyl!-1H-1,2,4-triazole-1-carboxamide

To 20 ml of acetic anhydride was added 0.9 g of sarcosin. The resultingmixture as heated under nitrogen to 98° C. and was stirred at 98° C. for10 minutes. To this reaction solution at 98° C. was then added asolution of 0.6 g ofN,N-diethyl-3-(1,2-propadienylsulfonyl)-1H-1,2,4-triazole-1-carboxamidein 5 ml of methylene chloride dropwise. The resulting mixture was thenheated to 110° C. and was stirred at 110° C. for 1.5 hours. The reactionmixture was then concentrated under reduced pressure. The residue wasthen purified by flash column chromatography twice (silica gel with 2:3ethyl acetate/hexane as eluent were employed for the first flash columnchromatography; silica gel with 2%, 4%, 6%, 8% and 10% ether inmethylene chloride as eluents were employed for the second flash columnchromatography) to provide 0.308 g of the title compound as an oil. NMR(CDCl₃): 1.3 (m, 6H); 2.23 (s, 3H); 2.53 (s, 3H); 3.48 (s, 3H); 3.6 (m,4H); 6.32 (s, 1H): 8.78 (s, 1H).

By the general procedures described in Schemes 1-29 and Examples 1-25 orby obvious modifications thereof one skilled in the art can prepare thecompounds of Tables 1-20.

                  TABLES 1-20    ______________________________________    The following tables pertain to compounds of Formula I:     ##STR37##    ______________________________________    wherein A is     ##STR38##     ##STR39##     ##STR40##     ##STR41##     ##STR42##     ##STR43##     ##STR44##    ______________________________________

In the following tables, each page or section is read in the order ofthe columns to the left of the vertical dividing line, in theirentirety, followed by the columns to the fight of the line, and thenfollowed again by the columns to the left of the line on the next pageor section.

                  TABLE 1    ______________________________________    A = A-1; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            H    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           H    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-1; X = O; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR45##                        ##STR46##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR47##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR48##   H    2           ##STR49##                        ##STR50##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-1; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     C(O)CH.sub.3 H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    0     C(O)CH.sub.3 H            Cl    ______________________________________    A = A-1; X = S; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR51##                        ##STR52##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR53##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR54##   H    2           ##STR55##                        ##STR56##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-1; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(CH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            C    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-1; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR57##                        ##STR58##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR59##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR60##   H    2           ##STR61##                        ##STR62##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    2     CH.sub.3     CH.sub.3     H    ______________________________________    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-1; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR63##                        ##STR64##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR65##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR66##   H    2           ##STR67##                        ##STR68##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-1; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-1; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR69##                        ##STR70##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR71##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR72##   H    2           ##STR73##                        ##STR74##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________

                  TABLE 2    ______________________________________    A = A-2; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-2; X = O; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR75##                        ##STR76##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR77##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR78##   H    2           ##STR79##                        ##STR80##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          H    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-2; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    H    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    H    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    H    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-2; X = S; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR81##                        ##STR82##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR83##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR84##   H    2           ##STR85##                        ##STR86##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-2; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(CH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-2; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR87##                        ##STR88##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR89##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR90##   H    2           ##STR91##                        ##STR92##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    0     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-2; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    H    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    H    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-2; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR93##                        ##STR94##   H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR95##   C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR96##   H    2           ##STR97##                        ##STR98##   H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          H    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________    A = A-2; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    0     CH.sub.3     CH.sub.3     H    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    1     CH.sub.3     CH.sub.3     H    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       H            H    2     CH(CH.sub.3).sub.2                       H            CH.sub.3    2     CH(CH.sub.3).sub.2                       H            C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-2; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR99##                        ##STR100##  H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR101##  C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR102##  H    2           ##STR103##                        ##STR104##  H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          H    0     CH.sub.3     CH.sub.3     H    1     CH.sub.3     CH.sub.3     H    ______________________________________

                  TABLE 3    ______________________________________    A = A-3; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-3; X = O; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR105##                               ##STR106##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR107##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR108##    2               ##STR109##                               ##STR110##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-3; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-3; X = S; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR111##                               ##STR112##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR113##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR114##    2               ##STR115##                               ##STR116##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-3; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         CHF.sub.2       CH.sub.3    2         CHF.sub.2       C.sub.2 H.sub.5    2         CHF.sub.2       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 Br     CH.sub.3    2         CH.sub.2 OCH.sub.3                              CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-3; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR117##                               ##STR118##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR119##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR120##    2               ##STR121##                               ##STR122##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-3; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    2         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    2         CHF.sub.2       CH.sub.3    2         CHF.sub.2       C.sub.2 H.sub.5    2         CHF.sub.2       CH.sub.2 CH.sub.2 CH.sub.3    ______________________________________    A = A-3; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    2         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR123##                               ##STR124##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR125##               ##STR126##                               ##STR127##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-3; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CHF.sub.2       CH.sub.3    2         CHF.sub.2       C.sub.2 H.sub.5    2         CHF.sub.2       CH.sub.2 CH.sub.2 CH.sub.3    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-3; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 =    CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR128##                               ##STR129##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR130##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR131##    2               ##STR132##                               ##STR133##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________

                  TABLE 4    ______________________________________    A = A-4; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = O; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR134##                               ##STR135##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR136##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR137##    2               ##STR138##                               ##STR139##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = S; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR140##                               ##STR141##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR142##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR143##    2               ##STR144##                               ##STR145##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR146##                               ##STR147##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR148##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR149##    2               ##STR150##                               ##STR151##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        H    1         Cl              H    1         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR152##                               ##STR153##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR154##    2               ##STR155##                               ##STR156##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    0         CH.sub.3        CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    0         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 H.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR157##                               ##STR158##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR159##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR160##    2               ##STR161##                               ##STR162##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NC.sub.6 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NC.sub.6 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR163##                               ##STR164##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR165##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR166##    2               ##STR167##                               ##STR168##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CF.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    0         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 CF.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4    = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR169##                               ##STR170##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR171##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR172##    2               ##STR173##                               ##STR174##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CO.sub.2 C.sub.2 H.sub.5 ; R.sup.1 = C.sub.2    H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 CO.sub.2 C.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR175##                               ##STR176##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR177##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR178##    2               ##STR179##                               ##STR180##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CN; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CN; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR181##                               ##STR182##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR183##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR184##    2               ##STR185##                               ##STR186##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NC(O)N(C.sub.2 H.sub.5).sub.2 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    0         CH.sub.3        CH.sub.3    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    0         CH.sub.3        CH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NC(O)N(C.sub.2 H.sub.5).sub.2 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR187##                               ##STR188##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR189##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR190##    2               ##STR191##                               ##STR192##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2    H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    0         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR193##                               ##STR194##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR195##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.4                              C.sub.2 H.sub.5    2         H                               ##STR196##    2               ##STR197##                               ##STR198##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CH(CH.sub.3).sub.2 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 CH(CH.sub.3).sub.2 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR199##                               ##STR200##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR201##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR202##    2               ##STR203##                               ##STR204##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 C.sub.6 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NCH.sub.2 C.sub.6 H.sub.5 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR205##                               ##STR206##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR207##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.4                              C.sub.2 H.sub.5    2         H                               ##STR208##    2               ##STR209##                               ##STR210##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NH; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        CH.sub.3    1         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NH; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR211##                               ##STR212##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR213##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR214##    2               ##STR215##                               ##STR216##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-4; X = NCH.sub.2 CH(CH.sub.3).sub.2 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    ______________________________________     ##STR217##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    0         CH.sub.3        H    0         Cl              H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-4; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR218##                               ##STR219##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR220##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR221##    2               ##STR222##                               ##STR223##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         H               CH.sub.3    0         CH.sub.3        CH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n                R.sup.6    ______________________________________                      ##STR224##    2                      ##STR225##    2                      ##STR226##    2                      ##STR227##    2                      ##STR228##    2                      ##STR229##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = C.sub.2 H.sub.5 ; R.sup.4 = C.sub.2 H.sub.5    n                R.sup.6    ______________________________________                      ##STR230##    2                      ##STR231##    2                      ##STR232##    2                      ##STR233##    2                      ##STR234##    2                      ##STR235##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = C.sub.2 H.sub.5 ; R.sup.4 = CH.sub.3    n                R.sup.6    ______________________________________                      ##STR236##    2                      ##STR237##    2                      ##STR238##    2                      ##STR239##    2                      ##STR240##    2                      ##STR241##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = CH.sub.3 ; R.sup.4 = C.sub.2 H.sub.5    n                R.sup.6    ______________________________________                      ##STR242##    2                      ##STR243##    2                      ##STR244##    2                      ##STR245##    2                      ##STR246##    2                      ##STR247##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5, R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = Cl; R.sup.4 = CH.sub.3    n                R.sup.6    ______________________________________                      ##STR248##    2                      ##STR249##    2                      ##STR250##    2                      ##STR251##    2                      ##STR252##    2                      ##STR253##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NR.sup.6 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5 ;    R.sup.3 = Cl; R.sup.4 = Cl    n                R.sup.6    ______________________________________                      ##STR254##    2                      ##STR255##    2                      ##STR256##    2                      ##STR257##    2                      ##STR258##    2                      ##STR259##    2                CH.sub.2 CH.sub.2 Cl    2                CH.sub.2 CH.sub.2 Br    2                CH.sub.2 CHCH.sub.2    2                CHCH.sub.2    2                CH.sub.2 CH.sub.2 OCH.sub.3    ______________________________________    A = A-4; X = NCH.sub.3 ; R.sup.1 and    R.sup.2 = CH(CH.sub.3)CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2    n         R.sup.3         R.sup.4    ______________________________________    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       Cl    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    ______________________________________    A = A-4; X = NC.sub.2 H.sub.5 ; R.sup.1 and    R.sup.2 = CH(CH.sub.3)CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2    n         R.sup.3         R.sup.4    ______________________________________    2         CH.sub.3        CH.sub.3    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    ______________________________________    A = A-4; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 and    R.sup.2 = CH(CH.sub.3)CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2    n         R.sup.3         R.sup.4    ______________________________________    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    ______________________________________    A = A-4; X = NCH.sub.2 CF.sub.3 ; R.sup.1 and    R.sup.2 = CH(CH.sub.3)CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2    n         R.sup.3         R.sup.4    ______________________________________    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    ______________________________________     ##STR260##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        CH.sub.3    1         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3        H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    ______________________________________     ##STR261##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         Cl              Cl    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH.sub.3        Cl    2         Cl              CH.sub.3    ______________________________________     ##STR262##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    1         CH.sub.3        H    1         Cl              H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    ______________________________________     ##STR263##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    1         CH.sub.3        CH.sub.3    1         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         CH.sub.3        H    1         Cl              H    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    ______________________________________     ##STR264##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               Cl    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       Cl    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         CH.sub.3        CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________     ##STR265##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         CH.sub.3        CH.sub.3    1         Cl              CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    ______________________________________     ##STR266##    R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         CH.sub.3        CH.sub.3    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH.sub.3        Cl    2         Cl              CH.sub.3    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    1         CH.sub.3        CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    ______________________________________

                  TABLE 5    ______________________________________    A = A-5; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-5; X = O; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR267##                               ##STR268##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR269##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR270##    2               ##STR271##                               ##STR272##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-5; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-5; X = S; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR273##                               ##STR274##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR275##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR276##    2               ##STR277##                               ##STR278##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-5; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-5; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR279##                               ##STR280##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR281##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR282##    2               ##STR283##                               ##STR284##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-5; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-5; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR285##                               ##STR286##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR287##    2               ##STR288##                               ##STR289##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-5; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-5; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR290##                               ##STR291##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR292##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR293##    2               ##STR294##                               ##STR295##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________

                  TABLE 6    ______________________________________    A = A-6; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.4         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-6; X = O; R.sup.4 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR296##                               ##STR297##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR298##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR299##    2               ##STR300##                               ##STR301##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-6; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.4         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-6; X = S; R.sup.4 = CH.sub.5 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR302##                               ##STR303##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR304##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR305##    2               ##STR306##                               ##STR307##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-6; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.4         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-6; X = NCH.sub.3 ; R.sup.4 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR308##                               ##STR309##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR310##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR311##    2               ##STR312##                               ##STR313##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-6; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.4         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-6; X = NC.sub.2 H.sub.5 ; R.sup.4 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR314##                               ##STR315##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR316##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR317##    2               ##STR318##                               ##STR319##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-6; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.4         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-6; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.4 = CH.sub.3 ;    R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR320##                               ##STR321##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR322##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR323##    2               ##STR324##                               ##STR325##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________

                  TABLE 7    ______________________________________    A = A-7; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-7; X = O; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH   CH.sub.2 CHCH.sub.2               ##STR326##                               ##STR327##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR328##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR329##    2               ##STR330##                               ##STR331##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-7; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-7; X = S; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR332##                               ##STR333##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR334##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR335##    2               ##STR336##                               ##STR337##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-7; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CHF.sub.2    1         Cl              CHF.sub.2    2         CHF.sub.2       CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-7; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR338##                               ##STR339##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR340##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR341##    2               ##STR342##                               ##STR343##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-7; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-7; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR344##                               ##STR345##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR346##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR347##    2               ##STR348##                               ##STR349##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-7; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-7; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR350##                               ##STR351##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR352##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR353##    2               ##STR354##                               ##STR355##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________

                  TABLE 8    ______________________________________    A = A-8; X = O; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-8; X = O; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR356##                               ##STR357##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR358##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR359##    2               ##STR360##                               ##STR361##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-8; X = S; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-8; X = S; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR362##                               ##STR363##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR364##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR365##    2               ##STR366##                               ##STR367##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-8; X = NCH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2    H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-8; X = NCH.sub.3 ; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR368##                               ##STR369##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR370##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR371##    2               ##STR372##                               ##STR373##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-8; X = NC.sub.2 H.sub.5 ; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 =    C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-8; X = NC.sub.2 H.sub.5 ; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR374##                               ##STR375##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR376##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR377##    2               ##STR378##                               ##STR379##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________    A = A-8; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.1 = C.sub.2 H.sub.5 ;    R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    0         CH.sub.3        H    1         CH.sub.3        H    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.3    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-8; X = NCH.sub.2 CH.sub.2 CH.sub.3 ; R.sup.3 = CH.sub.3 ;    R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR380##                               ##STR381##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5              (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR382##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR383##    2               ##STR384##                               ##STR385##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    0         H               CH.sub.3    1         H               CH.sub.3    ______________________________________

                  TABLE 9    ______________________________________    A = A-9; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 10    ______________________________________    A = A-10; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 11    ______________________________________    A = A-11; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 12    ______________________________________    A = A-12; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.5        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 13    ______________________________________    A = A-13; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.5        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 14    ______________________________________    A = A-14; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.5        X    ______________________________________    2         H              O    2         H              S    2         H              NCH.sub.3    2         H              NC.sub.2 H.sub.5    2         H              NCH.sub.2 CH.sub.2 CH.sub.3    2         Cl             O    2         Cl             S    2         Cl             NCH.sub.3    2         Cl             NC.sub.2 H.sub.5    2         Cl             NCH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3      O    2         OCH.sub.3      S    2         OCH.sub.3      NCH.sub.3    2         OCH.sub.3      NC.sub.2 H.sub.5    2         OCH.sub.3      NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3       O    2         CH.sub.3       S    2         CH.sub.3       NCH.sub.3    2         CH.sub.3       NC.sub.2 H.sub.5    2         CH.sub.3       NCH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5                             O    2         C.sub.2 H.sub.5                             S    2         C.sub.2 H.sub.5                             NCH.sub.3    2         C.sub.2 H.sub.5                             NC.sub.2 H.sub.5    2         C.sub.2 H.sub.5                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                             O    2         CH(CH.sub.3).sub.2                             S    2         CH(CH.sub.3).sub.2                             NCH.sub.3    2         CH(CH.sub.3).sub.2                             NC.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                             NCH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             O    2         CH.sub.2 CH.sub.2 CH.sub.3                             S    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                             NC.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                             NCH.sub.2 CH.sub.2 CH.sub.3    0         CH.sub.3       NCH.sub.3    1         CH.sub.3       NCH.sub.3    ______________________________________

                  TABLE 15    ______________________________________    A = A-15; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    H    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    H    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    H    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    H    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       H            CH.sub.3    2     CH(CH.sub.3).sub.2                       H            C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     COCH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     CH.sub.3     CF.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     SCH.sub.3    CH.sub.3     H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-15; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR386##                        ##STR387##  H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR388##  C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR389##  H    2           ##STR390##                        ##STR391##  H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    ______________________________________

                  TABLE 16    ______________________________________    A = A-16; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           H            H    2     Cl           H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    H    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    H    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    H    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    H    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       H            H    2     CH(CH.sub.3).sub.2                       H            CH.sub.3    2     CH(CH.sub.3).sub.2                       H            C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           H    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    H    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     H    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    H    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            H    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           H    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-16; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR392##                        ##STR393##  H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR394##  C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR395##  H    2           ##STR396##                        ##STR397##  H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    ______________________________________

                  TABLE 17    ______________________________________    A = A-17; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n     R.sup.3      R.sup.4      R.sup.5    ______________________________________    2     H            H            H    2     H            I            H    2     H            H            CH.sub.3    2     H            H            C.sub.2 H.sub.5    2     H            H            CH.sub.2 CH.sub.2 CH.sub.3    2     H            Cl           H    2     H            Cl           CH.sub.3    2     H            Cl           C.sub.2 H.sub.5    2     H            Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     H            OCH.sub.3    H    2     H            OCH.sub.3    CH.sub.3    2     H            OCH.sub.3    C.sub.2 H.sub.5    2     H            OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.3     H    2     H            CH.sub.3     CH.sub.3    2     H            CH.sub.3     C.sub.2 H.sub.5    2     H            CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     H            C.sub.2 H.sub.5                                    H    2     H            C.sub.2 H.sub.5                                    CH.sub.3    2     H            C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     H            C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    H    2     H            CH(CH.sub.3).sub.2                                    CH.sub.3    2     H            CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     H            CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           H            H    2     Cl           H            CH.sub.3    2     CF.sub.3     H            CH.sub.3    2     Cl           H            C.sub.2 H.sub.5    2     CF.sub.3     H            C.sub.2 H.sub.5    2     Cl           H            CH.sub.2 CH.sub.2 CH.sub.3    2     CF.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           Cl           H    2     Cl           Cl           CH.sub.3    2     CF.sub.3     CF.sub.3     CH.sub.3    2     Cl           Cl           C.sub.2 H.sub.5    2     CF.sub.3     CF.sub.3     C.sub.2 H.sub.5    2     Cl           Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CF.sub.3     CF.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           OCH.sub.3    H    2     Cl           OCH.sub.3    CH.sub.3    2     Cl           OCH.sub.3    C.sub.2 H.sub.5    2     Cl           OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     Cl           CH.sub.3     CH.sub.3    2     CF.sub.3     CH.sub.3     CH.sub.3    2     Cl           CH.sub.3     C.sub.2 H.sub.5    2     CF.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     Cl           CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CF.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    H    2     CF.sub.3     C.sub.2 H.sub.5                                    H    2     Cl           C.sub.2 H.sub.5                                    CH.sub.3    2     Cl           C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     Cl           C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    H    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.3    2     Cl           CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     Cl           CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.3     H            CF.sub.3    2     CH.sub.3     Cl           CF.sub.3    2     CH.sub.3     Br           CF.sub.3    2     CH.sub.3     CH.sub.3     CF.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    CF.sub.3    2     CF.sub.3     H            CF.sub.3    2     CF.sub.3     Cl           CF.sub.3    2     CF.sub.3     Br           CF.sub.3    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     Cl           CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    H            H    2     OCH.sub.3    H            CH.sub.3    2     OCH.sub.3    H            C.sub.2 H.sub.5    2     OCH.sub.3    H            CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    Cl           H    2     OCH.sub.3    Cl           CH.sub.3    2     OCH.sub.3    Cl           C.sub.2 H.sub.5    2     OCH.sub.3    Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    OCH.sub.3    H    2     OCH.sub.3    OCH.sub.3    CH.sub.3    2     OCH.sub.3    OCH.sub.3    C.sub.2 H.sub.5    2     OCH.sub.3    OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    CH.sub.3     CH.sub.3    2     OCH.sub.3    CH.sub.3     C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.3    2     OCH.sub.3    C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     OCH.sub.3    C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    H    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.3    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            H    2     CH.sub.3     H            CH.sub.3    2     CH.sub.3     Br           CH.sub.3    2     CH.sub.3     H            C.sub.2 H.sub.5    2     CH.sub.3     H                                     ##STR398##    2     CH.sub.3     H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl           H    2     CH.sub.3     Cl           CH.sub.3    2     CH.sub.3     Br           C.sub.2 H.sub.5    2     CH.sub.3     Cl           C.sub.2 H.sub.5    2     CH.sub.3     Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     Cl                                     ##STR399##    2     CH.sub.3     OCH.sub.3    H    2     CH.sub.3     Br                                     ##STR400##    2     CH.sub.3     OCH.sub.3    CH.sub.3    2     CH.sub.3     OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.3     OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     H    2     CH.sub.3     CH.sub.3     CH.sub.3    2     CH.sub.3     CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    H    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.3     C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.3     C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            CH.sub.2 CH(CH.sub.3).sub.2    2     CH.sub.3     H            CH(CH3).sub.2    2     CH.sub.3     CH(CH.sub.3).sub.2                                    H    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.3     CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.3     CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     H            C.sub.6 H.sub.5    2     CH.sub.3     Br           C.sub.6 H.sub.5    2     CH.sub.3     Cl           C.sub.6 H.sub.5    2     CH.sub.3     H            CH(CH.sub.3).sub.2    2     CH.sub.3     Br           CH(CH.sub.3).sub.2    2     CH.sub.3     Cl           CH(CH.sub.3).sub.2    2     C.sub.6 H.sub.5                       H            CH.sub.3    2     C.sub.6 H.sub.5                       Cl           CH.sub.3    2     C.sub.6 H.sub.5                       Br           CH.sub.3    2     C.sub.2 H.sub.5                       H            H    2     C.sub.2 H.sub.5                       H            CH.sub.3    2     C.sub.2 H.sub.5                       H            C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       Cl           H    2     C.sub.2 H.sub.5                       Cl           CH.sub.3    2     C.sub.2 H.sub.5                       Cl           C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    H    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.3    2     C.sub.2 H.sub.5                       OCH.sub.3    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.3     C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.3    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    H    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     C.sub.2 H.sub.5                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       H            H           ##STR401##  Br           CH.sub.3    2     CH(CH.sub.3).sub.2                       H            CH.sub.3    2           ##STR402##  H            CH.sub.3    2     CH(CH.sub.3).sub.2                       H            C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           H    2     CH(CH.sub.3).sub.2                       Br           CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.3    2           ##STR403##  Cl           CH.sub.3    2     CH(CH.sub.3).sub.2                       Cl           C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    H    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.3    2     CH(CH.sub.3).sub.2                       OCH.sub.3    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     H    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.3     C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    H    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH(CH.sub.3).sub.2                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            H    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       H            CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           H    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       Cl           CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       OCH.sub.3    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH(CH.sub.3).sub.2                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    C.sub.2 H.sub.5    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.2 CH.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     Cl    2     CH.sub.3     CH.sub.3     OCH.sub.3    2     CH.sub.3     CH.sub.3     F    2     CH.sub.3     CH.sub.3     Br    2     CH.sub.3     CH.sub.3     CO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     CO.sub.2 C.sub.2 H.sub.5    2     CH.sub.3     CH.sub.3     CH.sub.2 OCH.sub.3    2     CH.sub.3     CH.sub.3     CON(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     SCH.sub.3    2     CH.sub.3     CH.sub.3     SO.sub.2 CH.sub.3    2     CH.sub.3     CH.sub.3     NO.sub.2    2     CH.sub.3     CH.sub.3     N(CH.sub.3).sub.2    2     CH.sub.3     CH.sub.3     NH.sub.2    2     CH.sub.3     CH.sub.3     C.sub.6 H.sub.5    2     CH.sub.3     C.sub.6 H.sub.5                                    H    2     C.sub.6 H.sub.5                       CH.sub.3     H    2     CH.sub.3     CF.sub.3     H    2     CF.sub.3     CH.sub.3     H    2     COCH.sub.3   H            H    2     CHCH.sub.2   CH.sub.3     H    2     CH.sub.3     CHCH.sub.2   H    2     SCH.sub.3    CH.sub.3     H    2     CH.sub.3     SCH.sub.3    H    2     NO.sub.2     CH.sub.3     H    2     NH.sub.2     CH.sub.3     H    2     CHO          CH.sub.3     H    2     CO.sub.2 CH.sub.3                       H            H    2     CH(OCH.sub.3).sub.2                       H            H    2     COCH.sub.3   H            Cl    2     C.sub.2 H.sub.5                       H            Cl    2     CO.sub.2 CH.sub.3                       H            Cl    ______________________________________    A = A-17; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n     R.sup.1      R.sup.2      R.sup.5    ______________________________________    2     CH.sub.3     CH.sub.3     H    2     C.sub.2 H.sub.5                       CH.sub.3     H    2     H            CH.sub.3     H    2     H            C.sub.2 H.sub.5                                    H    2     H            CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     OCH.sub.3    CH.sub.3     H    2     OCH.sub.3    C.sub.2 H.sub.5                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    H    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    H           ##STR404##                        ##STR405##  H    2     CH(CH.sub.3).sub.2                       CH(CH.sub.3).sub.2                                    H    2     (CH.sub.2).sub.5          H    2     (CH.sub.2).sub.4          H    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    H    2           ##STR406##  C.sub.2 H.sub.5                                    H    2     OC.sub.2 H.sub.5                       CH.sub.3     H    2     OC.sub.2 H.sub.5                       C.sub.2 H.sub.5                                    H    2     H                        ##STR407##  H    2           ##STR408##                        ##STR409##  H    2     H            CH.sub.2 CHCH.sub.2                                    H    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.3     H    2     CH.sub.2 CHCH.sub.2                       CH.sub.3     CH.sub.3    2     CH.sub.2 CHCH.sub.2                       C.sub.2 H.sub.5                                    CH.sub.3    2     CH.sub.2 CHCH.sub.2                       CH.sub.2 CHCH.sub.2                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       CH.sub.2 CH.sub.2 CH.sub.3                                    CH.sub.3    2     CH.sub.2 CH.sub.2 CH.sub.3                       C.sub.2 H.sub.5                                    CH.sub.3    2     (CH.sub.2).sub.5          CH.sub.3    ______________________________________

                  TABLE 18    ______________________________________    A = A-18; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.4    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         CH.sub.3        CF.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         SCH.sub.3       CH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-18; R.sup.3 = CH.sub.3 ; R.sup.4 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR410##                               ##STR411##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR412##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR413##    2               ##STR414##                               ##STR415##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    ______________________________________

                  TABLE 19    ______________________________________    A = A-19; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-19; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR416##                               ##STR417##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR418##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR419##    2               ##STR420##                               ##STR421##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    ______________________________________

                  TABLE 20    ______________________________________    A = A-20; R.sup.1 = C.sub.2 H.sub.5 ; R.sup.2 = C.sub.2 H.sub.5    n         R.sup.3         R.sup.5    ______________________________________    2         H               H    2         H               Cl    2         H               OCH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH(CH.sub.3).sub.2    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         Cl              H    2         Cl              Cl    2         Cl              OCH.sub.3    2         Cl              CH.sub.3    2         Cl              C.sub.2 H.sub.5    2         Cl              CH(CH.sub.3).sub.2    2         Cl              CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       H    2         OCH.sub.3       Cl    2         OCH.sub.3       OCH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         OCH.sub.3       CH(CH.sub.3).sub.2    2         OCH.sub.3       CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        H    2         CH.sub.3        Cl    2         CH.sub.3        OCH.sub.3    2         CH.sub.3        CH.sub.3    2         CH.sub.3        C.sub.2 H.sub.5    2         CH.sub.3        CH(CH.sub.3).sub.2    2         CH.sub.3        CH.sub.2 CH.sub.2 CH.sub.3    2         C.sub.2 H.sub.5 H    2         C.sub.2 H.sub.5 Cl    2         C.sub.2 H.sub.5 OCH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         C.sub.2 H.sub.5 C.sub.2 H.sub.5    2         C.sub.2 H.sub.5 CH(CH.sub.3).sub.2    2         C.sub.2 H.sub.5 CH.sub.2 CH.sub.2 CH.sub.3    2         CH(CH.sub.3).sub.2                              H    2         CH(CH.sub.3).sub.2                              Cl    2         CH(CH.sub.3).sub.2                              OCH.sub.3    2         CH(CH.sub.3).sub.2                              CH.sub.3    2         CH(CH.sub.3).sub.2                              C.sub.2 H.sub.5    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         CH(CH.sub.3).sub.2                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              H    2         CH.sub.2 CH.sub.2 CH.sub.3                              Cl    2         CH.sub.2 CH.sub.2 CH.sub.3                              OCH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    2         CH.sub.2 CH.sub.2 CH.sub.3                              C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH(CH.sub.3).sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.3        C.sub.6 H.sub.5    2         C.sub.6 H.sub.5 CH.sub.3    2         CH.sub.3        CF.sub.3    2         CF.sub.3        CH.sub.3    2         COCH.sub.3      H    2         CHCH.sub.2      CH.sub.3    2         CH.sub.3        CHCH.sub.2    2         SCH.sub.3       CH.sub.3    2         CH.sub.3        SCH.sub.3    2         NO.sub.2        CH.sub.3    2         NH.sub.2        CH.sub.3    2         CHO             CH.sub.3    2         CO.sub.2 CH.sub.3                              H    2         CH(OCH.sub.3).sub.2                              H    ______________________________________    A = A-20; R.sup.3 = CH.sub.3 ; R.sup.5 = CH.sub.3    n         R.sup.1         R.sup.2    ______________________________________    2         CH.sub.3        CH.sub.3    2         C.sub.2 H.sub.5 CH.sub.3    2         H               CH.sub.3    2         H               C.sub.2 H.sub.5    2         H               CH.sub.2 CH.sub.2 CH.sub.3    2         OCH.sub.3       CH.sub.3    2         OCH.sub.3       C.sub.2 H.sub.5    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.2 CH.sub.2 CH.sub.3    2         CH.sub.2 CHCH.sub.2                              CH.sub.2 CHCH.sub.2               ##STR422##                               ##STR423##    2         CH(CH.sub.3).sub.2                              CH(CH.sub.3).sub.2    2         (CH.sub.2).sub.5    2         (CH.sub.2).sub.4    2         CH.sub.2 CHCH.sub.2                              C.sub.2 H.sub.5    2               ##STR424##     C.sub.2 H.sub.5    2         OC.sub.2 H.sub.5                              CH.sub.3    2         OC.sub.2 H.sub.5                              C.sub.2 H.sub.5    2         H                               ##STR425##    2               ##STR426##                               ##STR427##    2         H               CH.sub.2 CHCH.sub.2    2         CH.sub.2 CH.sub.2 CH.sub.3                              CH.sub.3    ______________________________________

Formulation

Compounds of this invention will generally be used in formulation withan agriculturally suitable carrier comprising a liquid or solid diluentor an organic solvent. Use formulations include dusts, granules,pellets, solutions, suspensions, emulsions, wettable powders,emulsifiable concentrates, dry flowables and the like, consistent withthe physical properties of the active ingredient, mode of applicationand environmental factors such as soil type, moisture and temperature.Sprayable formulations can be extended in suitable media and used atspray volumes from about one to several hundred liters per hectare. Highstrength compositions are primarily used as intermediates for furtherformulation. The formulations will typically contain effective amountsof active ingredient, diluent and surfactant within the followingapproximate ranges which add up 100 weight percent.

    ______________________________________                 Weight Percent                 Active                 Ingredient                         Diluent   Surfactant    ______________________________________    Wettable Powders                   25-90      0-74      1-10    Oil Suspensions, Emulsions,                    5-50     40-95      0-15    Solutions, (including    Emulsifiable Concentrates)    Dusts           1-25     70-99     0-5    Granules and Pellets                   0.01-99      5-99.99                                        0-15    High Strength  90-99      0-10     0-2    Compositions    ______________________________________

Typical solid diluents are described in Watkins, et at., Handbook ofInsecticide Dust Diluents and Carriers, 2nd Ed., Dotland Books,Caldwell, N.J. Typical liquid diluents and solvents are described inMarsden, Solvents Guide, 2nd Ed., Interscience, New York, 1950.McCutcheon's Detergents and Emulsifiers Annual, Allured Publ. Corp.,Ridgewood, N.J., as well as Sisely and Wood, Encyclopedia of SurfaceActive Agents, Chemical Publ. Co., Inc., New York, 1964, listsurfactants and recommended uses. All formulations can contain minoramounts of additives to reduce foam, caking, corrosion, microbiologicalgrowth, etc.

Solutions are prepared by simply mixing the ingredients. Fine solidcompositions are made by blending and, usually, grinding as in a hammermill or fluid energy mill. Water-dispersible granules can be produced beagglomerating a free powder composition; see for example, Cross et at.,Pesticide Formulations, Washington, D.C., 1988, pp 251-259. Suspensionsare prepared by wet-milling; see. for example, U.S. Pat. No. 3,060,084.Granules and pellets can be made by spraying the active material uponproformed granular carriers or by agglomeration techniques. SeeBrowning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp147-48, Perry's Chemical Engineer's Handbook, 4th Ed., McGraw-Hill, NewYork, 1963. pages 8-57 and following, and WO 91/13546. Pellets can beprepared as described in U.S. Pat. No. 4,172,714. Water-dispersible andwater-soluble granules can also be prepared as taught in DE 3,246,493.

For further information regarding the an of formulation, see U.S. Pat.No. 3,235,361, Col. 6, line 16 through Col. 7, line 19 and Examples10-41; U.S. Pat. No. 3,309,192, Col. 5, line 43 through Col. 7, line 62and Examples 8, 12, 15, 39, 41, 52, 53, 58,132, 138-140, 162-164, 166,167 and 169-182; U.S. Pat. No. 2,891,855, Col. 3, line 66 through Col.5, line 17 and Examples 1-4; Klingrnan, Weed Control as a Science, JohnWiley and Sons, Inc., New York, 1961, pp 81-96; and Hance et al., WeedControl Handbook, 8th Ed., Blackwell Scientific Publications, Oxford,1989.

In the following Examples, all percentages are by weight and allformulations are worked up in conventional ways. Compound numbers referto compounds in Index Table A.

    ______________________________________    Example A    High Strength Concentrate    Compound 1              98.5%    silica aerogel          0.5%    synthetic amorphous fine silica                            1.0%    Example B    Wettable Powder    Compound 1              65.0%    dodecylphenol polyethylene glycol ether                            2.0%    sodium ligninsulfonate  4.0%    sodium silicoaluminate  6.0%    montmorillonite (calcined)                            23.0%    Example C    Granule    Compound 1              10.0%    attapulgite granules (low volatile                            90.0%    matter, 0.71/0.30 mm; U.S.S. No.    25-50 sieves)    Example D    Extruded Pellet    Compound 1              25.0%    anhydrous sodium sulfate                            10.0%    crude calcium ligninsulfonate                            5.0%    sodium alkylnaphthalenesulfonate                            1.0%    calcium/magnesium bentonite                            59.0%    ______________________________________

Utility

Test results indicate compounds of this invention are activepostemergence and, in particular, preemergence herbicides. Manycompounds in this invention are useful for the control of selected grassand broadleaf weeds with tolerance to important agronomic crops such asbarley (Hordeum vulgare), corn (Zea mays), cotton (Gossypium hirsutum),rape (Brassica napus), rice (Oryza sativa), sorghum (Sorghum bicolor),soybean (Glycine max), sugar beet (Beta vulgaris), and wheat (Triticumaestivum), and to vegetable crops. Grass and broadleaf weed speciescontrolled include, but are not limited to, barnyardgrass (Echinochloacrusgali), blackgrass (Alopecurus myosuroides), chickweed (Stellariamedia), crabgrass (Digitaria spp.), foxtail (Setaria spp.),lambsquarters (Chenopodium spp.), and wild oats (Avena fatua).

Compounds 15 and 18 demonstrated excellent control of weeds includingpigweed, grabgrass, giant foxtail, green foxtail, fall panicum and wildproso with outstanding crop tolerance to cotton and soybeans in Table C.Compounds 30 and 38 demonstrated control of important weeds such aslambsquarter, barnyardgrass, crabgrass, giant foxtail, blackgrass andwild oats with excellent tolerance to crops including corn, soybean,cotton and wheat in Table B.

These compounds also have utility for weed control of selectedvegetation in specified areas such as around storage tanks, parkinglots, highways, and railways: in fallow crop areas: and in citrus andplantation crops such as banana, coffee, oil palm, and rubber.Alternatively, these compounds are useful to modify plant growth.

Effective rates of application for compounds of this invention aredetermined by a number of factors. These factors include: formulationselected, method of application, mount and type of vegetation present,growing conditions, etc. In general terms, the subject compounds shouldbe applied at rates from 0.03 to 20 kg/ha with a preferred rate range of0.05 to 2 kg/ha. One skilled in the an can easily determine effectiveapplication rates necessary for desired level of weed control.

Compounds of this invention can be used alone or in combination withother commercial herbicides, insecticides or fungicities. A mixture ofone or more of the following herbicides with a compound of titisinvention may be particularly useful for weed control. Examples of otherherbicides with which compounds of this invention can be formulated are:acetochlor, acifluoffen, acrolein, 2-propenal, alachlor, ametryn,amidosulfuron, ammonium sulfamate, amitrole, anilofos, asulam, atrazine,barban. benefta, bensulfuron methyl, bensulide, bentazon, benzofiuor,benzoylprop, bifenox, bromacil, bromoxynil, bromoxynil heptanoate,bromoxynil octanoate, butachlor, buthidazole, butralin, butrate,cacodylic acid, 2-chloro-N,N-di-2-propenylacetamide, 2-chloroallyldiethyldithiocarbamate, chloramben, chlorbromuron, chloridazon,chlorimuron ethyl, chlormethoxynil, chlomitrofen, chloroxuron,chlorpropharn, chlorsulfuron, chlortoluron, cinmethylin, cinosulfuron,clethodim, clomazone, cloproxydim, clopyralid, calcium salt ofmethylarsonic acid, cyanazine, cycloate, cycluron, cyperquat, cyprazine,cyprazole, cypromid, dalapon, dazomet, dimethyl2,3,5,6-tetrachloro-1,4-benzenedicarboxylate, desmedipham, desmetryn,dicamba, dichlebenil, dichlorprop, diclofop, diethatyl, difenzoquat,diflufenican, dimepiperate, dmitramine, dmoseb, diphenamid, dipropetryn,diquat, diuron, 2-methyl-4,6-dmitrophenol, disodium salt ofmethylarsonic acid, dymron, endothall, S-ethyl dipropylcarbamothioate,esprocarb, ethalfluralin, ethametsulfuron methyl, ethofumesate, fenac,fenoxaprop, fentuon, salt of fenuron and trichloroacetic acid,flareprop, fluazkfop, fluazkfop-P, fluchloralin, flumesulam,flumipropyn, fiuometuron, fiuorochloridone, fluorodffen, fluoroglycofen,fiupoxam, fluffdone, fluroxypyr, fluzasulfuron, fomesafen, losamine,glyphosate, haloxyfop, hexaflurate, hexazinone, imazamethabenz,irnazapyr, imazaquin, imazamethabenz methyl, imazethapyr, imazosulfuron,ioxynil, isopropalin, isoproturon, isouron, isoxaben, karbutilate,lactofen, lenacil, linuron, metobenzuron, metsulfuron methyl,methylarsonic acid, monoammonium salt of methylarsonic acid,(4-chloro-2-methylphenoxy)acetic acid, S,S'-dimethyl-2-(difluoromethyl)4-(2-methylpropyl)-6-(triftuoromethyl)-3,5-pyridmedicarbothioate,mecoprop, mefenacet, mefluidide, methalpropalin, methabenzthiazuron,metham, methazole, methoxuron, metolachlor, metribuzin,1,2-dihydropyridazine-3,6-dione, molinate, monolinuron, monuron, monuronsalt and trichloroacetic acid, monosodium salt of methylarsonic acid,napropamide, naptalam, neburon, nicosulfuron, nitralin, nitrofen,nitrofluorfen, norca, norflurazon, oryzalin, oxadiazon, oxyfluorfen,paraquat, pebulate, pendimethalm, perfluidone, phenmedipham, picloram,5- 2-chloro-4-(trifluoromethyl)phenoxy!-2-nitroacctophenoneoxime-O-acctic acid methyl ester, pretilachlor, primisulfuron,procyazine, profluralm, prometon, prometryn, pronamide, propachlor,propanil, propazine, propham, prosulfalin, prynachlor, pyrazolatc,pyrazon, pyrazosulfuron ethyl, quinchlorac, quizalofop ethyl,rimsulfuron, secbumeton, scthoxydim, siduron, simazme,1-(a,a-dimethylbenzyl)-3-(4-methylphenyl)urea, sulfometuron methyl,trichloroacetic acid, tebuthiuron, terbacil, terbuchlor, terbuthylazine,terbutol, terbutryn, thifensulfuron methyl, thiobencarb, tri-allate,trialkoxydim, triasulfuron, tribenuron methyl, triclopyr, tridiphane,trifluralin, trimemron, (2,4-dichlorophenoxy)acetic acid,4-(2,4-dichlorophenoxy)butanoic acid, vernolate, and xylachlor.

In certain instances, combinations with other herbicides having asimiliar spectrum of control but a different mode of action will beparticularly advantageous for resistance management.

Selective herbicidal properties of the subject compounds were discoveredin greenhouse tests as described below.

                                      INDEX TABLE A    __________________________________________________________________________    CMPD        A  X         R.sup.1                        R.sup.2                           R.sup.3                                R.sup.4                                   R.sup.5 n m.p. (°C.)    __________________________________________________________________________     1  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     2  A-4           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 90-96     3  A-4           O         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 108-110     4  A-4           NC.sub.6 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     5  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     6  A-4           NCH.sub.2 CO.sub.2 C.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     7  A-4           NCH.sub.2 CH.sub.2 CN                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     8  A-4           NC(O)N(C.sub.2 H.sub.5).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil     9  A-4           NC.sub.2 H.sub.5                     CH.sub.3                        CH.sub.3                           CH.sub.3                                CH.sub.3   2 oil    10  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    11  A-4           NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    12  A-4           NCH.sub.2 CH(CH.sub.3).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    13  A-4           NCH.sub.2 C.sub.6 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 118-120    14  A-1           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C(O)CH.sub.3                                H  Cl      2 128-130    15  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   2 103-105    16  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   2 oil    17  A-4           NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   2 oil    18  A-4           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   2 88-90    19  A-4            ##STR428##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    20  A-4            ##STR429##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    21  A-4            ##STR430##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    22  A-4            ##STR431##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    23  A-4            ##STR432##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    24  A-2           O         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                   H       2 oil    25  A-4           NCH.sub.2 CH.sub.2 Cl                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    26  A-4           NCH.sub.2 CH.sub.2 Br                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 70-72    27  A-6           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                H  Br      2 110-111    28  A-4           NCH.sub.2 CHCH.sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 102-104    29  A-4           NCHCH.sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    30  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                CH.sub.3   2 oil    31  A-3           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CHF.sub.2                                CH.sub.3   1 oil    32  A-3           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CHF.sub.2                                CH.sub.3   2 89-91    33  A-4           NCH.sub.2 CH.sub.2 OCH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 83-85    34  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                C.sub.2 H.sub.5                                           2 oil    35  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                C.sub.2 H.sub.5                                           2 oil    36  A-4           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                C.sub.2 H.sub.5                                           2 oil    37  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                C.sub.2 H.sub.5                                           2 oil    38  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                CH.sub.3   2 95-96    39  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                C.sub.2 H.sub.5                                           2 oil    40  A-6           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                H  NO.sub.2                                           2 115-118    41  A-4           NCH(CH.sub.3).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 oil    42  A-4            ##STR433##                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3   2 97-99    43  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  CH.sub.3                                           2 86-88    44  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                C.sub.2 H.sub.5                                           2 oil    45  A-15         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           H    H  H       2 oil    46  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                Br CH.sub.3                                           2 93-95    47  A-15         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                    ##STR434##                                           2 86-89    48  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           H    I  H       2 109-111    49  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                H  C.sub.2 H.sub.5                                           2 70-71    50  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           H    H  H       2 110-112    51  A-15         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                   C.sub.2 H.sub.5                                           2 oil    52  A-1           NH        C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                C.sub.2 H.sub.5                                   CH.sub.3                                           2 oil    53  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H                                    ##STR435##                                           2 73-76    54  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                            ##STR436##                                H  CH.sub.3                                           2 93-95    55  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  C.sub.6 H.sub.5                                           2 117-119    56  A-4           NCH(CH.sub.3).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                CH3        2 oil    57  A-4           NCH(CH.sub.3).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                C.sub.2 H.sub.5                                           2 oil    58  A-2           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                   H       2 oil    59  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   C.sub.2 H.sub.5                                           2 78-80    60  A-3           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.2 Br                                CH.sub.3   2 oil    61  A-3           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Br   Br         2 93-94    62  A-3           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Br   Br         1 oil    63  A-12           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                   CO.sub.2 CH.sub.3                                           2 105-107    64  A-12           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                   CO.sub.2 CH.sub.3                                           1 oil    65  A-9           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CO.sub.2 C.sub.2 H.sub.5                                           1 oil    66  A-9           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CO.sub.2 C.sub.2 H.sub.5                                           2 oil    67  A-6           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                Br Br      1 oil    68  A-6           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                                Br Br      2 oil    69  A-16         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  H       2 oil    70  A-16         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  CH.sub.3                                           2 oil    71  A-16         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                H  CH.sub.3                                           2 70-72    72  A-19         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           H       H       2 111-113    73  A-16         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                H  H       2 oil    74  A-4           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl      C.sub.2 H.sub.5                                           2 67-68    92  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                C.sub.2 H.sub.5                                   CH.sub.3                                           2 64-66    93  A-4           NCH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   1 oil    94  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  CH(CH.sub.3).sub.2                                           2 64-66    95  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  CH.sub.2 CH(CH.sub.3).sub.2                                           2 oil    96  A-17         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                H  C.sub.2 H.sub.5                                           2 oil    97  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C.sub.2 H.sub.5                                CH.sub.3   2 oil    98  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           OCH.sub.3                                CH.sub.3   2 oil    99  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3   2 oil    100 A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           OCH.sub.3                                CH.sub.3   2 oil    101 A-7           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl      CHF.sub.2                                           2 106-107    102 A-7           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl      CHF.sub.2                                           1 oil    103 A-7           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CHF.sub.2                                   CH.sub.2 CH.sub.2 CH.sub.3                                           2 97-98    __________________________________________________________________________    Compound     Spectra Data    __________________________________________________________________________     1           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 2.45 (s, 3H); 2.57                 (s, 3H); 3.6                 (bq, 4H); 3.75 (s, 3H); 8.8 (s, 1H)     4           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 254 (s, 3H); 2.59                 (s, 3H); 3.4-3.8                 (m, 4H); 7.3-7.6 (m, 5H); 8.85 (s, 1H)     5           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 2.47 (s, 3H); 2.64                 (s, 3H); 3.6                 (m, 4H); 4.6 (q, 2H); 8.83 (s, 1H)     6           (NMR, CDCl.sub.3): δ 1.1-1.4 (m, 9H); 2.46 (s, 3H);                 2.55 (s, 3H);                 3.4-3.7 (m, 4H); 4.22 (q, 2H); 4.8 (s, 2H); 8.82 (s, 1H)     7           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 2.45 (s, 3H); 2.68                 (s, 3H); 2.96                 (t, 2H); 3.6 (m, 4H); 4.29 (t, 2H); 8.83 (s, 1H)                 IR, Nujol): 2237 cm.sup.-1     8           (NMR, CDCl.sub.3): δ 1.30 (m, 12H); 2.49 (s, 3H); 2.68                 (s, 3H);                 3-3.7 (m, 8H); 8.84 (s, 1H)     9           (NMR, CDCl.sub.3): δ 1.4 (t, 3H); 2.46 (s, 3H); 2.58                 (s, 3H); 3.2                 (bs, 3H); 3.3 (bs, 3H); 4.05 (q, 2H); 8.79 (s, 1H)    10           (NMR, CDCl.sub.3): δ 0.92 (t, 3H); 1.29 (t, 6H); 1.8                 (m, 2H); 2.45                 (s, 3H); 2.57 (s, 3H); 3.6 (m, 4H); 3.95 (t, 2H); 8.8 (s,                 1H)    11           (NMR, CDCl.sub.3): δ 0.94 (t, 3H); 1.29 (m, 8H); 1.79                 (m, 2H);                 2.45 (s, 3H); 2.57 (s, 3H); 3.58 (m, 4H); 4 (t, 2H); 8.81                 (s, 1H)    12           (NMR, CDCl.sub.3): δ 0.9 (d, 6H); 1.29 (t, 6H); 2.2                 (m, 1H); 2.45                 (s, 3H); 2.57 (s, 3H); 3.58 (m, 4H); 3.8 (d, 2H); 8.8 (s,                 1H)    16           (NMR, CDCl.sub.3): δ 0.93 (t, 3H); 1.29 (t, 6H); 1.87                 (m, 2H); 2.5                 (s, 3H); 3.6 (m, 4H); 4.07 (t, 2H); 8.84 (s, 1H)    17           (NMR, CDCl.sub.3): δ 0.98 (t, 3H); 1.3 (m, 8H); 1.8                 (m, 2H); 2.5 (s,                 3H); 3.6 (m, 4H); 4.1 (t, 2H); 8.84 (s, 1H)    18           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 1.43 (t, 3H); 2.5                 (s, 3H); 3.6 (m,                 4H); 4.15 (q, 2H); 8.84 (s, 1H)    19           (NMR, CDCl.sub.3): δ 1.31 (t, 6H); 2.54 (s, 3H); 2.61                 (s, 3H); 3.6                 (m, 4H); 7.2-7.5 (m, 4H); 8.82 (s, 1H)    20           (NMR, CDCl.sub.3): δ 1.31 (t, 6H); 2.54 (s, 3H); 2.59                 (s, 3H); 3.6                 (m, 4H); 7.34 (d, 2H); 7.48 (d, 2H); 8.82 (s, 1H)    21           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 2.53 (s, 3H); 2.57                 (s, 3H); 3.6 (m,                 4H); 7.1-7.4 (m, 4H); 8.82 (s, 1H)    22           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 2.5 (s, 3H); 2.54                 (s, 3H); 3.6 (bs,                 4H); 7.2-7.6 (m, 4H); 8.87 (s, 1H)    23           (NMR, CDCl.sub.3): δ 1.31 (t, 6H); 2.54 (s, 3H); 2.62                 (s, 3H); 3.6                 (m, 4H); 7.1-7.6 (m, 4H); 8.82 (s, 1H)    24           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 2.17 (d, 3H); 2.65                 (s, 3H); 3.6                 (bs, 4H); 7.1 (bs, 1H); 8.82 (s, 1H)    25           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 2.46 (s, 3H); 2.63                 (s, 3H); 3.58                 (bs, 4H); 3.85 (t, 2H); 4.3 (t, 2H); 8.82 (s, 1H)    29           (NMR, CDCl.sub.3): δ 1.28 (m, 6H); 2.5 (s, 3H); 2.64                 (s, 3H);                 3.4-3.7 (m, 4H); 5.07 (d, 1H); 5.85 (d, 1H); 6.93 (dd, 1H);                 8.82                 (s, 1H)    30           (NMR, CDCl.sub.3): δ 1.2-1.4 (m, 9H); 2.45 (s, 3H); 3                 (q, 2H);                 3.43-3.7 (m, 4H); 3.77 (s, 3H); 8.81 (s, 1H)    31           (NMR, CDCl.sub.3): δ 1.25 (m, 6H); 2.36 (s, 3H); 3.58                 (m, 4H);                 4.09 (s, 3H); 6.99 (t, 1H); 8.9 (s, 1H)    34           (NMR, CDCl.sub.3): δ 1.2-1.4 (m, 12H); 2.92 (q, 2H);                 3.05 (q, 2H);                 3.6 (m, 4H); 4.61 (q, 2H); 8.83 (s, 1H)    35           (NMR, CDCl.sub.3): δ 1.1-1.4 (m, 12H); 2.82 (q, 2H);                 2.98 (q, 2H);                 3.4-3.7 (m, 4H); 3.71 (s, 1H)    36           (NMR, CDCl.sub.3): δ 1.15-1.4 (m, 12H); 1.44 (t, 3H);                 2.82-3.1 (m,                 4H); 3.6 (m, 4H); 4.05 (q, 2H); 8.81 (s, 1H)    37           (NMR, CDCl.sub.3): δ 1.18-1.4 (m, 9H); 2.58 (s, 3H);                 2.9 (q, 2H);                 3.6 (m, 4H); 3.76 (s, 3H); 8.8 (s, 1H)    39           (NMR, CDCl.sub.3): δ 0.95 (t, 3H); 1.1-1.4 (m, 12H);                 1.88 (m, 2H);                 2.82-3.1 (m, 4H); 3.6 (m, 4H); 3.95 (t, 2H); 8.81 (s, 1H)    41           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 1.45 (d, 6H); 2.46                 (s, 3H); 2.58                 (s, 3H); 3.6 (m, 4H); 4.4 (m, 1H); 8.82 (s, 1H)    44           (NMR, CDCl.sub.3): δ 1.28 (m, 9H); 2.64 (s, 3H); 2.9                 (q, 2H); 3.58                 (m, 4H); 4.63 (q, 2H): 8.84 (s, 1H)    45           (NMR, CDCl.sub.3): δ 1.24 (t, 6H); 3.5 (q, 4H); 6.42                 (bs, 2H); 7.3                 (bs, 2H); 9.08 (s, 1H)    51           0.94 (t, 3H); 1.21 (t, 6H); 1.88 (s, 3H); 2.23 (q, 2H); 2.27                 (s,                 3H); 3.5 (m, 4H), 6.87 (s, 1H), 8.74 (s, 1H)    52           (NMR, CDCl.sub.3): δ 1.05 (t, 3H); 1.2 (m, 6H); 2.08                 (s, 3H); 2.19                 (s, 3H); 2.39 (q, 2H); 3.5 (m, 4H); 7.87 (bs, 1H); 8.69 (s,                 1H)    56           (NMR, CDCl.sub.3): δ 1.2-1.3 (m, 9H); 1.47 (d, 6H);                 2.47 (s, 3H);                 3.02 (q, 2H); 3.5-3.7 (m, 4H); 4.43 (m, 1H); 8.82 (s, 1H)    57           (NMR, CDCl.sub.3): δ 3.5-3.7 (m, 4H); 4.43 (m, 1H);                 8.81 (s, 1H)    58           (NMR, CDCl.sub.3): δ 1.3 (m, 6H); 2.23 (s, 3H); 2.53                 (s, 3H); 3.48                 (s, 3H); 3.6 (m, 4H); 5.32 (s, 1H); 8.78 (s, 1H)    60           (NMR, CDCl.sub.3): δ 1.29 (m, 6H); 2.28 (s, 3H); 3.6                 (m, 4H); 4.2                 (s, 3H); 4.69 (s, 2H); 8.87 (s, 1H)    62           (NMR, CDCl.sub.3): δ 1.25 (bs, 6H); 3.58 (bs, 4H); 4.2                 (s, 3H); 8.7                 (s, 1H). (IR, Nujol): 1720 cm.sup.-1, 1081 cm.sup.-1    64           (NMR, CDCl.sub.3): δ 1.28 (t, 6H); 3.6 (bs, 4H); 4.09                 (s, 3H); 8.9                 (s, 1H)    65           (NMR, CDCl.sub.3): δ 1.3 (m, 6H); 1.4 (t, 3H); 3.5 (q,                 4H); 4.4 (q.                 2H); 8.8 (s, 1H)    66           (NMR, CDCl.sub.3): δ 1.25 (bd, 6H); 1.38 (t, 3H); 3.58                 (bs, 4H);                 4.45 (q, 2H); 8.82 (s, 1H)    67           (NMR, CDCl.sub.3): δ 1.28 (t, 6H); 3.6 (bd, 4H); 4.05                 (s, 3H); 8.9                 (s, 1H). (IR, neat): 1744 cm.sup.-1 ; 1073 cm.sup.-1 ;    68           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 3.6 (bd, 4H); 4.15                 (s, 3H); 8.8 (s,                 1H). (IR, Nujol): 1728 cm.sup.-1 ; 1376 cm.sup.-1 ; 1170                 cm.sup.-1    69           (NMR, CDCl.sub.3): δ 1.3 (t, 6H); 2.65 (s, 3H); 3.55                 (bs, 4H); 6.95                 (s, 1H); 7.4 (s, 1H); 8.9 (s, 1H)    70           (NMR, CDCl.sub.3): δ 1.29 (t, 5H); 2.14 (s, 3H); 2.64                 (s, 3H); 3.55                 (bs, 4H); 7.07 (s, 1H); 8.76 (s, 1H)    73           (NMR, CDCl.sub.3): δ 1.28 (t, 6H); 1.35 (t, 3H); 3.04                 (q, 2H); 3.5                 (bs, 4H); 6.97 (s, 1H); 7.40 (s, 1H); 8.88 (s, 1H)    93           (NMR, CDCl.sub.3): δ 1.28 (m, 6H); 1.43 (t, 3H); 2.33                 (s, 3H);                 3.4-3.8 (m, 4H); 4.15 (q, 2H); 8.9 (s, 1H)    95           (NMR, CDCl.sub.3): δ 0.86 (d, 6H); 1.28 (t, 6H); 1.87                 (m, 1H); 2.43                 (d, 2H); 2.62 (s, 3H); 3.58 (m, 4H); 6.04 (s, 1H); 8.81 (s,                 1H)    96           (NMR, CDCl.sub.3): δ 1.18 (t, 3H); 1.28 (t, 6H); 2.6                 (m, 5H); 3.58                 (m, 4H); 6.08 (s, 1H); 8.83 (s, 1H)    97           (NMR, CDCl.sub.3): δ 0.95 (t, 3H); 1.29 (m, 9H); 1.9                 (m, 2H); 2.46                 (s, 3H); 3 (q, 2H); 3.6 (m, 4H); 3.94 (t, 2H); 8.82 (s, 1H)    98           (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 2.43 (s, 3H); 3.6                 (m, 4H); 4.31                 (s, 3H); 4.51 (q, 2H); 8.86 (s, 1H)    99           (NMR, CDCl.sub.3): δ 1.30 (t, 6H); 2.50 (s, 3H); 3.6                 (m, 4H); 3.82                 (s, 3H); 8.84 (s, 1H)    100          (NMR, CDCl.sub.3): δ 1.29 (t, 6H); 2.42 (s, 3H);                 3.45-3.75 (m, 7H);                 4.21 (s, 3H); 8.83 (s, 1H)    102          (NMR, CDCl.sub.3): δ 1.27 (bs, 6H); 3.6 (bs, 4H); 4.1                 (s, 3H); 6.7                 (t, 1H); 8.95 (s, 1H)    __________________________________________________________________________

                                      INTERMEDIATE TABLE    __________________________________________________________________________    CMPD        A  X         R.sup.1                        R.sup.2                           R.sup.3                                R.sup.4                                   R.sup.5                                     n m.p. (°C.)    __________________________________________________________________________    75  A-4           NCH.sub.3 C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    76  A-4           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 67-69    77  A-4           NC.sub.6 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    78  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    79  A-4           NCH.sub.2 C.sub.6 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    80  A-4           NCH.sub.2 CO.sub.2 C.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    81  A-4           NC.sub.2 H.sub.5                     CH.sub.3                        CH.sub.3                           CH.sub.3                                CH.sub.3                                     0 oil    82  A-4           NCH.sub.2 CH.sub.2 CN                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 95-97    83  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 81-83    84  A-4           NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    85  A-4           NCH.sub.2 CH(CH.sub.3).sub.2                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    86  A-4           NCH.sub.2 CF.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3                                     0 112-114    87  A-4           O         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           CH.sub.3                                CH.sub.3                                     0 oil    88  A-1           S         C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           C(O)CH.sub.3                                H  Cl                                     0 103-105    89  A-1           NC.sub.2 H.sub.5                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3                                     0 88-90    90  A-4           NCH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3                                     0 oil    91  A-4           NCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.3                     C.sub.2 H.sub.5                        C.sub.2 H.sub.5                           Cl   CH.sub.3                                     0 oil    __________________________________________________________________________    Compound Spectra Data    __________________________________________________________________________    75       (NMR, CDCl.sub.3): δ 1.2 (t, 6H); 2.24 (s, 3H); 2.30 (s,             3H); 3.5 (q,             4H); 3.76 (s, 3H); 8.7 (s, 1H)    77       (NMR, CDCl.sub.3): δ 1.2 (m, 6H); 2.34 (s, 3H); 2.39 (s,             3H); 3.43             (q, 4H); 7.45 (m, 5H); 8.72 (s, 1H)    78       (NMR, CDCl.sub.3): δ 1.1-1.2 (m, 6H); 2.26 (s, 3H); 2.37             (s, 3H);             3.3-3.6 (q, 4H); 4.6 (q, 2H); 8.7 (s, 1H)    79       (NMR, CDCl.sub.3): δ 1.1 (m, 6H); 2.25 (s, 3H); 2.29 (s,             3H); 3.47             (q, 4H); 5.26 (s, 2H); 7-7.4 (m, 5H); 8.69 (s, 1H)    80       (NMR, CDCl.sub.3): δ 1-1.35 (m, 9H); 2.26 (s, 3H); 2.29             (s, 3H);             3.5 (bq, 4H); 4.23 (q, 2H); 4.81 (s, 2H); 8.69 (s, 1H)    81       (NMR, CDCl.sub.3): δ 1.4 (t, 3H); 2.26 (s, 3H); 2.32 (s,             3H); 3.17             (bs, 6H); 4.07 (q, 2H); 8.66 (s, 1H)    84       (NMR, CDCl.sub.3): δ 0.94 (t, 3H); 1.15 (m, 6H); 1.3 (m,             2H); 1.8             (m, 2H); 2.25 (s, 3H); 2.3 (s, 3H); 3.47 (q, 4H); 4 (t, 2H);             8.89             (s, 1H)    85       (NMR, CDCl.sub.3): δ 0.9 (d, 6H); 1.18 (t, 6H); 2.2 (m,             1H); 2.25             (s, 3H); 2.29 (s, 3H); 3.43 (q, 4H); 3.8 (d, 2H); 8.69 (s, 1H)    87       (NMR, CDCl.sub.3): δ 1.2 (m, 6H); 2.27 (s, 3H); 2.48 (s,             3H); 3.48             (q, 4H); 8.72 (s, 1H)    89       (NMR, CDCl.sub.3): δ 1.2 (m, 6H); 1.4 (t, 3H); 2.28 (s,             3H); 3.5 (m,             4H); 4.17 (q, 2H); 8.7 (s, 1H)    90       (NMR, CDCl.sub.3): δ 0.94 (t, 3H); 1.2 (m, 6H); 1.87 (m,             2H); 2.28             (s, 3H); 3.45 (q, 4H); 4.07 (t, 2H); 8.7 (s, 1H)    91       (NMR, CDCl.sub.3): δ 0.95 (t, 3H); 1.2 (m, 6H); 1.3 (m,             2H); 1.8             (m, 2H); 2.28 (s, 3H); 3.45 (q, 4H); 4.1 (t, 2H); 8.7 (s,    __________________________________________________________________________             1H)

TEST A

Seeds of barnyardgrass (Echmochloa crusgalli), cheatgrass (Bromussecalinus), cocklebur (Xanthium pensylvanicum), crabgrass (Digitariaspp.), giant foxtaft (Setaria faberii), morningglory (Ipomoea spp.),sorghum (Sorghum bicolor), velvetled (Abutilon theophrasti), and wildoat (Avena farua) were planted into a sandy loam soft and treatedpreemergence with test chemicals dissolved in a nonphytotoxic solvent.At the same time, these crop and weed species were also treatedpostemergence with test chemicals. Plants ranged in height from two toeighteen cm and were in the two to three leaf stage for thepostemergence treatment. Treated plants and untreated controls weremaintained in a greenhouse for approximately eleven days, after whichall treated plants were compared to untreated controls and visuallyevaluated for injury. Plant response ratings, summarized in Table A, arebased on a 0 to 10 scale where 0 is no effect and 10 is completecontrol. A dash (-) response means no test results.

                  TABLE A    ______________________________________               COMPOUND    Rate (2000 g/ha)                 1      2       3    4    6    13    ______________________________________    POSTEMERGENCE    Barnyardgrass                 8      8       8    9    7    7    Cheatgrass   8      8       3    4    0    2    Cocklebur    4      5       1    2    0    0    Crabgrass    8      7       9    9    7    2    Giant foxtail                 8      8       6    9    2    7    Morningglory 7      2       9    2    7    7    Sorghum      8      8       7    1    5    3    Velvetleaf   7      7       8    7    5    5    Wild oat     7      7       7    5    2    2    PREEMERGENCE    Barnyardgrass                 10     10      10   10   9    9    Cheatgrass   10     9       9    8    9    8    Cocklebur    5      8       0    2    0    0    Crabgrass    10     10      10   5    9    9    Giant foxtail                 10     10      9    10   10   10    Morningglory 9      10      9    8    1    0    Sorghum      10     10      10   9    9    9    Velvetleaf   9      10      10   1    0    0    Wild oat     10     9       10   9    9    9    ______________________________________

TEST B

Seeds of barley (Hordeum vulgare), bayardgrass (Echinochloa crusgalli),bedstraw (Galium aparine), blackgrass (Alopecurus myosuroides),cheatgrass (Bromus secalinus), chickweed (Stellaria media), cocklebur(Xanthium pensylvanicum), corn (Zea mays), cotton (Gossypium hirsutum),crategrass (Digitaria spp.), giant foxtail (Setaria faberii),lambsquarters (Chenopodium album), morningglory (Ipomoea hederacea),rape (Brassica napus), rice (Oryza sativa), sorghum (Sorghum bicolor),soybean (Glycine max), sugar beet (Beta vulgaris), velvetleaf (Abutilontheophrasti), wheat (Triticum aestivum), wild buckwheat (Polygonumconvolvulus) and wild oat (Avena farua) and purple nutsedge (Cyperusrotundus) tubers were planted and treated preemergence with testchemicals dissolved in a non-phytotoxic solvent. At the same time, thesecrop and weed species were also treated with postemergence applicationsof test chemicals. Plants ranged in height from two to eighteen cm (oneto four leaf stage) for postemergence treatments. Treated plants andcontrols were maintained in a greenhouse for twelve to sixteen days,after which all species were compared to controls and visuallyevaluated. Plant response ratings, summarized in Table B, are based on ascale of 0 to i0 where 0 is no effect and 10 is complete control. A dash(-) response means no test result.

                                      TABLE B    __________________________________________________________________________                                      COMPOUND               Rate (2000 g/ha)       27 40    __________________________________________________________________________               POSTEMERGENCE               Barley                 2  0               Barnyardgrass          7  0               Bedstraw               2  0               Blackgrass             2  0               Cheatgrass             0  0               Chickweed              2  0               Cocklebur              2  0               Corn                   4  0               Cotton                 1  4               Crabgrass              4  0               Giant foxtail          1  0               Lambsquarters          1  0               Morningglory           1  0               Nutsedge               0  0               Rape                   5  0               Rice                   8  0               Sorghum                1  0               Soybean                3  1               Sugar beet             5  0               Velvetleaf             1  0               Wheat                  2  0               Wild buckwheat         1  --               Wild oat               0  0               PREEMERGENCE               Barley                 0  0               Barnyardgrass          10 0               Bedstraw               7  0               Blackgrass             9  0               Cheatgrass             4  0               Chickweed              3  0               Cocklebur              0  0               Corn                   7  0               Cotton                 2  0               Crabgrass              9  0               Giant foxtail          9  0               Lambsquarters          9  0               Morningglory           0  0               Nutsedge               3  0               Rape                   1  0               Rice                   2  0               Sorghum                8  0               Soybean                0  0               Sugar beet             2  0               Velvetleaf             1  0               Wheat                  0  0               Wild buckwheat         10 0               Wild oat               9  0    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               1 2 3 4 5 6 7 8 9 10                                   11                                     13 14                                          15                                            16                                              17 18                                                   19                                                     20                                                       21 22                                                            23                                                              24                                                                25    __________________________________________________________________________    POSTEMERGENCE    Barley     6 4 4 0 0 0 0 0 3 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               9 9 9 9 9 5 6 9 9 9 9 4  6 9 9 3  9 0        0                                                            8                                                            8                                                            8 9 8    Bedstraw   6 5 2 4 5 5 4 1 0 1 0 3  0 0 0 3  0 3        3                                                            2                                                            5                                                            7 3 5    Blackgrass 6 8 9 5 8 0 2 2 9 6 2 0  0 9 7 10 10                                                   0        0                                                            7                                                            7                                                            7 5 9    Cheatgrass 1 1 2 2 0 0 0 0 0 0 0 0  0 0 0 0  2 0        0                                                            0                                                            1                                                            0 0 1    Chickweed  2 5 --                     3 3 0 2 --                               --                                 0 0 0  0 0 2 0  0 0        0                                                            0                                                            1                                                            2 2 0    Cocklebur  1 1 1 2 0 1 1 --                               1 0 0 0  --                                          0 1 0  1 0        1                                                            1                                                            1                                                            0 0 0    Corn       9 8 8 2 0 0 1 4 4 3 0 0  0 0 0 0  4 0        1                                                            0                                                            0                                                            0 4 0    Cotton     4 2 2 1 4 0 5 5 4 1 0 5  0 2 5 5  5 0        0                                                            0                                                            0                                                            2 0 3    Crabgrass  6 8 8 1 1 0 0 1 3 6 0 0  4 2 7 5  8 0        1                                                            7                                                            8                                                            3 4 6    Giant foxtail               5 6 0 3 1 0 0 1 7 3 0 0  3 2 2 1  7 0        0                                                            2                                                            7                                                            0 1 3    Lambsquarters               1 2 6 3 7 0 4 6 0 0 2 0  0 0 0 0  --                                                   2        1                                                            --                                                            2                                                            --                                                              1 --    Morningglory               1 5 5 9 5 0 3 3 1 5 1 1  1 8 6 3  7 2        2                                                            5                                                            3                                                            2 1 0    Nutsedge   0 --                   --                     0 4 0 0 --                               --                                 3 0 0  0 0 0 0  0 1        0                                                            4                                                            0                                                            0 0 0    Rape       4 1 0 0 0 0 1 0 0 2 0 0  0 0 0 2  3 0        2                                                            0                                                            5                                                            2 0 2    Rice       5 8 9 3 5 0 1 2 5 2 0 0  0 3 3 2  4 0        0                                                            0                                                            4                                                            2 4 3    Sorghum    5 5 3 0 0 0 0 2 0 0 0 0  0 0 0 0  2 0        0                                                            0                                                            0                                                            0 3 0    Soybean    4 1 5 2 3 0 4 2 1 3 2 3  0 3 4 2  7 1        0                                                            1                                                            2                                                            2 1 3    Sugar beet 5 8 2 0 0 2 0 0 0 2 1 0  0 2 0 2  3 0        3                                                            2                                                            0                                                            2 2 4    Velvetleaf 2 5 5 7 4 0 3 1 0 0 0 0  2 2 0 0  2 1        1                                                            3                                                            5                                                            2 1 2    Wheat      6 6 5 0 0 0 0 0 6 2 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 2 3    Wild buckwheat               --                 --                   --                     1 0 0 --                             --                               --                                 1 0 4  0 0 0 0  0 0        0                                                            0                                                            1                                                            1 1 1    Wild oat   6 3 3 0 0 0 0 2 2 0 0 0  0 0 0 0  0 0        0                                                            2                                                            1                                                            0 0 2    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               26                 27                   28                     29                       30                         31                           32                             33                               34                                 35                                   36                                     37 38                                          39                                            40                                              41 42                                                   43                                                     44                                                       45 46                                                            47                                                              48                                                                49    __________________________________________________________________________    POSTEMERGENCE    Barley     0 0 2 3 6 4 0 0 2 3 0 3  2 0 0 2  2 0        3                                                            3                                                            0                                                            0 0 3    Barnyardgrass               6 6 8 9 9 9 9 9 8 9 9 9  9 9 0 7  9 0        9                                                            9                                                            9                                                            3 0 8    Bedstraw   4 0 2 5 5 5 4 2 --                                 3 3 5  6 5 0 4  5 0        3                                                            1                                                            2                                                            0 0 3    Blackgrass 5 0 5 9 8 9 0 2 1 9 8 9  5 8 0 6  7 0        3                                                            6                                                            1                                                            --                                                              0 2    Cheatgrass 0 0 0 2 3 3 0 2 4 4 2 5  4 3 0 0  3 0        1                                                            1                                                            1                                                            2 2 0    Chickweed  2 0 3 0 4 1 0 1 1 0 0 4  3 1 --                                              1  4 0        2                                                            0                                                            0                                                            0 4 5    Cocklebur  1 0 1 0 1 0 0 0 0 0 1 0  1 0 0 1  0 0        0                                                            0                                                            0                                                            0 0 2    Corn       6 2 6 5 7 8 3 4 5 5 6 7  8 6 0 4  6 0        6                                                            4                                                            2                                                            2 0 3    Cotton     3 0 4 5 5 9 2 2 0 6 5 3  1 0 0 3  2 0        1                                                            2                                                            2                                                            2 0 2    Crabgrass  6 0 8 9 9 9 9 9 9 8 9 9  9 9 0 2  6 0        5                                                            7                                                            2                                                            2 0 8    Giant foxtail               6 2 8 9 9 9 9 9 9 9 9 9  9 9 0 6  7 0        4                                                            5                                                            0                                                            2 0 9    Lambsquarters               1 0 4 1 1 1 1 --                               3 2 0 -- 3 0 0 2  1 0        --                                                            3                                                            2                                                            0 0 0    Morningglory               3 0 2 2 3 3 2 2 1 2 9 5  5 3 0 2  6 0        5                                                            0                                                            0                                                            0 0 3    Nutsedge   0 0 0 0 6 0 2 0 0 0 5 2  0 0 0 0  0 0        3                                                            0                                                            0                                                            0 0 0    Rape       0 0 0 0 0 0 1 0 0 0 0 0  3 0 0 2  0 0        0                                                            0                                                            0                                                            0 0 4    Rice       6 6 8 2 8 8 7 6 8 7 8 8  7 5 0 5  5 0        3                                                            5                                                            3                                                            2 0 9    Sorghum    3 0 3 4 8 8 5 7 1 7 6 6  6 4 0 6  7 0        4                                                            6                                                            2                                                            2 0 6    Soybean    7 0 3 3 7 6 2 2 7 6 3 6  5 6 0 6  2 0        5                                                            4                                                            2                                                            0 0 4    Sugar beet 0 0 0 0 0 0 2 0 2 0 0 0  5 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 6    Velvetleaf 3 0 6 0 2 1 1 1 1 2 5 2  1 1 0 2  2 0        2                                                            0                                                            0                                                            0 0 2    Wheat      0 0 2 2 6 7 0 0 0 5 2 6  2 2 0 2  6 0        7                                                            3                                                            0                                                            0 0 4    Wild buckwheat               0 0 0 0 1 1 0 0 0 --                                   0 2  4 0 0 5  0 0        1                                                            0                                                            0                                                            0 0 0    Wild oat   1 0 0 0 1 2 0 0 2 0 0 5  0 1 0 0  2 0        1                                                            0                                                            3                                                            0 0 3    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               50                 51                   52                     53                       54                         55                           56                             57                               58                                 59                                   61                                     62 63                                          64                                            65                                              66 67                                                   68                                                     69                                                       70 71                                                            72                                                              73                                                                74    __________________________________________________________________________    POSTEMERGENCE    Barley     2 0 0 0 0 0 0 0 2 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 1    Barnyardgrass               9 0 0 9 8 0 9 9 8 9 7 7  0 0 0 0  3 1        0                                                            2                                                            0                                                            0 0 9    Bedstraw   --                 0 0 4 0 3 7 0 6 --                                   3 3  0 1 0 0  0 1        0                                                            0                                                            0                                                            0 0 5    Blackgrass 9 0 0 7 9 0 8 0 2 3 --                                     4  0 0 0 0  0 0        0                                                            3                                                            0                                                            0 0 9    Cheatgrass 2 2 0 0 0 2 0 0 2 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 3    Chickweed  7 --                   --                     7 0 --                           --                             --                               --                                 0 3 0  0 2 0 0  0 3        0                                                            0                                                            0                                                            0 0 --    Cocklebur  0 0 0 4 2 0 5 2 1 0 0 0  0 0 0 0  0 0        0                                                            1                                                            0                                                            0 0 1    Corn       7 1 0 4 1 0 9 7 2 4 0 3  0 0 0 0  0 0        0                                                            2                                                            0                                                            0 0 7    Cotton     0 0 0 3 3 1 6 4 5 6 0 1  0 0 0 0  0 2        0                                                            5                                                            0                                                            0 0 2    Crabgrass  9 2 0 9 9 0 9 9 3 7 1 3  0 0 0 0  0 3        0                                                            2                                                            0                                                            0 0 9    Giant foxtail               8 0 0 8 9 0 9 8 2 4 0 3  0 0 0 0  0 0        0                                                            2                                                            0                                                            0 0 8    Lambsquarters               1 0 0 0 5 0 9 0 4 1 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 1    Morningglory               2 2 1 5 3 0 5 2 2 3 2 2  0 0 0 0  2 0        0                                                            1                                                            0                                                            0 0 7    Nutsedge   5 0 0 5 5 0 8 2 3 7 0 0  0 0 0 0  0 0        0                                                            2                                                            0                                                            0 0 5    Rape       0 0 0 0 0 0 0 5 1 1 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 1    Rice       8 0 0 8 9 2 9 7 5 5 0 4  0 0 0 0  0 2        0                                                            2                                                            0                                                            0 0 7    Sorghum    8 0 0 7 3 1 7 6 2 2 3 6  0 0 0 0  0 0        0                                                            2                                                            0                                                            0 0 3    Soybean    1 0 0 4 2 1 7 3 1 4 0 2  0 0 0 0  2 2        0                                                            4                                                            0                                                            0 0 1    Sugar beet 0 0 0 0 0 0 1 2 2 0 3 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Velvetleaf 0 0 0 2 3 0 6 2 1 1 0 1  0 0 0 0  0 0        0                                                            2                                                            0                                                            0 0 2    Wheat      8 0 0 0 4 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Wild buckwheat               0 0 0 0 0 4 2 0 7 1 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 3    Wild oat   2 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               1 2 3 4 5 6 7 8 9 10                                   11                                     13 14                                          15                                            16                                              17 18                                                   19                                                     20                                                       21 22                                                            23                                                              24                                                                25    __________________________________________________________________________    PREEMERGENCE    Barley     1 3 0 2 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               10                 10                   10                     9 10                         3 10                             10                               10                                 10                                   10                                     7  9 9 9 9  9 5        5                                                            10                                                            10                                                            10                                                              10                                                                10    Bedstraw   0 5 7 8 0 0 6 0 6 10                                   3 0  4 10                                            3 0  9 5        2                                                            2                                                            3                                                            3 6 10    Blackgrass 9 10                   10                     8 10                         0 6 10                               9 10                                   9 9  2 10                                            10                                              10 10                                                   8        5                                                            8                                                            9                                                            9 9 10    Cheatgrass 9 10                   5 4 5 0 2 1 3 8 7 0  7 9 4 5  5 1        2                                                            3                                                            4                                                            6 2 6    Chickweed  10                 10                   --                     --                       --                         0 10                             10                               10                                 10                                   5 3  0 9 10                                              5  10                                                   5        5                                                            4                                                            4                                                            7 2 5    Cocklebur  0 3 3 3 0 0 0 0 --                                 7 0 0  0 0 10                                              0  0 0        0                                                            0                                                            0                                                            0 0 0    Corn       8 9 7 1 8 1 2 1 10                                 6 5 1  0 0 0 0  7 2        1                                                            3                                                            7                                                            2 2 6    Cotton     1 6 9 0 0 0 4 1 0 0 0 1  0 0 0 0  2 0        0                                                            0                                                            2                                                            0 0 1    Crabgrass  10                 10                   9 9 8 9 10                             9 9 10                                   10                                     9  10                                          10                                            10                                              10 10                                                   10       9                                                            10                                                            10                                                            10                                                              10                                                                10    Giant foxtail               9 10                   1 8 9 2 10                             10                               9 10                                   9 7  9 10                                            10                                              9  9 7        7                                                            10                                                            9                                                            10                                                              10                                                                10    Lambsquarters               10                 10                   10                     9 9 0 10                             10                               10                                 10                                   9 -- --                                          10                                            10                                              10 10                                                   5        6                                                            8                                                            2                                                            8 7 9    Morningglory               1 5 1 0 0 0 0 0 0 0 0 2  0 0 0 0  0 0        0                                                            0                                                            0                                                            1 0 0    Nutsedge   0 0 0 7 4 0 6 0 0 0 --                                     0  0 0 9 0  5 0        0                                                            0                                                            0                                                            0 0 9    Rape       2 5 6 2 0 0 0 0 0 1 1 0  0 0 5 0  2 0        0                                                            2                                                            0                                                            0 1 0    Rice       8 4 7 0 2 0 6 3 7 1 0 0  0 0 0 0  3 0        0                                                            0                                                            2                                                            2 4 1    Sorghum    7 5 3 2 8 0 7 3 1 8 4 1  0 6 9 6  4 0        2                                                            4                                                            4                                                            4 3 5    Soybean    1 3 0 1 0 0 0 0 0 0 0 1  0 0 0 0  1 0        0                                                            0                                                            4                                                            0 1 1    Sugar beet 5 5 8 2 1 0 0 2 0 2 2 0  0 0 6 0  9 2        2                                                            5                                                            6                                                            5 7 5    Velvetleaf 5 8 3 0 2 1 3 1 0 0 0 1  0 5 2 0  4 0        1                                                            0                                                            0                                                            1 2 0    Wheat      0 0 2 0 0 0 0 0 2 0 1 0  0 0 0 0  0 0        0                                                            2                                                            2                                                            1 0 4    Wild buckwheat               --                 0 --                     --                       --                         0 4 0 0 --                                   0 0  0 10                                            10                                              10 9 0        0                                                            0                                                            0                                                            0 0 4    Wild oat   9 10                   9 9 9 0 9 3 8 9 7 4  4 10                                            9 3  10                                                   2        2                                                            7                                                            7                                                            2 3 9    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               26                 27                   28                     29                       30                         31                           32                             33                               34                                 35                                   36                                     37 38                                          39                                            40                                              41 42                                                   43                                                     44                                                       45 46                                                            47                                                              48                                                                49    __________________________________________________________________________    PREEMERGENCE    Barley     0 0 1 0 9 0 0 0 1 0 0 0  1 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Barnyardgrass               10                 7 10                     10                       10                         10                           10                             9 10                                 10                                   10                                     10 10                                          10                                            0 10 9 0        7                                                            5                                                            9                                                            9 1 10    Bedstraw   2 0 4 3 5 8 7 2 5 0 5 7  9 5 0 2  3 --       8                                                            0                                                            5                                                            0 --                                                                --    Blackgrass 10                 7 10                     8 9 9 9 5 9 10                                   10                                     10 9 9 0 9  7 0        9                                                            10                                                            9                                                            5 0 8    Cheatgrass 6 2 9 6 9 7 8 5 7 7 7 9  9 8 0 7  5 0        7                                                            2                                                            3                                                            2 0 2    Chickweed  9 0 9 5 9 7 3 0 4 7 8 9  9 7 0 8  --                                                   --       3                                                            --                                                            --                                                            --                                                              0 7    Cocklebur  --                 0 4 0 2 1 0 0 0 0 0 1  0 1 0 -- 2 0        0                                                            2                                                            3                                                            0 0 0    Corn       8 3 2 7 9 9 7 7 7 9 8 8  9 9 0 10 8 0        5                                                            5                                                            2                                                            0 0 3    Cotton     2 0 0 0 8 2 9 2 5 5 7 8  6 5 0 3  0 0        2                                                            0                                                            0                                                            0 0 0    Crabgrass  10                 9 10                     10                       10                         10                           10                             10                               10                                 10                                   10                                     10 10                                          10                                            0 10 9 0        10                                                            9                                                            9                                                            8 5 10    Giant foxtail               10                 2 10                     10                       10                         10                           10                             9 10                                 10                                   10                                     10 10                                          10                                            0 10 9 0        10                                                            6                                                            10                                                            9 1 10    Lambsquarters               8 0 9 9 9 8 10                             3 6 9 9 9  10                                          9 0 8  7 0        8                                                            4                                                            8                                                            5 0 10    Morningglory               0 0 0 6 5 6 4 0 5 3 5 5  1 2 0 2  0 0        0                                                            0                                                            0                                                            0 0 2    Nutsedge   7 0 0 0 4 0 0 0 2 5 5 5  7 3 0 4  6 0        8                                                            0                                                            0                                                            0 0 0    Rape       1 0 3 2 6 5 3 0 1 3 5 4  9 4 0 1  1 0        3                                                            0                                                            1                                                            1 0 2    Rice       0 0 1 2 7 2 1 2 3 2 4 6  6 2 0 4  0 0        2                                                            0                                                            0                                                            0 0 2    Sorghum    8 2 6 9 9 9 9 6 9 9 9 9  9 9 0 2  8 0        6                                                            0                                                            5                                                            0 0 10    Soybean    2 0 0 1 8 3 2 2 3 2 4 6  6 5 0 8  0 0        2                                                            0                                                            2                                                            0 0 0    Sugar beet 6 0 2 7 6 6 3 0 0 5 7 7  9 3 0 5  5 0        0                                                            0                                                            0                                                            1 0 8    Velvetleaf 3 0 0 1 5 1 1 0 2 1 3 5  7 1 0 1  0 0        0                                                            1                                                            0                                                            0 0 2    Wheat      0 0 3 1 5 0 1 0 2 0 1 1  1 0 0 3  2 0        2                                                            0                                                            0                                                            2 0 2    Wild buckwheat               5 2 5 5 7 8 10                             0 5 7 1 7  10                                          6 0 5  6 0        --                                                            0                                                            0                                                            0 --                                                                --    Wild oat   8 0 9 6 9 9 9 4 7 9 9 8  9 9 0 10 6 0        8                                                            9                                                            9                                                            3 0 5    __________________________________________________________________________               COMPOUND    Rate (400 g/ha)               50                 51                   52                     53                       54                         55                           56                             57                               58                                 59                                   61                                     62 63                                          64                                            65                                              66 67                                                   68                                                     69                                                       70 71                                                            72                                                              73                                                                74    __________________________________________________________________________    PREEMERGENCE    Barley     2 0 0 0 0 0 2 3 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Barnyardgrass               10                 0 3 10                       9 7 10                             10                               0 10                                   3 5  0 0 0 0  5 8        0                                                            0                                                            0                                                            0 0 10    Bedstraw   9 --                   --                     9 8 7 --                             1 0 2 0 0  0 0 0 -- 0 0        0                                                            0                                                            0                                                            0 0 5    Blackgrass 9 0 0 9 0 2 10                             10                               9 8 9 10 2 2 0 2  0 9        0                                                            0                                                            0                                                            0 0 9    Cheatgrass 7 0 0 2 2 3 3 9 3 7 2 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 8    Chickweed  5 0 0 3 4 5 9 10                               7 3 0 8  0 0 0 0  0 3        0                                                            0                                                            0                                                            0 0 10    Cocklebur  0 0 0 0 0 0 0 1 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Corn       5 0 2 3 1 1 4 4 2 1 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 7    Cotton     0 0 0 0 0 0 0 0 5 4 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 3    Crabgrass  10                 0 3 10                       10                         9 10                             10                               9 9 9 10 0 7 0 0  9 9        0                                                            0                                                            0                                                            0 0 9    Giant foxtail               9 2 4 10                       10                         9 10                             10                               7 9 9 10 0 0 0 0  4 8        0                                                            0                                                            0                                                            0 0 10    Lambsquarters               8 --                   0 10                       10                         9 10                             10                               10                                 8 0 10 0 0 0 0  0 7        0                                                            0                                                            0                                                            0 0 10    Morningglory               0 0 2 1 1 2 4 5 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 5    Nutsedge   0 0 0 0 0 0 0 2 4 0 0 0  0 0 0 0  0 0        0                                                            0                                                            --                                                            0 0 2    Rape       0 6 0 2 0 3 7 9 0 7 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 7    Rice       7 0 1 2 0 0 1 2 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Sorghum    8 0 1 7 3 2 9 9 0 4 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 9    Soybean    2 0 0 1 0 0 2 3 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 2    Sugar beet 0 --                   0 10                       3 2 7 4 0 2 0 0  0 0 0 0  0 1        0                                                            0                                                            0                                                            0 0 7    Velvetleaf 2 0 0 2 1 1 1 2 0 2 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 1    Wheat      6 0 0 0 2 0 4 0 0 0 0 2  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 3    Wild buckwheat               8 4 --                     10                       10                         10                           --                             4 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            --                                                            0 0 10    Wild oat   9 0 0 7 6 0 7 6 2 9 0 5  0 0 0 0  0 2        0                                                            0                                                            0                                                            0 0 9    __________________________________________________________________________                             COMPOUND                  Rate (200 g/ha)                             60    __________________________________________________________________________                  POSTEMERGENCE                  Barley     0                  Barnyardgrass                             0                  Bedstraw   3                  Blackgrass 0                  Cheatgrass 0                  Chickweed  --                  Cocklebur  0                  Corn       0                  Cotton     0                  Crabgrass  2                  Giant foxtail                             0                  Lambsquarters                             0                  Morningglory                             0                  Nutsedge   0                  Rape       0                  Rice       0                  Sorghum    0                  Soybean    0                  Sugar beet 0                  Velvetleaf 0                  Wheat      0                  Wild buckwheat                             5                  Wild oat   0                  PREEMERGENCE                  Barley     0                  Barnyardgrass                             3                  Bedstraw   0                  Blackgrass 0                  Cheatgrass 0                  Chickweed  0                  Cocklebur  0                  Corn       0                  Cotton     0                  Crabgrass  3                  Giant foxtail                             2                  Lambsquarters                             0                  Morningglory                             0                  Nutsedge   0                  Rape       0                  Rice       0                  Sorghum    0                  Soybean    0                  Sugar beet 0                  Velvetleaf 0                  Wheat      0                  Wild buckwheat                             --                  Wild oat   0    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               1 2 3 4 5 6 7 8 9 10                                   11                                     12 13                                          14                                            15                                              16 17                                                   18                                                     19                                                       20 21                                                            22                                                              23                                                                24    __________________________________________________________________________    POSTEMERGENCE    Barley     0 2 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               3 5 8 1 2 0 0 2 0 6 0 2  0 0 5 1  1 8        0                                                            0                                                            1                                                            1 0 2    Bedstraw   2 1 0 0 1 0 1 0 0 0 0 0  2 0 0 0  0 0        2                                                            2                                                            2                                                            --                                                              --                                                                1    Blackgrass 0 2 2 2 0 0 2 0 1 0 0 0  0 0 0 0  7 --       0                                                            0                                                            1                                                            1 2 0    Cheatgrass 0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Chickweed  1 2 0 0 0 0 --                             0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Cocklebur  0 0 0 0 0 0 0 1 --                                 0 0 1  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Corn       2 3 1 0 0 0 1 1 1 0 0 0  0 0 0 0  0 2        0                                                            0                                                            0                                                            0 0 0    Cotton     0 0 0 0 2 0 --                             1 3 2 0 1  0 0 4 2  1 4        0                                                            0                                                            0                                                            0 0 0    Crabgrass  0 5 6 0 0 0 0 0 0 0 0 0  0 0 1 5  2 2        0                                                            0                                                            2                                                            1 1 1    Giant foxtail               0 0 0 0 0 0 0 0 0 0 0 1  0 0 0 1  0 4        0                                                            0                                                            0                                                            0 0 0    Lambsquarters               1 --                   2 0 0 0 0 2 0 0 0 0  0 0 0 -- 0 4        0                                                            0                                                            0                                                            --                                                              1 0    Morningglory               1 4 3 2 0 0 1 1 0 2 0 3  0 0 7 2  2 3        2                                                            1                                                            1                                                            1 1 0    Nutsedge   0 0 0 --                       0 0 0 --                               0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Rape       1 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 4        0                                                            0                                                            0                                                            0 0 0    Rice       0 0 3 0 0 0 1 0 0 0 0 0  0 0 3 2  2 3        0                                                            0                                                            0                                                            0 0 0    Sorghum    0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Soybean    1 1 2 1 3 0 2 1 0 2 0 1  0 0 3 3  2 5        1                                                            1                                                            1                                                            1 1 0    Sugar beet 1 0 0 0 0 0 0 0 0 1 0 0  0 0 0 0  0 3        0                                                            0                                                            0                                                            0 0 0    Velvetleaf 0 1 3 2 3 0 1 0 0 0 0 0  0 0 0 -- 0 0        1                                                            1                                                            0                                                            1 0 0    Wheat      0 2 0 0 0 0 --                             0 --                                 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Wild buckwheat               --                 --                   --                     0 --                         0 --                             --                               --                                 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Wild oat   0 1 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               25                 26                   28                     29                       30                         31                           32                             33                               34                                 35                                   36                                     37 38                                          39                                            41                                              42 43                                                   44                                                     45                                                       46 47                                                            48                                                              49                                                                50    __________________________________________________________________________    POSTEMERGENCE    Barley     0 0 0 0 2 2 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               1 0 2 2 9 9 8 0 0 7 2 8  7 2 6 5  0 0        4                                                            1                                                            0                                                            0 4 8    Bedstraw   3 2 0 3 1 1 3 1 1 2 2 2  3 2 2 3  0 2        0                                                            1                                                            0                                                            0 0 --    Blackgrass 1 0 0 2 5 3 0 0 1 0 1 1  3 2 0 2  0 0        1                                                            0                                                            0                                                            0 0 3    Cheatgrass 0 0 0 0 2 0 0 0 0 0 0 2  3 0 0 2  0 0        0                                                            0                                                            0                                                            0 0 0    Chickweed  0 0 2 0 0 0 0 0 0 0 0 0  2 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Cocklebur  0 1 0 0 0 0 0 0 0 0 0 0  --                                          0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Corn       0 0 0 1 2 0 0 0 0 3 1 4  2 2 4 2  0 0        2                                                            0                                                            0                                                            0 2 2    Cotton     0 5 2 0 7 1 0 2 0 2 0 0  0 0 3 0  0 0        1                                                            0                                                            0                                                            0 0 0    Crabgrass  0 3 7 6 6 8 6 1 4 2 2 4  5 --                                            0 2  0 2        0                                                            0                                                            0                                                            0 9 7    Giant foxtail               2 0 2 1 5 7 8 0 2 1 2 2  5 4 2 4  0 0        0                                                            0                                                            0                                                            0 6 7    Lambsquarters               0 0 0 0 1 0 0 0 --                                 0 0 0  --                                          --                                            --                                              0  0 --       0                                                            0                                                            0                                                            0 0 0    Morningglory               0 2 2 2 2 1 1 1 1 1 5 3  0 2 1 6  0 4        0                                                            0                                                            0                                                            0 0 0    Nutsedge   0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Rape       0 0 0 0 0 0 0 0 0 0 0 0  1 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Rice       0 0 1 0 5 2 1 1 2 2 2 2  3 2 3 3  0 2        2                                                            0                                                            0                                                            0 5 4    Sorghum    0 0 0 0 2 1 2 0 0 1 0 2  2 0 --                                              2  0 0        3                                                            0                                                            0                                                            0 1 3    Soybean    0 4 2 0 4 2 0 1 3 3 2 3  2 1 3 2  0 3        3                                                            0                                                            0                                                            0 1 0    Sugar beet 0 0 0 0 0 0 0 0 0 0 0 0  2 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Velvetleaf 0 0 1 0 2 0 0 0 1 0 0 0  1 0 2 0  0 2        0                                                            0                                                            0                                                            0 1 0    Wheat      0 0 0 0 2 2 0 0 0 0 0 0  0 0 0 3  0 0        0                                                            0                                                            0                                                            0 0 2    Wild buckwheat               0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  --                                                   0        0                                                            0                                                            0                                                            0 0 0    Wild oat   0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               51                 52                   53                     54                       55                         56                           57                             58                               59                                 61                                   62                                     63 64                                          65                                            66                                              67 68                                                   69                                                     70                                                       71 72                                                            73                                                              74    __________________________________________________________________________    POSTEMERGENCE    Barley     0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Barnyardgrass               0 0 6 0 0 7 2 1 0 0 0 0  0 0 0 0  0 0        2                                                            0                                                            0                                                            0 6    Bedstraw   0 0 2 0 2 5 0 --                               2 3 1 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 4    Blackgrass 0 0 2 2 0 2 0 0 1 2 2 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 2    Cheatgrass 0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Chickweed  0 0 --                     --                       3 --                           --                             --                               0 1 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 --    Cocklebur  0 0 2 0 0 2 0 3 0 0 0 0  0 0 0 0  0 0        2                                                            0                                                            0                                                            0 0    Corn       0 0 2 0 0 4 4 0 0 0 0 0  0 0 0 0  0 0        1                                                            0                                                            0                                                            0 2    Cotton     0 0 0 0 0 1 2 0 2 0 0 0  0 0 0 0  0 0        --                                                            0                                                            0                                                            0 2    Crabgrass  0 0 8 5 0 8 3 0 3 0 0 0  0 0 0 0  0 --       2                                                            0                                                            0                                                            0 4    Giant foxtail               0 0 5 3 0 7 1 0 0 0 0 0  0 0 0 0  0 0        1                                                            0                                                            0                                                            0 2    Lambsquarters               0 0 7 0 0 2 0 0 1 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 1    Morningglory               0 0 2 1 0 5 2 3 2 2 2 0  0 0 0 2  0 0        1                                                            0                                                            0                                                            0 5    Nutsedge   0 0 0 0 0 2 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Rape       0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Rice       0 0 7 5 0 6 1 0 1 0 0 0  0 0 0 0  0 0        2                                                            0                                                            0                                                            0 3    Sorghum    0 0 4 1 0 2 3 0 0 0 0 0  0 0 0 0  0 0        2                                                            0                                                            0                                                            0 1    Soybean    0 0 1 0 0 5 1 1 1 0 0 0  0 0 0 2  0 0        2                                                            0                                                            0                                                            0 4    Sugar beet 0 0 0 0 0 0 1 0 0 2 0 0  0 0 0 0  0 0        --                                                            0                                                            0                                                            0 0    Velvetleaf 0 0 0 0 0 2 1 3 1 0 0 0  0 0 0 0  0 0        2                                                            0                                                            0                                                            0 1    Wheat      0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Wild buckwheat               0 0 0 0 0 --                           0 2 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Wild oat   0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               1 2 3 4 5 6 7 8 9 10                                   11                                     12 13                                          14                                            15                                              16 17                                                   18                                                     19                                                       20 21                                                            22                                                              23                                                                24    __________________________________________________________________________    PREEMERGENCE    Barley     0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               6 6 10                     2 9 1 6 2 6 9 9 0  1 0 8 6  2 5        1                                                            0                                                            2                                                            6 3 5    Bedstraw   0 0 7 --                       0 0 0 0 4 10                                   --                                     3  0 0 3 3  0 6        0                                                            0                                                            0                                                            0 0 0    Blackgrass 2 3 10                     4 8 0 3 4 6 10                                   10                                     10 5 --                                            10                                              7  9 10       2                                                            3                                                            5                                                            5 1 6    Cheatgrass 0 2 0 2 0 0 1 1 1 5 0 0  0 0 3 0  2 2        0                                                            0                                                            0                                                            0 1 0    Chickweed  0 2 --                     --                       0 0 10                             0 4 8 0 0  0 0 9 0  0 10       0                                                            0                                                            0                                                            0 0 0    Cocklebur  0 2 0 0 0 0 0 0 0 0 --                                     0  0 0 0 0  0 0        0                                                            --                                                            0                                                            0 0 0    Corn       0 2 0 0 2 0 0 0 10                                 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            2 0 0    Cotton     0 0 0 0 0 0 2 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Crabgrass  8 10                   9 5 6 2 5 2 4 10                                   9 6  8 6 9 9  9 9        7                                                            9                                                            8                                                            9 9 5    Giant foxtail               3 7 0 2 6 0 1 3 1 9 9 6  0 6 9 7  6 9        2                                                            6                                                            3                                                            3 2 2    Lambsquarters               10                 10                   9 0 8 --                           10                             10                               10                                 9 0 8  0 0 10                                              5  10                                                   10       0                                                            0                                                            2                                                            2 0 0    Morningglory               0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Nutsedge   0 0 0 0 --                         0 --                             0 0 0 0 0  --                                          0 --                                              0  0 0        0                                                            0                                                            0                                                            0 0 0    Rape       0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Rice       2 0 2 0 0 0 2 2 2 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Sorghum    3 2 0 0 0 0 0 0 0 2 0 0  0 0 0 0  0 2        0                                                            0                                                            0                                                            0 0 0    Soybean    0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Sugar beet 0 2 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 1        0                                                            0                                                            2                                                            2 0 6    Velvetleaf 0 1 0 0 0 0 0 0 0 0 0 0  0 0 3 2  0 2        0                                                            0                                                            0                                                            0 0 0    Wheat      0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Wild buckwheat               --                 0 --                     --                       --                         0 0 0 --                                 --                                   --                                     3  0 0 0 3  0 2        0                                                            0                                                            0                                                            0 0 0    Wild oat   7 8 5 6 4 0 3 2 2 7 0 3  0 0 8 9  2 4        0                                                            0                                                            0                                                            0 2 0    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               25                 26                   28                     29                       30                         31                           32                             33                               34                                 35                                   36                                     37 38                                          39                                            41                                              42 43                                                   44                                                     45                                                       46 47                                                            48                                                              49                                                                50    __________________________________________________________________________    PREEMERGENCE    Barley     0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Barnyardgrass               7 9 3 8 9 9 9 5 8 8 9 9  10                                          9 7 7  0 2        2                                                            8                                                            2                                                            0 8 7    Bedstraw   0 0 2 0 0 0 0 0 0 0 --                                     3  7 0 0 0  0 0        0                                                            0                                                            --                                                            --                                                              0 2    Blackgrass 3 7 9 4 9 2 9 0 8 5 8 8  9 7 9 8  0 6        2                                                            2                                                            0                                                            0 3 7    Cheatgrass 0 2 2 3 5 0 0 2 2 6 6 4  7 6 6 5  0 0        0                                                            0                                                            0                                                            0 2 7    Chickweed  1 5 4 7 --                         0 2 0 0 2 4 3  8 0 0 -- 0 --       --                                                            0                                                            0                                                            0 0 --    Cocklebur  0 --                   0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 --                                                                0    Corn       1 1 0 3 0 0 0 3 2 2 2 2  8 3 2 0  0 0        0                                                            0                                                            0                                                            0 0 0    Cotton     0 1 0 0 0 0 2 --                               --                                 2 5 -- 0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Crabgrass  9 9 10                     9 10                         9 10                             9 9 9 9 10 10                                          10                                            10                                              8  0 10       6                                                            8                                                            5                                                            4 10                                                                7    Giant foxtail               3 7 6 9 10                         9 9 9 9 9 9 10 9 9 9 7  0 9        3                                                            4                                                            4                                                            0 9 8    Lambsquarters               2 5 5 7 9 0 8 0 5 --                                   --                                     9  9 7 2 5  0 4        0                                                            0                                                            0                                                            0 8 2    Morningglory               0 0 0 0 2 0 1 0 2 0 2 3  0 2 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Nutsedge   4 7 0 0 0 0 0 0 0 0 0 2  0 0 10                                              0  0 0        0                                                            0                                                            --                                                            0 0 0    Rape       0 0 0 0 2 0 0 0 0 1 0 0  3 1 0 1  0 0        0                                                            0                                                            0                                                            0 0 0    Rice       0 0 0 0 4 5 0 0 0 2 0 3  0 0 2 0  0 0        0                                                            0                                                            0                                                            0 0 4    Sorghum    0 2 2 2 8 6 7 2 2 4 2 8  8 3 1 0  0 0        0                                                            0                                                            0                                                            0 0 5    Soybean    0 0 0 0 0 0 0 0 0 2 2 3  1 2 0 0  0 1        0                                                            0                                                            0                                                            0 0 0    Sugar beet 0 2 0 0 5 0 0 0 0 2 3 6  5 1 2 4  0 0        0                                                            0                                                            0                                                            0 0 0    Velvetleaf 0 1 0 0 2 0 0 0 0 0 0 1  2 1 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Wheat      0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0 0    Wild buckwheat               0 0 0 0 0 7 0 --                               0 0 0 0  6 3 0 0  0 5        --                                                            0                                                            0                                                            --                                                              0 0    Wild oat   2 5 0 4 7 3 7 0 2 7 4 4  9 5 8 4  0 2        0                                                            6                                                            0                                                            0 0 5    __________________________________________________________________________               COMPOUND    Rate (100 g/ha)               51                 52                   53                     54                       55                         56                           57                             58                               59                                 61                                   62                                     63 64                                          65                                            66                                              67 68                                                   69                                                     70                                                       71 72                                                            73                                                              74    __________________________________________________________________________    PREEMERGENCE    Barley     0 0 0 0 0 2 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Barnyardgrass               0 2 9 5 2 9 4 0 7 0 2 0  0 0 0 0  1 0        0                                                            0                                                            0                                                            0 5    Bedstraw   --                 0 10                     5 2 --                           0 --                               --                                 0 0 0  0 --                                            0 0  0 0        0                                                            0                                                            0                                                            0 --    Blackgrass 0 0 2 0 2 6 5 0 2 6 6 0  0 0 0 0  9 0        0                                                            0                                                            0                                                            0 3    Cheatgrass 0 0 2 0 2 3 6 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 2    Chickweed  0 0 2 0 0 3 5 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 9    Cocklebur  --                 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Corn       0 0 0 0 0 2 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 1    Cotton     0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Crabgrass  0 0 9 8 8 10                           7 5 8 2 6 0  4 0 0 6  8 0        0                                                            0                                                            0                                                            0 9    Giant foxtail               0 0 8 5 9 9 3 7 5 3 3 0  0 0 0 2  2 0        0                                                            0                                                            0                                                            0 9    Lambsquarters               --                 0 10                     2 4 9 8 5 --                                 0 4 0  0 --                                            0 0  0 0        0                                                            0                                                            0                                                            0 8    Morningglory               0 0 0 0 0 2 1 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 4    Nutsedge   0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Rape       0 0 0 0 0 0 0 0 0 0 0 0  0 --                                            0 0  0 0        0                                                            0                                                            0                                                            0 0    Rice       0 0 0 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Sorghum    0 0 0 0 0 6 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 2    Soybean    0 0 0 0 0 1 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Sugar beet 3 0 10                     0 0 1 --                             --                               0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 2    Velvetleaf 0 0 0 0 0 2 1 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Wheat      0 0 3 0 0 0 0 0 0 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 0    Wild buckwheat               --                 --                   10                     10                       0 3 --                             0 0 0 0 0  0 --                                            0 0  0 0        0                                                            0                                                            0                                                            0 8    Wild oat   0 0 4 0 0 5 2 0 2 0 0 0  0 0 0 0  0 0        0                                                            0                                                            0                                                            0 3    __________________________________________________________________________                             COMPOUND                  Rate (50 g/ha)                             60    __________________________________________________________________________                  POSTEMERGENCE                  Barley     0                  Barnyardgrass                             0                  Bedstraw   2                  Blackgrass 0                  Cheatgrass 0                  Chickweed  --                  Cocklebur  0                  Corn       0                  Cotton     0                  Crabgrass  0                  Giant foxtail                             0                  Lambsquarters                             0                  Morningglory                             0                  Nutsedge   0                  Rape       0                  Rice       0                  Sorghum    0                  Soybean    0                  Sugar beet 0                  Velvetleaf 0                  Wheat      0                  Wild buckwheat                             3                  Wild oat   0                  PREEMERGENCE                  Barley     0                  Barnyardgrass                             0                  Bedstraw   0                  Blackgrass 0                  Cheatgrass 0                  Chickweed  0                  Cocklebur  0                  Corn       0                  Cotton     0                  Crabgrass  0                  Giant foxtail                             0                  Lambsquarters                             0                  Morningglory                             0                  Nutsedge   0                  Rape       0                  Rice       0                  Sorghum    0                  Soybean    0                  Sugar beet --                  Velvetleaf 0                  Wheat      0                  Wild buckwheat                             0                  Wild oat   0    __________________________________________________________________________

TEST C

The compounds evaluated in this test were formulated in a non-phytoxicsolvent and applied to the soft surface before plant seedlings emerged(proemergence application), to water that covered the soft surface(flood application), and to plants that were in the one-to-four leafstage (postemergence application). A sandy loam soft was used for theproemergence and postemergence tests, while a silt loam soil was used inthe flood test. Water depth was approximately 2.5 cm for the flood testand was maintained at this level for the duration of the test.

Plant species in the proemergence and postemergence tests consisted ofbarley (Hordeum vulgare), bedstraw (Galium aparine), blackgrass(Alopecurus myosuroides), chickweed (Stellaria media), corn (Zea mays),cotton (Gossypium hirsutum), crabgrass (Digitaria sanguinalis), downybrome (Bromus tectorum), giant foxtail (Setaria faberii), lambsquarters(Chenopodium album), morningglory (Ipomoea hederacea), pigweed(Amaranthus retroflexus), rape (Brassica napus), ryegrass (Loliummultiflorum), sorghum (Sorghum bicolor), soybean (Glycine max),speedwell (Veronica persica), sugar beet (Beta vulgaris), velvefleaf(Abutilon theophrasti), wheat (Triticum aestivum), wild buckwheat(Polygonum convolvulus), and wild oat (Avena fatua). All plant specieswere planted one day before application of the compound for theproemergence portion of this test. Plantings of these species wereadjusted to produce plants of appropriate size for the postemergenceportion of the test. Plant species in the flood test consisted ofbarnyardgrass (Echinochloa crusgalli), rice (Oryza saliva), umbrellasedge (Cyperus difformis) and duck salad (Heteranthera limosa).

All plant species were grown using normal greenhouse practices. Visualevaluations of injury expressed on treated plants, when compared tountreated controls, were recorded approximately fourteen to twenty onedays after application of the test compound. Plant response ratings,summarized in Table C, were recorded on a 0 to 10 scale where 0 is noeffect and I 0 is complete control. A dash (-) response means no testresult.

                                      TABLE C    __________________________________________________________________________                                  COMPOUND             Rate (1000 g/ha)     1 2    __________________________________________________________________________             POSTEMERGENCE             Barley Igri          --                                    --             Bedstraw             --                                    --             Blackgrass           --                                    --             Chickweed            --                                    --             Corn                 --                                    --             Cotton               --                                    --             Crabgrass            --                                    --             Downy brome          --                                    --             Duck salad            5                                     3             Giant foxtail        --                                    --             Lambsquarters        --                                    --             Morningglory         --                                    --             Pigweed              --                                    --             Rape                 --                                    --             Ryegrass             --                                    --             Sorghum              --                                    --             Soybean              --                                    --             Speedwell            --                                    --             Sugar beet           --                                    --             Velvetleaf           --                                    --             Wheat                --                                    --             Wild buckwheat       --                                    --             Wild oat             --                                    --             Barnyardgrass         9                                     9             Rice Japonica         8                                     8             Umbrella sedge        0                                     0    __________________________________________________________________________                                  COMPOUND             Rate (1000 g/ha)     1 2    __________________________________________________________________________             PREEMERGENCE             Barley Igri           3                                     2             Bedstraw             10                                    10             Blackgrass           10                                    10             Chickweed            10                                    10             Corn                  8                                     7             Cotton                7                                    10             Crabgrass            10                                    10             Downy brome           7                                    10             Duck salad           --                                    --             Giant foxtail        10                                    10             Lambsquarters        10                                    10             Morningglory         10                                    10             Pigweed              10                                    10             Rape                  4                                     0             Ryegrass             10                                    10             Sorghum              10                                    10             Soybean               5                                     6             Speedwell            10                                    10             Sugar beet           10                                    10             Velvetleaf           10                                    10             Wheat                 6                                     5             Wild buckwheat       10                                    10             Wild oat             10                                    10             Barnyardgrass        --                                    --             Rice Japonica        --                                    --             Umbrella sedge       --                                    --    __________________________________________________________________________               COMPOUND    Rate (500 g/ha)               1     2  7     10 11    15 18    26 41    __________________________________________________________________________    POSTEMERGENCE    Barley Igri               --    -- --    -- --    -- --    -- --    Bedstraw   --    -- --    -- --    -- --    -- --    Blackgrass --    -- --    -- --    -- --    -- --    Chickweed  --    -- --    -- --    -- --    -- --    Corn       --    -- --    -- --    -- --    -- --    Cotton     --    -- --    -- --    -- --    -- --    Crabgrass  --    -- --    -- --    -- --    -- --    Downy brome               --    -- --    -- --    -- --    -- --    Duck salad 4     0  0     9  9     9  9     0  2    Giant foxtail               --    -- --    -- --    -- --    -- --    Lambsquarters               --    -- --    -- --    -- --    -- --    Morningglory               --    -- --    -- --    -- --    -- --    Pigweed    --    -- --    -- --    -- --    -- --    Rape       --    -- --    -- --    -- --    -- --    Ryegrass   --    -- --    -- --    -- --    -- --    Sorghum    --    -- --    -- --    -- --    -- --    Soybean    --    -- --    -- --    -- --    -- --    Speedwell  --    -- --    -- --    -- --    -- --    Sugar beet --    -- --    -- --    -- --    -- --    Velvetleaf --    -- --    -- --    -- --    -- --    Wheat      --    -- --    -- --    -- --    -- --    Wild buckwheat               --    -- --    -- --    -- --    -- --    Wild oat   --    -- --    -- --    -- --    -- --    Barnyardgrass               9     9  6     10 10    10 10    9  9    Rice Jamonica               8     8  7     9  9     8  8     9  8    Umbrella sedge               0     0  0     9  9     9  9     7  8    __________________________________________________________________________               COMPOUND    Rate (500 g/ha)               1     2  7     10 11    15 18    26 41    __________________________________________________________________________    PREEMERGENCE    Barley Igri               2     0  2     2  2     2  2     3  5    Bedstraw   10    10 10    9  5     8  9     2  10    Blackgrass 10    10 10    8  6     9  9     10 10    Chickweed  10    10 10    7  2     5  8     6  7    Corn       6     6  0     5  6     8  10    0  6    Cotton     6     6  7     0  --    8  7     0  7    Crabgrass  10    10 10    10 10    10 10    10 10    Downy brome               3     4  5     5  5     5  7     6  6    Duck salad --    -- --    -- --    -- --    -- --    Giant foxtail               10    10 10    10 10    10 10    10 10    Lambsquarters               10    10 10    10 10    8  10    9  10    Morningglory               10    7  0     7  2     7  8     0  0    Pigweed    10    10 10    7  8     8  9     8  8    Rape       0     0  7     4  3     7  7     2  8    Ryegrass   10    10 7     8  8     9  9     9  9    Sorghum    10    10 9     10 10    10 10    10 10    Soybean    1     4  0     2  0     2  4     0  3    Speedwell  10    10 10    10 10    8  10    6  10    Sugar beet 10    9  9     8  5     7  9     6  7    Velvetleaf 8     8  8     7  6     8  9     5  5    Wheat      5     4  2     2  2     1  2     4  6    Wild buckwheat               10    9  8     8  0     5  8     0  6    Wild oat   10    10 10    8  6     7  9     9  9    Barnyardgrass               --    -- --    -- --    -- --    -- --    Rice Japonica               --    -- --    -- --    -- --    -- --    Umbrella sedge               --    -- --    -- --    -- --    -- --    __________________________________________________________________________               COMPOUND    Rate (250 g/ha)               1 2 7 10                       11                         15                           18 26                                30                                  32                                    34 35                                         36                                           37                                             38 39                                                  41                                                    42                                                      44    __________________________________________________________________________    POSTEMERGENCE    Barley Igri               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Bedstraw   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Blackgrass --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Chickweed  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Corn       --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Cotton     --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Crabgrass  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Downy brome               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Duck salad 0 0 0 9 9 9 0  0 0 2 2  0 2 7 7  0 1 2  0    Giant foxtail               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Lambsquarters               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Morningglory               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Pigweed    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Rape       --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Ryegrass   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Sorghum    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Soybean    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Speedwell  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Sugar beet --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Velvetleaf --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wheat      --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wild buckwheat               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wild oat   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Barnyardgrass               8 8 5 10                       10                         10                           10 9 9 8 9  9 9 9 9  9 9 9  9    Rice Japonica               8 8 6 9 8 8 8  8 7 7 8  8 8 8 8  7 8 8  8    Umbrella sedge               0 0 0 9 9 9 9  0 0 3 8  5 9 9 9  3 0 0  0    __________________________________________________________________________               COMPOUND    Rate (250 g/ha)               1 2 7 10                       11                         15                           18 26                                30                                  32                                    34 35                                         36                                           37                                             38 39                                                  41                                                    42                                                      44    __________________________________________________________________________    PREEMERGENCE    Barley lgri               0 0 0 0 0 0 2  2 1 0 1  0 1 2 2  0 2 1  1    Bedstraw   5 10                   10                     5 2 6 8  0 7 5 1  5 10                                           10                                             7  0 10                                                    4  0    Blackgrass 10                 10                   8 7 4 9 9  10                                10                                  10                                    4  10                                         10                                           9 9  10                                                  10                                                    9  9    Chickweed  10                 10                   10                     5 0 3 7  5 10                                  5 4  9 5 10                                             7  7 5 9  5    Corn       5 4 0 5 5 6 8  0 6 2 2  2 5 6 1  4 5 7  6    Cotton     3 5 5 0 0 8 2  0 8 0 2  4 3 7 0  4 0 2  0    Crabgrass  10                 10                   10                     10                       10                         10                           10 10                                10                                  10                                    10 10                                         10                                           10                                             10 10                                                  10                                                    10 10    Downy brome               --                 4 2 2 3 3 5  3 6 2 2  6 6 7 6  2 5 3  1    Duck salad --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Giant foxtail               9 10                   10                     10                       10                         10                           10 10                                10                                  10                                    9  10                                         10                                           10                                             10 10                                                  10                                                    10 10    Lambsquarters               10                 10                   7 9 5 8 10 8 10                                  8 3  10                                         10                                           9 9  10                                                  8 9  9    Morningglory               8 7 0 2 0 3 7  0 10                                  7 0  0 0 4 0  0 0 2  3    Pigweed    9 9 6 7 8 8 8  5 9 8 0  7 6 1 2  7 8 7  8    Rape       0 0 0 2 0 3 3  0 7 4 0  2 0 2 2  0 2 0  0    Ryegrass   10                 7 3 3 3 6 8  3 10                                  8 2  10                                         10                                           9 4  9 4 7  6    Sorghum    10                 10                   4 9 9 10                           10 10                                10                                  9 5  10                                         10                                           7 10 6 10                                                    10 10    Soybean    0 0 0 0 0 0 2  0 4 1 3  0 1 4 0  0 0 2  0    Speedwell  10                 10                   10                     10                       8 --                           10 2 7 5 10 7 3 10                                             10 7 7 10 10    Sugar beet 9 9 7 7 2 7 9  3 8 5 3  7 2 8 6  2 6 10 3    Velvetleaf 7 7 5 5 4 7 8  2 8 8 0  8 7 9 0  6 3 7  8    Wheat      3 1 0 2 2 0 2  2 5 3 2  0 4 3 4  0 5 5  2    Wild buckwheat               5 9 7 5 0 5 7  0 5 0 0  3 2 6 4  0 3 1  0    Wild oat   8 7 4 7 2 7 9  9 10                                  9 0  1 7 7 5  7 7 9  9    Barnyardgrass               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Rice Japonica               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Umbrella sedge               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    __________________________________________________________________________               COMPOUND    Rate (125 g/ha)               1 2 3 5 7 10                           11                             15                               18                                 26                                   30                                     32                                       34                                         35                                           36                                             37                                               38                                                 39                                                   41                                                     42                                                       44    __________________________________________________________________________    POSTEMERGENCE    Barley Igri               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Bedstraw   --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Blackgrass --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Chickweed  --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Corn       --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Cotton     --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Crabgrass  --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Downy brome               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Duck salad 0 0 0 0 0 9 2 8 0 0 0 1 0 0 0 3 2 0      0                                                 1      0    Giant foxtail               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Lambsquarters               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Morningglory               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Pigweed    --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Rape       --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Ryegrass   --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Sorghum    --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Soybean    --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Speedwell  --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Sugar beet --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Velvetleaf --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Wheat      --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Wild buckwheat               --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Wild oat   --                 --                   --                     --                       --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --     --                                                 --     --    Barnyardgrass               8 8 9 8 0 10                           9 9 9 8 9 8 9 8 9 8 9 8      8                                                 9      4    Rice Japonica               7 6 8 7 5 9 6 6 7 7 6 7 8 7 7 8 8 6      8                                                 8      7    Umbrella sedge               0 0 0 9 0 9 9 9 8 0 0 2 0 0 6 0 7 0      0                                                 0      0    __________________________________________________________________________               COMPOUND    Rate (125 g/ha)               1 2 3   7 10                           11                             15                               18                                 26                                   30                                     32                                       34                                         35                                           36                                             37                                               38                                                 39                                                   41                                                     42                                                       44    __________________________________________________________________________    PREEMERGENCE    Barley Igri               0 0 0   0 0 0 0 0 0 0 0 1 0 0 0 0 0 0    0                                                   0    Bedstraw   0 6 6   4 2 0 5 8 0 5 3 0 2 10                                             6 5 0 5    2                                                   0    Blackgrass 2 10                   10  5 5 3 8 9 9 10                                     10                                       2 9 7 9 9 7 9    9                                                   9    Chickweed  5 8 9   9 3 0 0 6 2 9 3 1 5 5 9 6 2 2    9                                                   2    Corn       0 0 6   0 3 4 5 5 0 3 0 2 2 5 4 0 1 5    4                                                   1    Cotton     0 4 5   3 0 0 3 0 0 5 0 2 4 2 5 0 3 0    0                                                   0    Crabgrass  10                 10                   10  9 10                           10                             10                               10                                 10                                   9 10                                       9 10                                           10                                             10                                               10                                                 10                                                   10   10                                                   10    Downy brome               0 4 3   0 0 0 2 3 2 4 0 0 3 4 5 4 2 2    2                                                   0    Duck salad --                 --                   --  --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --                                                   --   --                                                   --    Giant foxtail               9 10                   4   8 10                           10                             10                               10                                 10                                   10                                     10                                       6 10                                           10                                             10                                               8 8 10   10                                                   9    Lambsquarters               5 10                   8   6 3 0 3 8 2 8 7 0 9 7 9 7 2 2    9                                                   5    Morningglory               6 2 0   0 0 0 3 5 0 4 2 0 0 0 0 0 0 0    2                                                   1    Pigweed    6 9 7   5 6 7 7 7 5 7 7 0 4 5 7 0 4 4    5                                                   2    Rape       0 0 0   0 0 0 0 2 0 2 0 0 0 0 2 0 0 0    0                                                   0    Ryegrass   5 4 7   0 2 2 3 6 2 10                                     7 0 7 5 6 3 6 2    4                                                   3    Sorghum    9 8 5   2 7 6 9 10                                 5 6 4 5 5 6 5 4 5 9    9                                                   7    Soybean    0 0 0   0 0 0 0 0 0 1 0 2 0 0 2 0 0 0    0                                                   0    Speedwell  10                 10                   10  10                         5 5 --                               10                                 0 5 2 2 3 0 10                                               9 2 3    10                                                   9    Sugar beet 6 8 10  5 4 0 5 8 0 7 2 2 3 2 7 5 2 3    3                                                   1    Velvetleaf 4 2 0   5 3 2 6 5 2 7 7 0 8 0 7 0 5 0    5                                                   3    Wheat      0 0 5   0 0 0 0 1 0 2 0 1 0 2 2 2 0 4    3                                                   0    Wild buckwheat               0 3 4   6 3 0 3 5 0 2 0 0 2 0 5 3 0 2    0                                                   0    Wild oat   0 4 4   2 4 0 3 7 5 10                                     7 0 5 4 2 1 3 4    6                                                   5    Barnyardgrass               --                 --                   --  --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --                                                   --   --                                                   --    Rice Japonica               --                 --                   --  --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --                                                   --   --                                                   --    Umbrella sedge               --                 --                   --  --                         --                           --                             --                               --                                 --                                   --                                     --                                       --                                         --                                           --                                             --                                               --                                                 --                                                   --   --                                                   --    __________________________________________________________________________               COMPOUND    Rate (62 g/ha)               3 5 7 10                       11                         15                           18 26                                30                                  32                                    34 35                                         36                                           37                                             38 39                                                  41                                                    42                                                      44    __________________________________________________________________________    POSTEMERGENCE    Barley Igri               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Bedstraw   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Blackgrass --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Chickweed  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Corn       --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Cotton     --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Crabgrass  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Downy brome               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Duck salad 0 0 0 9 0 8 0  0 0 0 0  0 0 0 0  0 0 0  0    Giant foxtail               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Lambsquarters               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Morningglory               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Pigweed    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Rape       --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Ryegrass   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Sorghum    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Soybean    --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Speedwell  --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Sugar beet --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Velvetleaf --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wheat      --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wild buckwheat               --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Wild oat   --                 --                   --                     --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    -- --    Barnyardgrass               8 8 0 10                       8 9 8  0 8 8 6  8 7 6 8  8 5 8  0    Rice Japonica               6 6 1 8 5 6 6  5 5 5 6  6 6 7 7  5 7 6  5    Umbrella sedge               0 0 0 9 9 9 8  0 0 0 0  0 0 0 0  0 0 0  0    __________________________________________________________________________               COMPOUND    Rate (62 g/ha)               3 7   10                       11                         15                           18 26                                30                                  32                                    34 35                                         36                                           37                                             38 39                                                  41                                                    42                                                      44    __________________________________________________________________________    PREEMERGENCE    Barley Igri               0 0   0 0 0 0  0 0 0 0  0 0 0 0  0 0 0 0    Bedstraw   0 0   0 0 2 5  0 2 3 0  0 2 5 5  0 0 0 0    Blackgrass 9 4   2 3 3 6  4 9 9 0  9 5 9 9  7 7 8 7    Chickweed  0 2   0 0 0 4  0 5 0 0  3 0 7 5  0 0 4 0    Corn       4 0   2 3 4 4  0 1 0 0  0 2 2 0  0 2 1 0    Cotton     3 0   0 0 0 0  0 4 0 0  1 0 2 0  2 0 0 0    Crabgrass  9 4   9 9 9 10 8 9 9 6  10                                         9 9 9  6 9 9 9    Downy brome               0 0   0 0 0 0  0 2 0 0  2 2 2 2  0 0 1 0    Duck salad --                 --  --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    --                                                      --    Giant foxtail               2 5   9 7 9 10 9 10                                  9 5  9 10                                           9 5  7 10                                                    9 7    Lambsquarters               0 0   0 0 3 8  0 8 5 0  5 3 7 7  0 0 8 3    Morningglory               0 0   0 0 0 2  0 2 0 0  0 0 0 0  0 0 1 1    Pigweed    7 0   6 7 7 7  0 5 6 0  2 4 7 0  2 0 2 0    Rape       0 0   0 0 0 0  0 0 0 0  0 0 0 0  0 0 0 0    Ryegrass   4 0   0 0 0 3  0 6 5 0  3 2 4 2  2 0 2 0    Sorghum    4 0   2 3 4 5  0 4 4 4  5 5 4 4  3 5 5 3    Soybean    0 0   0 0 0 0  0 0 0 0  0 0 0 0  0 0 0 0    Speedwell  10                 6   2 5 --                           9  0 0 0 0  2 0 5 9  0 0 9 9    Sugar beet 5 5   0 0 3 5  0 5 0 0  2 0 6 3  0 2 1 1    Velvetleaf 0 4   0 0 5 5  0 5 5 0  4 4 5 0  4 0 2 2    Wheat      3 0   0 0 0 0  0 0 0 0  0 0 0 0  0 2 1 0    Wild buckwheat               4 3   0 0 0 0  0 0 0 0  0 0 4 3  0 0 0 0    Wild oat   2 0   0 0 0 2  2 7 4 0  3 2 0 0  0 0 1 0    Barnyardgrass               --                 --  --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    --                                                      --    Rice Japonica               --                 --  --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    --                                                      --    Umbrella sedge               --                 --  --                       --                         --                           -- --                                --                                  --                                    -- --                                         --                                           --                                             -- --                                                  --                                                    --                                                      --    __________________________________________________________________________               COMPOUND    Rate (31 g/ha)               3  5  10 30 32  34 35 36 37  38 39 42 44    __________________________________________________________________________    POSTEMERGENCE    Barley Igri               -- -- -- -- --  -- -- -- --  -- -- -- --    Bedstraw   -- -- -- -- --  -- -- -- --  -- -- -- --    Blackgrass -- -- -- -- --  -- -- -- --  -- -- -- --    Chickweed  -- -- -- -- --  -- -- -- --  -- -- -- --    Corn       -- -- -- -- --  -- -- -- --  -- -- -- --    Cotton     -- -- -- -- --  -- -- -- --  -- -- -- --    Crabgrass  -- -- -- -- --  -- -- -- --  -- -- -- --    Downy brome               -- -- -- -- --  -- -- -- --  -- -- -- --    Duck salad 0  0  -- 0  0   0  0  0  0   0  0  0  0    Giant foxtail               -- -- -- -- --  -- -- -- --  -- -- -- --    Lambsquarters               -- -- -- -- --  -- -- -- --  -- -- -- --    Morningglory               -- -- -- -- --  -- -- -- --  -- -- -- --    Pigweed    -- -- -- -- --  -- -- -- --  -- -- -- --    Rape       -- -- -- -- --  -- -- -- --  -- -- -- --    Ryegrass   -- -- -- -- --  -- -- -- --  -- -- -- --    Sorghum    -- -- -- -- --  -- -- -- --  -- -- -- --    Soybean    -- -- -- -- --  -- -- -- --  -- -- -- --    Speedwell  -- -- -- -- --  -- -- -- --  -- -- -- --    Sugar beet -- -- -- -- --  -- -- -- --  -- -- -- --    Velvetleaf -- -- -- -- --  -- -- -- --  -- -- -- --    Wheat      -- -- -- -- --  -- -- -- --  -- -- -- --    Wild buckwheat               -- -- -- -- --  -- -- -- --  -- -- -- --    Wild oat   -- -- -- -- --  -- -- -- --  -- -- -- --    Barnyardgrass               0  1  0  6  8   3  0  2  3   6  2  4  0    Rice Japonica               4  3  3  5  3   1  5  4  7   4  1  5  2    Umbrella sedge               0  0  -- 0  0   0  0  0  0   0  0  0  0    __________________________________________________________________________               COMPOUND    Rate (31 g/ha)               3   30 32   34 35   36 37   38 39   42 44    __________________________________________________________________________    PREEMERGENCE    Barley Igri               0   0  0    0  0    0  0    0  0    0  0    Bedstraw   0   0  0    0  0    0  2    1  0    0  0    Blackgrass 4   9  9    0  5    2  3    4  3    3  3    Chickweed  0   4  0    0  0    0  2    0  0    0  --    Corn       0   0  0    0  0    0  0    0  0    0  0    Cotton     2   3  0    0  1    0  0    0  0    0  0    Crabgrass  8   9  6    2  9    9  8    6  5    9  8    Downy brome               0   0  0    0  0    0  0    0  0    0  0    Duck salad --  -- --   -- --   -- --   -- --   -- --    Giant foxtail               0   7  5    0  7    5  5    2  5    8  2    Lambsquarters               0   7  0    0  2    0  0    3  0    0  --    Morningglory               0   0  0    0  0    0  0    0  0    0  0    Pigweed    5   4  4    0  0    0  2    0  0    0  0    Rape       0   0  0    0  0    0  0    0  0    0  0    Ryegrass   0   2  2    0  0    0  3    0  0    0  0    Sorghum    0   3  4    2  4    4  3    2  3    2  0    Soybean    0   0  0    0  0    0  0    0  0    0  0    Speedwell  7   0  0    0  0    0  1    3  0    8  9    Sugar beet 5   0  0    0  0    0  5    2  0    0  0    Velvetleaf 0   4  3    0  4    2  4    0  4    0  0    Wheat      0   0  0    0  0    0  0    0  0    0  0    Wild buckwheat               0   0  0    0  0    0  3    0  0    0  0    Wild oat   0   4  0    0  0    0  0    0  0    0  0    Barnyardgrass               --  -- --   -- --   -- --   -- --   -- --    Rice Japonica               --  -- --   -- --   -- --   -- --   -- --    Umbrella sedge               --  -- --   -- --   -- --   -- --   -- --    __________________________________________________________________________                      COMPOUND           Rate (16 g/ha)                      3               5  10    __________________________________________________________________________           POSTEMERGENCE           Barley Igri                      --              -- --           Bedstraw   --              -- --           Blackgrass --              -- --           Chickweed  --              -- --           Corn       --              -- --           Cotton     --              -- --           Crabgrass  --              -- --           Downy brome                      --              -- --           Duck salad 0               0  --           Giant foxtail                      --              -- --           Lambsquarters                      --              -- --           Morningglory                      --              -- --           Pigweed    --              -- --           Rape       --              -- --           Ryegrass   --              -- --           Sorghum    --              -- --           Soybean    --              -- --           Speedwell  --              -- --           Sugar beet --              -- --           Velvetleaf --              -- --           Wheat      --              -- --           Wild buckwheat                      --              -- --           Wild oat   --              -- --           Barnyardgrass                      0               0  0           Rice Japonica                      1               0  0           Umbrella sedge                      0               0  --    __________________________________________________________________________                      COMPOUND           Rate (16 g/ha)                      3    __________________________________________________________________________           PREEMERGENCE           Barley Igri                      0           Bedstraw   0           Blackgrass 0           Chickweed  0           Corn       0           Cotton     0           Crabgrass  5           Downy brome                      0           Duck salad --           Giant foxtail                      0           Lambsquarters                      0           Morningglory                      0           Pigweed    0           Rape       0           Ryegrass   0           Sorghum    0           Soybean    0           Speedwell  3           Sugar beet 4           Velvetleaf 0           Wheat      0           Wild buckwheat                      0           Wild oat   0           Barnyardgrass                      --           Rice Japonica                      --           Umbrella sedge                      --    __________________________________________________________________________

TEST D

Seeds of barnyardgrass (Echinochloa crusgalli), black nightshade(Solanum prycanthum dunal), common ragweed (Ambrosia elatior), corn (Zeamays), cotton (Gossypium hirsutum), crabgrass (Digitaria spp.), fallpanicum (Panicum dicholomiflorum), giant foxtail (Setaria faberii),green foxtail (Setaria viridis), johnsongrass (Sorghum halepense),lambsquarter (Chenopodium album), pigweed (Amaranthus retroflexus),signalgrass (Brachiaria platyphylla), smartweed (Polygonumpensylvanicum), soybean (Glycine max), wild proso (Panicum miliaceum)and wooly cupgrass (Eriochloa villosa) were planted into a silt loamsoil. Test chemicals, dissolved in a non-phytotoxic solvent, were thenapplied to the soil surface within one clay after the seeds wereplanted.

Treated plants and untreated controls were maintained in the greenhouseapproximately 21 days, then treated plants were compared to tintreatedcontrols and visually evaluated. Plant response ratings, summarized inTable D, are reported on a 0 to 10 scale where 0 is no effect and 10 iscomplete control.

                                      TABLE D    __________________________________________________________________________                       COMPOUND    Rate (1000 g/ha)   3 10    __________________________________________________________________________    PREEMERGENCE    Barnyardgrass      10                         10    Black Nightshade   --                         10    Common Ragweed     --                          9    Corn G4689A        10                          9    Cotton              7                         10    Crabgrass          10                         10    Fall Panicum       10                         10    Giant Foxtail       7                         10    Green Foxtail       7                         10    Johnson Grass      10                         10    Lambsquarter       --                         10    Pigweed            --                          9    Signalgrass        10                         10    Soybean             8                          6    Wild Proso         10                         10    __________________________________________________________________________               COMPOUND    Rate (500 g/ha)               1 2 3 10 15                          18                            26                              30 35                                   36                                     37                                       41    __________________________________________________________________________    PREEMERGENCE    Barnyardgrass               10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Black Nightshade               --                 --                   --                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Common Ragweed               --                 --                   --                     7  9 10                            8 9  5 8 10                                       10    Corn G4689A               7 9 8 7  8 9 6 6  6 7 8 7    Cotton     5 10                   --                     10 --                          9 1 0  0 3 4 0    Crabgrass  10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Fall Panicum               10                 10                   10                     10 10                          10                            10                              -- 10                                   10                                     --                                       10    Giant Foxtail               10                 10                   2 10 10                          10                            10                              10 10                                   10                                     10                                       10    Green Foxtail               10                 10                   1 10 10                          10                            10                              10 10                                   10                                     10                                       10    Johnson Grass               10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Lambsquarter               --                 --                   --                     9  10                          10                            9 7  9 10                                     10                                       9    Pigweed    --                 --                   --                     6  10                          10                            7 7  7 5 9 5    Signalgrass               10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Smartweed  --                 --                   --                     -- --                          --                            10                              9  7 7 9 9    Soybean    3 0 1 2  6 8 2 0  0 2 5 6    Wild Proso 10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Wooly Cupgrass               --                 --                   --                     -- 9 10                            8 -- 10                                   10                                     --                                       10    __________________________________________________________________________               COMPOUND    Rate (250 g/ha)               1 2 3 10 15                          18                            26                              30 35                                   36                                     37                                       41    __________________________________________________________________________    PREEMERGENCE    Barnyardgrass               10                 10                   10                     10 10                          10                            6 10 10                                   10                                     7 10    Black Nightshade               --                 --                   --                     9  9 10                            9 10 10                                   10                                     10                                       10    Common Ragweed               --                 --                   --                     6  8 6 3 6  0 5 6 7    Corn G4689A               4 6 7 2  4 7 1 5  2 2 6 6    Cotton     --                 7 0 10 --                          0 0 0  0 0 3 0    Crabgrass  10                 10                   10                     10 10                          10                            9 10 10                                   8 10                                       8    Fall Panicum               10                 10                   10                     10 10                          10                            10                              -- 10                                   10                                     --                                       10    Giant Foxtail               10                 10                   1 10 10                          10                            10                              10 10                                   10                                     10                                       10    Green Foxtail               10                 10                   1 10 10                          10                            10                              10 10                                   10                                     10                                       10    Johnson Grass               10                 10                   10                     10 10                          10                            6 7  10                                   10                                     10                                       10    Lambsquarter               --                 --                   --                     8  8 10                            7 9  9 9 10                                       9    Pigweed    --                 --                   --                     5  6 6 4 6  5 3 8 5    Signalgrass               10                 10                   8 10 10                          10                            7 10 10                                   10                                     9 10    Smartweed  --                 --                   --                     -- --                          --                            6 5  6 5 6 6    Soybean    --                 --                   --                     0  0 3 0 0  0 0 1 0    Wild Proso 10                 10                   10                     10 10                          10                            10                              10 10                                   10                                     10                                       10    Wooly Cupgrass               --                 --                   --                     -- 8 10                            7 -- 9 9 --                                       10    __________________________________________________________________________               COMPOUND    Rate (125 g/ha)               1 2 3 10 15                          18                            26                              30 35                                   36                                     37                                       41    __________________________________________________________________________    PREEMERGENCE    Barnyardarass               10                 9 10                     5  10                          10                            5 8  8 9 8 8    Black Nightshade               --                 --                   --                     8  9 9 9 9  9 9 9 9    Common Ragweed               --                 --                   --                     0  7 5 0 1  0 0 6 0    Corn G4689A               2 1 6 1  2 5 0 1  0 0 0 1    Cotton     --                 0 0 0  0 0 0 0  0 0 0 0    Crabgrass  10                 10                   10                     9  10                          10                            6 10 8 7 10                                       7    Fall Panicum               10                 10                   10                     10 10                          10                            10                              -- 10                                   10                                     --                                       10    Giant Foxtail               10                 10                   1 6  9 10                            10                              9  9 10                                     10                                       9    Green Foxtail               7 10                   0 6  10                          10                            10                              6  9 10                                     7 7    Johnson Grass               6 10                   10                     9  10                          10                            6 7  7 10                                     9 8    Lambsquarter               --                 --                   --                     3  8 9 7 8  3 7 8 8    Pigweed    --                 --                   --                     4  4 3 4 1  4 2 6 2    Signalgrass               8 9 0 10 10                          10                            5 10 7 10                                     7 9    Smartweed  --                 --                   --                     -- --                          --                            3 2  3 5 6 5    Soybean    0 0 0 0  0 0 0 0  0 0 0 0    Wild Proso 9 10                   10                     8  10                          10                            8 9  9 9 10                                       8    Wooly Cupgrass               --                 --                   --                     -- 8 10                            7 -- 6 6 --                                       9    __________________________________________________________________________               COMPOUND    Rate (62 g/ha)               1 2 3 10 15                          18                            26                              30 35                                   36                                     37                                       41    __________________________________________________________________________    PREEMERGENCE    Barnyardarass               7 9 1 5  8 10                            2 6  5 6 6 6    Black Nightshade               --                 --                   --                     6  4 9 5 8  9 5 8 9    Common Ragweed               --                 --                   --                     0  3 1 0 0  0 0 0 0    Corn G4689A               1 1 0 0  2 0 0 0  0 0 0 0    Cotton     0 0 --                     -- 0 0 0 0  0 0 0 0    Crabgrass  6 10                   4 4  10                          9 3 6  7 4 6 4    Fall Panicum               2 10                   0 8  10                          10                            5 -- 10                                   10                                     --                                       10    Giant Foxtail               5 6 0 1  9 10                            6 6  9 6 9 8    Green Foxtail               4 6 0 0  9 10                            5 4  6 6 6 6    Johnson Grass               1 2 10                     1  10                          6 2 1  5 5 2 4    Lambsquarter               --                 --                   --                     0  1 7 5 7  0 0 4 6    Pigweed    --                 --                   --                     0  0 2 3 1  3 2 0 2    Signalgrass               0 7 0 0  10                          10                            1 8  5 3 1 8    Smartweed  --                 --                   --                     -- --                          --                            0 1  2 0 3 0    Soybean    0 0 0 0  0 0 0 0  0 0 0 0    Wild Proso 5 10                   1 4  9 9 5 8  6 7 8 5    Woolu Cupgrass               --                 --                   --                     -- 8 9 5 -- 6 5 --                                       4    __________________________________________________________________________               COMPOUND    Rate (31 g/ha)               1 2  15 18 26 30 35 36                                     37                                       41    __________________________________________________________________________    PREEMERGENCE    Barnyardgrass               0 0  4  6  0  2  0  0 5 1    Black Nightshade               --                 -- 4  7  3  2  0  0 5 8    Common Ragweed               --                 -- 0  0  0  0  0  0 0 0    Corn G4689A               0 1  0  0  0  0  0  0 0 0    Cotton     0 0  0  -- 0  0  0  0 0 0    Crabgrass  0 3  5  6  0  3  0  0 5 0    Fall Panicum               0 0  6  10 0  -- 9  0 --                                       5    Giant Foxtail               0 0  4  6  0  0  3  0 1 2    Green Foxtail               0 0  4  6  0  0  2  0 1 2    Johnson Grass               0 0  0  5  2  0  0  3 1 4    Lambsquarter               --                 -- 0  0  0  4  0  0 0 0    Pigweed    --                 -- 0  0  3  0  0  1 0 0    Signalgrass               0 0  8  9  0  0  1  0 0 5    Smartweed  --                 -- -- -- 0  0  0  0 0 0    Soybean    0 0  0  0  0  0  0  0 0 0    Wild Proso 0 0  3  9  0  0  0  4 2 4    Wooly Cupgrass               --                 -- 1  9  0  -- 0  0 --                                       1    __________________________________________________________________________

TEST E

Compounds evaluated in this test were formulated in a non-phytoxicsolvent and applied to the soil surface before plant seedlings emerged(preemergence application) and to plants that were in the one-to-fourleaf stage (postemergence application). A sandy loam soil was used forthe preemergence test while a mixture of sandy loam soil and greenhousepotting mix in a 60:40 ratio was used for the postemergence test. Testcompounds were applied within approximately one day after planting seedsfor the preemergence test.

Plantings of these crops and weed species were adjusted to produceplants of appropriate size for the postemergence test. All plant specieswere grown using normal greenhouse practices. Crop and weed speciesinclude winter barley (Hordeum vulgare cv. `Igri`), blackgrass(Alopecurus myosuroides), chickweed (Stellaria media), downy brome(Bromus rectorum), field violet (Viola arvensis), galium (Galiumaparine), green foxtail (Setaria viridis), kochia (Kochia scoparia),lambsquarters (Chenopodium album), speedwell (Veronica persica), rape(Brassica napus), ryegrass (Lolium multiflorum), sugar beet (Betavulgrais cv. `US1`), sunflower (Helianthus annuus cv. `Russian Giant`),spring wheat (Triticum aestivum cv. `ERA`), winter wheat (Triticumaestivum cv. Talent`), wild buckwheat (Polygonum convolvulus), wildmustard (Sinapis arvensis), wild oat (Avena fatua), and wild radish(Raphanus raphamstrum).

Blackgrass, galium and wild oat were treated at two growth stages. Thefirst stage (1) was when the plants had two to three leaves. The secondstage (2) was when the plants had approximately four leaves or in theinitial stages of tillering. Treated plants and untreated controls weremaintained in a greenhouse for approximately 21 to 28 days, after whichall treated plants were compared to untreated controls and visuallyevaluated. Plant response ratings, summarized in Table E, axe based upona 0 to 10 scale where 0 is no effect and 10 is complete control. A dashresponse (-) means no test result.

                  TABLE E    ______________________________________                      COMPOUND    Rate (1000 g/ha)    10     15    ______________________________________    POSTEMERGENCE    Blackgrass (1)      2      8    Blackgrass (2)      2      7    Chickweed           2      0    Downy brome         3      2    Field violet        0      0    Galium (1)          4      3    Galium (2)          3      3    Green foxtail       5      10    Kochia              0      0    Lambsquarters       7      2    Speedwell           0      3    Rape                2      3    Ryegrass            5      9    Sugar beet          3      2    Sunflower           2      5    Wheat (Spring)      3      3    Wheat (Winter)      2      2    Wild buckwheat      2      3    Wild mustard        3      4    Wild oat (1)        3      8    Wild oat (2)        2      8    Wild radish         --     2    Winter Barley       2      0    ______________________________________                      COMPOUND    Rate (1000 g/ha)    10     15    ______________________________________    PREEMERGENCE    Blackgrass (1)      10     10    Blackgrass (2)      10     10    Chickweed           10     10    Downy brome         10     8    Field violet        10     4    Galium (1)          10     10    Galium (2)          10     10    Green foxtail       10     10    Kochia              10     10    Lambsquarters       10     --    Speedwell           10     8    Rape                9      10    Ryegrass            10     10    Sugar beet          9      9    Sunflower           5      4i    Wheat (Spring)      5      4    Wheat (Winter)      5      Q    Wild buckwheat      9      2    Wild mustard        10     10    Wild oat (1)        10     10    Wild oat (2)        10     10    Wild radish         7      5    Winter Barley       2      5    ______________________________________               COMPOUND    Rate (500 g/ha)                 10     15      18   26   30   41    ______________________________________    POSTEMERGENCE    Blackgrass (1)                 0      3       --   --   --   --    Blackgrass (2)                 0      3       --   --   --   --    Chickweed    0      0       --   --   --   --    Downy brome  0      0       --   --   --   --    Field violet 0      0       --   --   --   --    Galium (1)   0      0       --   --   --   --    Galium (2)   0      0       --   --   4    --    Green foxtail                 2      7       --   --   --   --    Kochia       0      0       --   --   --   --    Lambsquarters                 3      0       --   --   --   --    Speedwell    0      0       --   --   --   --    Rape         0      0       --   --   --   --    Ryegrass     2      4       --   --   --   --    Sugar beet   0      0       --   --   --   --    Sunflower    0      2       --   --   --   --    Wheat (Spring)                 0      0       --   --   --   --    Wheat (Winter)                 0      0       --   --   --   --    Wild buckwheat                 0      0       --   --   --   --    Wild mustard 0      0       --   --   --   --    Wild oat (1) 0      3       --   --   --   --    Wild oat (2) 0      2       --   --   --   --    Wild radish  --     0       --   --   --   --    Winter Barley                 0      0       --   --   --   --    ______________________________________               COMPOUND    Rate (500 g/ha)                 10     15      18   26   30   41    ______________________________________    PREEMERGENCE    Blackgrass (1)                 10     9       10   3    10   10    Blackgrass (2)                 10     8       10   10   9    10    Chickweed    10     10      10   9    10   9    Downy brome  7      4       10   5    10   7    Field violet 10     2       10   6    8    10    Galium (1)   9      7       6    10   10   10    Galium (2)   10     7       10   10   10   10    Green foxtail                 10     10      10   10   10   10    Kochia       10     6       --   --   10   --    Lambsquarters                 10     --      --   10   10   9    Speedwell    10     6       10   9    8    10    Rape         6      8       8    9    9    9    Ryegrass     10     10      10   8    10   10    Sugar beet   8      6       8    5    7    7    Sunflower    3      2       8    10   10   10    Wheat (Spring)                 2      2       0    0    7    4    Wheat (Winter)                 2      1       5    4    9    6    Wild buckwheat                 8      0       --   5    7    6    Wild mustard 7      8       10   10   10   10    Wild oat (1) 10     9       10   10   10   10    Wild oat (2) 10     8       10   10   10   10    Wild radish  5      2       9    8    8    10    Winter Barley                 0      2       0    2    4    5    ______________________________________                      COMPOUND    Rate (250 g/ha)     10     15    ______________________________________    POSTEMERGENCE    Blackgrass (1)      0      0    Blackgrass (2)      0      0    Chickweed           0      0    Downy brome         0      0    Field violet        0      0    Galium (1)          0      0    Galium (2)          0      0    Green foxtail       0      2    Kochia              0      0    Lambsquarters       0      0    Speedwell           0      0    Rape                0      0    Ryegrass            0      0    Sugar beet          0      0    Sunflower           0      0    Wheat (Spring)      0      0    Wheat (Winter)      0      0    Wild buckwheat      0      0    Wild mustard        0      0    Wild oat (1)        0      0    Wild oat (2)        0      0    Wild radish         --     0    Winter Barley       0      0    ______________________________________               COMPOUND    Rate (250 g/ha)                 10    15     18  26   30  37   38  41    ______________________________________    PREEMERGENCE    Blackgrass (1)                 8     6      9   3    9   7    8   6    Blackgrass (2)                 8     5      10  5    9   10   6   10    Chickweed    10    8      10  8    7   7    3   7    Downy brome  5     2      0   3    9   7    6   5    Field violet 10    0      10  6    7   7    4   10    Galium (1)   7     3      4   9    10  0    9   7    Galium (2)   8     3      10  5    10  10   10  9    Green foxtail                 10    10     10  10   10  10   10  10    Kochia       8     2      --  --   9   --   --  --    Lambsquarters                 6     --     --  9    10  9    8   8    Speedwell    10    4      10  9    7   8    10  10    Rape         2     5      6   2    9   2    5   4    Ryegrass     9     8      10  4    10  10   10  10    Sugar beet   6     4      8   --   7   5    3   7    Sunflower    0     0      7   10   10  10   3   10    Wheat (Spring)                 0     0      0   0    6   3    2   4    Wheat (Winter)                 0     0      0   3    6   2    1   5    Wild buckwheat                 3     0      --  5    5   2    0   3    Wild mustard 4     6      10  10   10  6    9   9    Wild oat (1) 7     4      5   9    7   8    10  7    Wild oat (2) 7     4      10  10   10  10   10  10    Wild radish  2     0      9   8    5   8    1   10    Winter Barley                 0     0      0   0    4   0    2   5    ______________________________________               COMPOUND    Rate (125 g/ha)                 10    15    18   26  30  32  37  38  41    ______________________________________    PREEMERGENCE    Blackgrass (1)                 3     3     8    2   5   0   4   2   5    Blackgrass (2)                 3     2     6    3   7   5   9   4   5    Chickweed    9     5     6    7   4   0   2   3   3    Downy brome  2     0     0    0   2   0   0   4   5    Field violet 7     0     4    3   0   2   3   4   8    Galium (1)   4     0     4    0   5   0   0   2   0    Galium (2)   4     0     5    3   6   0   4   2   0    Green foxtail                 10    7     10   10  10  10  10  10  10    Kochia       3     0     --   --  8   --  --  --  --    Lambsquarters                 3     --    --   6   5   0   7   6   5    Speedwell    8     2     10   6   2   0   5   9   10    Rape         0     2     5    0   3   0   0   0   2    Ryegrass     7     5     8    0   10  4   10  3   5    Sugar beet   4     3     8    0   4   0   5   3   7    Sunflower    0     0     0    10  10  --  4   0   3    Wheat (Spring)                 0     0     0    0   5   1   0   1   4    Wheat (Winter)                 0     0     0    1   3   0   0   0   4    Wild buckwheat                 0     0     --   5   5   0   0   0   3    Wild mustard 0     3     10   6   9   3   0   7   8    Wild oat (1) 3     3     0    2   3   0   5   5   5    Wild oat (2) 3     2     9    0   7   1   8   8   7    Wild radish  0     0     8    4   2   0   0   1   7    Winter Barley                 0     0     0    0   1   0   0   0   4    ______________________________________               COMPOUND    Rate (64 g/ha)                 10    15    18   26  30  32  37  38  41    ______________________________________    PREEMERGENCE    Blackgrass (1)                 0     0     6    0   3   0   0   0   3    Blackgrass (2)                 0     0     4    --  4   0   2   0   4    Chickweed    3     2     5    2   3   0   2   0   3    Downy brome  0     0     0    0   0   0   0   2   4    Field violet 3     0     3    3   0   0   0   3   7    Galium (1)   2     0     0    0   0   0   0   0   0    Galium (2)   2     0     5    3   0   0   2   0   0    Green foxtail                 7     4     10   10  10  9   10  10  10    Kochia       0     0     --   --  8   --  --  --  --    Lambsquarters                 0     --    --   6   5   0   6   5   4    Speedwell    4     0     10   2   0   0   2   1   8    Rape         0     0     0    0   0   0   0   0   0    Ryegrass     4     2     0    0   1   2   3   0   4    Sugar beet   2     0     6    0   3   0   2   2   4    Sunflower    0     0     0    10  3   0   --  --  --    Wheat (Spring)                 0     0     0    0   5   0   0   1   4    Wheat (Winter)                 0     0     0    0   3   0   0   0   4    Wild buckwheat                 0     0     0    5   2   0   0   0   3    Wild mustard 0     0     5    0   7   3   0   0   8    Wild oat (1) 0     0     0    0   2   0   0   0   0    Wild oat (2) 0     0     3    0   3   0   0   5   5    Wild radish  0     0     5    4   0   0   0   0   6    Winter Barley                 0     0     0    0   1   0   0   0   3    ______________________________________               COMPOUND    Rate (32 g/ha)                 10    18     26  30   32  37   38  41    ______________________________________    PREEMERGENCE    Blackgrass (1)                 0     3      0   0    0   0    0   0    Blackgrass (2)                 0     0      0   0    0   0    0   2    Chickweed    0     --     0   0    0   0    0   2    Downy brome  0     0      0   0    0   0    0   3    Field violet 0     --     2   0    0   0    0   6    Galium (1)   0     0      0   0    0   0    0   0    Galium (2)   0     0      3   0    0   0    --  0    Green foxtail                 4     4      10  5    3   10   10  8    Kochia       0     --     --  --   --  --   --  --    Lambsquarters                 0     --     5   0    0   0    0   0    Speedwell    2     0      0   0    0   0    0   8    Rape         0     0      0   0    0   0    0   0    Ryegrass     0     0      0   1    2   0    0   2    Sugar beet   0     0      0   2    0   0    0   0    Sunflower    0     0      4   0    0   --   --  3    Wheat (Spring)                 0     0      0   3    0   0    0   3    Wheat (Winter)                 0     0      0   3    0   0    0   2    Wild buckwheat                 0     0      0   0    0   0    0   3    Wild mustard 0     --     0   2    2   0    0   0    Wild oat (1) 0     0      0   2    0   0    0   0    Wild oat (2) 0     0      0   3    0   0    2   3    Wild radish  --    0      4   0    0   0    0   6    Winter Barley                 0     0      0   1    0   0    0   1    ______________________________________                   COMPOUND    Rate (16 g/ha)   32         37    38    ______________________________________    PREEMERGENCE    Blackgrass (1)   0          0     0    Blackarass (2)   0          0     0    Chickweed        0          0     0    Downy brome      0          0     0    Field violet     0          0     0    Galium (1)       0          0     0    Galium (2)       0          0     0    Green foxtail    0          1     0    Lambsquarters    0          0     0    Speedwell        0          0     0    Rape             0          0     0    Ryegrass         0          0     0    Sugar beet       0          0     0    Sunflower        0          3     --    Wheat (Spring)   0          0     0    Wheat (Winter)   0          0     0    Wild buckwheat   0          0     0    Wild mustard     0          0     0    Wild oat (1)     0          0     0    Wild oat (2)     0          0     0    Wild radish      0          0     0    Winter Barley    0          0     0    ______________________________________

What is claimed is:
 1. A compound of the formula: ##STR437## wherein Ais a pyrazole ring substituted with 1 to 3 substituents selected fromR³, R⁴, R⁵ and R⁶ ;R¹ is H; C₁ -C₆ alkyl optionally substituted with C₁-C₃ alkoxy or 1 to 5 halogens; C.sub. -C₆ cycloalkyl; C₂ -C₆ alkenyloptionally substituted with 1 to 3 halogens; C.sub. -C₆ alkynyl; or C₁-C₃ alkoxy; R² is C₁ -C₆ alkyl optionally substituted with C₁ -C₃ alkoxyor 1 to 5 halogens; C.sub. -C₆ cycloalkyl; C₂ -C₆ alkenyl optionallysubstituted with 1 to 3 halogens; or C.sub. -C₆ alkynyl; R³, R⁴ and R⁵are independently H; halogen; C₁ -C₆ alkyl optionally substituted withone or more halogen, C₁ -C₆ alkoxy, CN, CO₂ R⁷, S(O)_(m) R⁸, C(O)NR⁹ R¹⁰or SO₂ NR¹³ R¹⁴ ; C.sub. -C₆ cycloalkyl; C₂ -C₆ alkenyl; C₂ -C₆haloalkenyl; C₂ -C₆ alkynyl; C₁ -C₆ alkoxy; CN; CO₂ R¹¹ ; S(O)_(p) R¹² ;C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ; C(O)R¹⁹, C(OR²⁰) (OR²¹) R²² ; CR²³ ═NOR²⁴; NO₂ ; NR²⁵ R²⁶ ; or phenyl or benzyl, each ring optionally substitutedwith 1 to 3 substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃haloalkyl and C₁ -C₃ alkoxy; R⁶ is H; C₁ -C₆ alkyl optionallysubstituted with one or more halogen, C₁ -C₆ alkoxy, CN, CO₂ R⁷,S(O)_(m) R⁸, C(O)NR⁹ R¹⁰ or SO₂ NR¹³ R¹⁴ ; C₂ -C₆ alkenyl; C₂ -C₆haloalkenyl; C₂ -C₆ alkynyl; CN; CO₂ R¹¹ ; SO₂ R¹² ; C(O)NR¹⁵ R¹⁶ ; SO₂NR¹⁷ R¹⁸ ; or phenyl or benzyl, each ring optionally substituted with 1to 3 substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃ haloalkyland C₁ -C₃ alkoxy; R⁷ and R¹¹ are independently H, C₁ -C₃ alkyl orallyl; R⁸ and R¹² are independently C₁ -C₃ alkyl; R⁹, R¹⁰, R¹³, R¹⁴,R¹⁵, R¹⁶, R¹⁷ and R¹⁸ are independently H or C₁ -C₃ alkyl; R¹⁹, R²² andR²³ are independently H or C₁ -C₃ alkyl; R²⁰ and R²¹ are independentlyC₁ -C₃ alkyl; R²⁴ is H or C₁ -C₃ alkyl; R²⁵ and R²⁶ are independently Hor C₁ -C₃ alkyl; and m, n and p are independently 0, 1 or 2;providedthat a) R³, R⁴ and R⁵ are independently bonded to carbon, and R⁶ isbonded to nitrogen; and b) when S(O)_(n) is bonded to nitrogen then n is2.
 2. A compound of claim 1 whereto n is 1 or
 2. 3. A compound of claim2 where A is ##STR438## wherein X is NR⁶.
 4. A compound of claim 3 wheren is 2 and R¹ and R² are independently C₁ -C₃ alkyl or C₂ -C₃ alkenyl.5. A compound of claim 4 whereR³, R⁴ and R⁵ are independently H; F; Cl;Br; C₁ -C₃ alkyl optionally substituted with one or more F, Cl, Br or C₁-C₃ alkoxy; cyclopropyl; C₂ -C₃ alkenyl; C₂ -C₃ haloalkenyl; C₂ -C₃alkynyl; C₁ -C₃ alkoxy; CN; CO₂ (C₁ -C₂ alkyl), S(O)_(p) (C₁ -C₂ alkyl);C(O)NR¹⁵ R¹⁶ ; SO₂ NR¹⁷ R¹⁸ ; C(O) R¹⁹, C (OR²⁰) (OR²¹) R²² ; CR²³═NOR²⁴ ; NO₂ ; NR²⁵ R²⁶ ; or phenyl optionally substituted with 1 to 3substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃ haloalkyl andC₁ -C₃ alkoxy; R⁶ is H, C₁ -C₄ alkyl optionally substituted with one ormore F, Cl, Br, C₁ -C₃ alkoxy, CN, CO₂ (C₁ -C₂ alkyl), S(O)_(m) (C₁ -C₂alkyl), C(O)NR⁹ R¹⁰ or SO₂ NR¹³ R¹⁴ ; C₂ -C₄ alkenyl; C₂ -C₄haloalkenyl; C₂ -C₄ alkynyl; CO₂ R¹¹ ; SO₂ (C₁ -C₂ alkyl); C(O)NR¹⁵ R¹⁶; SO₂ NR¹⁷ R¹⁸ ; or phenyl or benzyl, each ring optionally substitutedwith 1 to 3 substituents selected from halogen, C₁ -C₃ alkyl, C₁ -C₃haloalkyl and C₁ -C₃ alkoxy; R⁹, R¹⁰, R¹³ and R¹⁴ are independently C₁-C₂ alkyl; R¹¹ is C₁ -C₂ alkyl or allyl; R¹⁵, R¹⁶, R¹⁷, R¹⁸, R²⁵ and R²⁶are independently C₁ -C₃ alkyl; and R¹⁹, R²² and R²³ are independently Hor C₁ -C₂ alkyl.
 6. A compound of claim 5 whereR¹ and R² axeindependently ethyl or allyl; and R⁵ is H, Cl, CH₃, C₂ H₅ or CF₃.
 7. Acomposition suitable for controlling the growth of undesired vegetationwhich comprises an effective mount of a compound of claim 2 and at leastone of the following: surfactant, solid or liquid inert diluent.
 8. Amethod for controlling the growth of undesired vegetation whichcomprises applying to the locus to be protected an effective amount of acompound of claim 2.